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Cobalt(II) complexes of 4-acetamidobenzaldehyde N(4)-substituted thiosemicarbazones

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Abstract

Cobalt(II) complexes of five 4-acetamidobenzaldehyde N(4)-substituted thiosemicarbazones have been prepared in EtOH solution and characterized by i.r., electronic and n.m.r. spectra, and by magnetic susceptibilities and molar conductivity measurements. The thiosemicarbazones coordinate as monoanionic or neutral ligands via the thiosemicarbazone azomethine nitrogen and thione/thiolato sulfur, the latter by loss of the thioamide hydrogen, N(2)H. The resulting cobalt(II) complexes exhibit a varied stereochemistry.

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References

  1. E. Reguera, J. Fernández-Bertrán, A. Dago and C. Díaz, Hyperf. Interact., 73, 295 (1992).

    Google Scholar 

  2. E. Reguera, J. Fernández-Bertrán, C. Díaz and J. Molerio, Hyperf. Interact., 73, 285 (1992).

    Google Scholar 

  3. A.G. Sharpe, in The Chemistry of Cyano Complexes of the Transition Metals, Academic Press, London (1976) Ch. VII.

    Google Scholar 

  4. E. Reguera, J. Fernández-Bertrán and L. Nuñez, Z. Naturforsch., 50B, 1067 (1995).

    Google Scholar 

  5. S.C. Fung and H.G. Drickamer, J. Chem. Phys., 51, 4353 (1969).

    Google Scholar 

  6. D.S. Murty and R.L. Collins, Bull. Amer. Phys. Soc., Ser II, 15, 819 (1970).

    Google Scholar 

  7. R.L. Collins, D.S. Murty and J.G. Cosgrove; Bull. Amer. Phys. Soc., Ser II, 16, 23 (1970).

    Google Scholar 

  8. D.S. Murty, J.G. Cosgrove and R.L. Collins, Nature, 231, 311 (1971).

    Google Scholar 

  9. J.G. Cosgrove, R.L. Collins and D.S. Murty, J. Amer. Chem. Soc., 95, 1083 (1973).

    Google Scholar 

  10. R. Robinette and R.L. Collins, J. Coord. Chem., 4, 65 (1974).

    Google Scholar 

  11. E. Reguera and J. Fernández-Bertrán, Hyperf. Interact., 88, 49 (1994).

    Google Scholar 

  12. J. Fernández-Bertrán, J. Blanco and E. Reguera, Spectrochim. Acta, 46A, 685 (1990).

    Google Scholar 

  13. A. Ludi and H.U. Gudel, Structure and Bonding, 14, 1 (1973).

    Google Scholar 

  14. G.W. Beall, W.O. Milligan, J. Korp and I. Bernal, Inorg. Chem., 16, 2715 (1977).

    Google Scholar 

  15. D.F. Mullica, J.D. Oliver, W.O. Milligan and D.F. Hills, J. Inorg. Nucl. Chem., 15, 361 (1979).

    Google Scholar 

  16. E. Reguera, J. Fernández-Bertrán and L. Nuñez, Polyhedron, 13, 1619 (1994).

    Google Scholar 

  17. P. Gutlich, in U. Gonser (Ed.). MoÈssbauer Spectroscopy, Springer, Berlin, 1975, p. 53

    Google Scholar 

  18. E. Reguera and J. Fernández-Bertrán, J. Radional. Nucl. Chem. Lett., 200, 443 (1995).

    Google Scholar 

  19. J. Fernández-Bertrán, E. Reguera and J. Blanco, Spectrochim. Acta, 46A, 1679 (1990).

    Google Scholar 

  20. E. Reguera and J. Fernández-Bertrán, Eur. J. Solid. State Inorg. Chem., 31, 1021 (1994).

    Google Scholar 

  21. E. Reguera, J. Fernández-Bertrán and J. Duque, Polyhedron, 13, 479 (1994).

    Google Scholar 

  22. J. Fernández-Bertrán and E. Reguera, Solid State Ionics, 93, 139 (1997).

    Google Scholar 

  23. J. Fernández-Bertrán and E. Reguera, Spectrochim. Acta, 49A, 43 (1992).

    Google Scholar 

  24. A.R. Champion and H.G. Drickamer, J. Chem. Phys., 47, 2591 (1967).

    Google Scholar 

  25. G.J. Lewis and E. Whalley, J. Chem Phys., 47, 2591 (1967).

    Google Scholar 

  26. P.G. Sim and E. Whalley, J. Phys. Chem., 91, 1877 (1987).

    Google Scholar 

  27. E. Reguera, J. Balmaseda, G. Quintana, A. Gömez and J. Fernández-Bertrán, Polyhedron, 17, 2353 (1998).

    Google Scholar 

  28. H. Inoue, T. Nakazawa, T. Mitsuhashi, T. Shirai and E. Fluck, Hyperf. Interact., 46, 725 (1989).

    Google Scholar 

  29. G.B. Seifer, Russ. J. Inorg Chem., 5, 33 (1960).

    Google Scholar 

  30. J.F. Allen and K. Bonnette, Jr., J. Inorg. Nucl. Chem., 36, 1011 (1974).

    Google Scholar 

  31. M.B. Robin, Inorg. Chem., 1, 337 (1962).

    Google Scholar 

  32. M.B. Robin and P. Day, Adv. Inorg. Radiochem., 10, 247 (1967).

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Illinois State University, Normal, IL, 61790-4160, USA

    Douglas X. West, Heloisa Beraldo & Amal A. Nassar

  2. Department of Chemistry, El-Menoufia University, Shebin El-Kom, Egypt

    Fathy A. El-Saied & Mohamed I. Ayad

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  1. Douglas X. West
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  2. Heloisa Beraldo
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  3. Amal A. Nassar
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  4. Fathy A. El-Saied
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  5. Mohamed I. Ayad
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West, D.X., Beraldo, H., Nassar, A.A. et al. Cobalt(II) complexes of 4-acetamidobenzaldehyde N(4)-substituted thiosemicarbazones. Transition Metal Chemistry 24, 595–599 (1999). https://doi.org/10.1023/A:1006950826755

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