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Synthesis and structures of bridged diruthenium complexes (E)[η5-C5H4)Ru(CO)]2(μ-CO)2 (E = Me2Ge, Me2SiOSiMe2, Me2SiOSiMe2OSiMe2)

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Abstract

A series of bridged diruthenium complexes (E)[(η5-C5H4)Ru(CO)]2(μ-CO)2 (E = Me2Ge (2); Me2SiOSiMe2 (3); Me2SiOSiMe2OSiMe2 (4)) has been prepared by reacting Ru3(CO)12 with Cp2E in refluxing heptane. The molecular structures of (2) and (4) have been determined by X-ray diffraction.

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Zhang, Y., Wang, B., Xu, S. et al. Synthesis and structures of bridged diruthenium complexes (E)[η5-C5H4)Ru(CO)]2(μ-CO)2 (E = Me2Ge, Me2SiOSiMe2, Me2SiOSiMe2OSiMe2). Transition Metal Chemistry 24, 610–614 (1999). https://doi.org/10.1023/A:1006918100619

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