Skip to main content
SpringerLink
Log in

4-Amino-2,6-dimethyl-5-oxo-3-thioxo-2,3,4,5-tetrahydro-1,2,4-triazine palladium(II) complexes

  • Full Papers
  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Summary

The reaction of [PdCl2(PhCN)2] with 4-amino-2,6-dimethyl-5-oxo-3-thioxo-2,3,4,5-tetrahydro-1,2,4-triazine (L) yields [{PdClL(μ-Cl)}2]·2H2O and [PdCl2L2]·4H2O complexes, which react with KBr in Me2Co to give the corresponding bromo-complexes [{PdBrL(μ-Br)}2] and [PdBr2L2]. When the chloro-complexes are treated with AgClO4 in EtOH, [Pd(H2O)2L](ClO4)2 and [Pd(H2O)2L2](ClO4)2 are formed. I.r., visible, and1H-n.m.r. spectra have been recorded and facilitate assignments.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. H. Neuenhoeffer,Comprehensive Heterocyclic Chemistry,2, 385 (1984).

    Google Scholar 

  2. H. Timmler, R. Wegler, L. Eue y H. Hack,S. Afr. Pat.,68, 04409 (1968);Chem. Abstr.,71, 39014 (1969).

    Google Scholar 

  3. G. López, G. García, G. Sánchez and P. Molina,Trans. Met. Chem.,11, 460 (1986).

    Google Scholar 

  4. P. D. Singh, and L. K. Mishra,J. Ind. Chem. Soc.,65, 21 (1988).

    Google Scholar 

  5. M. I. Iskander, J. Stephanos, N. El Kady, M. El Essawi, A. El Toukhy and L. El Sayed,Transition Met. Chem.,14, 27 (1989).

    Google Scholar 

  6. G. López, G. Sánchez, G. García, E. Pérez, J. Casabó, E. Molins and C. Miravitlles,Inorg. Chem. Acta,178, 213 (1990).

    Google Scholar 

  7. J. R. Doyle, P. E. Slade and H. B. Jonassen,Inorg. Synth.,6, 218 (1960).

    Google Scholar 

  8. P. Molina, M. Alajarín and F. J. Navarro,Heterocycles,24, 1031 (1986).

    Google Scholar 

  9. D. X. West and L. K. Pannell,Transition Met. Chem.,14, 457 (1989).

    Google Scholar 

  10. D. X. West, R. M. Makkever, G. Ertem, J. P. Skovill and L. K. Pannell,Transition Met. Chem.,11, 131 (1986).

    Google Scholar 

  11. D. X. West, G. Ertem, R. M. Makeever, J. P. Skovill and D. L. Klayman,Transition Met. Chem.,10, 41 (1985).

    Google Scholar 

  12. A. B. P. Lever,Inorganic Electronic Spectroscopy, Elsevier, Amsterdam, 1986, p. 544.

    Google Scholar 

  13. K. Nakamoto,Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley, New York, 1986, p. 324.

    Google Scholar 

  14. W. J. Geary,Coord. Chem. Rev.,7, 81 (1971).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Departamento de Química Inorgánica, Universidad de Murcia, 30071, Murcia, Spain

    Gregorio López, Gregorio Sánchez, Gabriel García & María J. Vidal

  2. Departamento de Ingeniería Química, E.U. Politécnica de Cartagena, Cartagena (Murcia), Spain

    Eduardo Pérez

Authors
  1. Gregorio López
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Gregorio Sánchez
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Gabriel García
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. María J. Vidal
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Eduardo Pérez
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

López, G., Sánchez, G., García, G. et al. 4-Amino-2,6-dimethyl-5-oxo-3-thioxo-2,3,4,5-tetrahydro-1,2,4-triazine palladium(II) complexes. Transition Met Chem 16, 469–471 (1991). https://doi.org/10.1007/BF01129467

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01129467

Keywords

Search

Navigation