Summary
Potentiometric and spectroscopic measurements were used to characterize the binding ability of α-hydroxy-methylserine (Hms) with copper(II) and oxovanadium(IV) ions. The ligand was found to be generally a more efficient chelating agent than serine. Both of the deprotonated hydroxyl groups of Hms can be involved in coordination to vanadyl ions, whereas copper(II) binds in the same way as with serine.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
N. Shimada, K. Morimoto, H. Naganawa, T. Takita, M. Hamada, K. Maeda, T. Takeuchi and H. Umezawa,J. Antibiot.,34, 1613 (1981).
K. Morimoto, N. Shimada, H. Naganawa, T. Takita and H. Umezawa,J. Antibiot.,34, 1615 (1981).
T. Shiroza, N. Ebisawa, K. Furihata, T. Endo, H. Seto and N. Otake,Agric. Biol. Chemi.,46, 865 (1986).
T. Shiroza, N. Ebisawa, A. Kojima, K. Furihata, A. Shimazu, T. Endo, H. Seto and N. Otake,Agric. Biol. Chem.,46, 1885 (1982).
T. Shiroza, N. Ebisawa, K. Furihata, T. Endo, H. Seto and N. Otake,Agric. Biol. Chem.,46, 1891 (1982).
Y. Nakamura and C. Shin,Chem. Lett.,49 (1992).
M. J. O'Connor, J. R. Brush and S. B. Ten,Aust. J. Chem.,30, 683 (1977).
K. Kociolek, U. Slomczynska and M. T. Leplawy in D. Theodoropoulos (Ed.),Peptides 1986, Waaletr de Gruyter Co., Berlin, 1987, p. 251.
L. D. Pettit and J. L. M. Swash,J. Chem. Soc., Dalton Trans., 2416 (1976).
T. Kiss, C. Simon and Z. Vachter,J. Coord. Chem.,16, 225 (1987).
H. Kozlowski and Z. Siatecki,Chem. Phys. Lett.,54, 498 (1978).
J. C. Pessoa, L. F. V. Boas and R. D. Gillard,Polyhedron,8, 1173 (1989).
M. Branca, G. Micera, A. Dessi' and H. Kozlowski,J. Chem. Soc., Dalton Trans., 1283 (1989).
M. Branca, G. Micera, D. Sanna, A. Dessi' and H. Kozlowski,J. Chem. Soc., Dalton Trans., 1997 (1990).
M. Jezowska-Bojczuk, H. Kozlowski, P. Decock, M. Cerny and T. Trnka,Carbohydr. Res.,216, 453 (1991).
H. M. Irving, M. G. Miles and L. D. Pettit,Anal. Chim. Acta,38, 475 (1967).
P. Gans, A. Sabatini and A. Vacca,J. Chem. Soc., Dalton Trans., 1196 (1985).
T. Szabo-Planka, G. Peintler, A. Rockenbauer, M. Gyor, M. Varga-Fabian, L. Institorish and L. Balzspiri,J. Chem. Soc., Dalton Trans., 1925 (1989).
L. D. Pettit, J. E. Gregor and H. Kozlowski in R. W. Hay, J. R. Dilworth, K. B. Nolan (Eds),Perspectives on Bioinorganic Chemistry, JAI Press, London, 1991, pp. 1–41.
H. Kozlowski, S. Bouhsina, P. Decock, G. Micera and J. Swiatek,J. Coord. Chem.,24, 319 (1991).
G. Micera, A. Dessi, H. Kozlowski, B. Radomska, J. Urbanska, P. Decock, B. Dubois and I. Olivier,Carbohydr. Res.,188, 25 (1989).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kowalik-Jankowska, T., Kozlowski, H., Kociolek, K. et al. Copper(II) and oxovanadium(IV) complexes of α-hydroxymethylserine. Transition Met Chem 20, 23–25 (1995). https://doi.org/10.1007/BF00135396
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00135396