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Transition metal ion complexes of thiosemicarbazones derived from 2-acetylpyridine. Part 9. The chemical and antifungal properties of the iron(III) and cobalt(II, III) complexes of 2-acetylpyridine4 N-diethyl-and4 N-diopropylthiosemicarbazones

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Summary

4 N-diethyl- and4 N-dipropylthiosemicarbazones of 2-acetylpyridine coordinate to FeIII, CoIII and CoII centres as tridentate NNS ligands. Spectral and physical data indicates that the size of the4 N-substituents can influence the stereochemistry and stoichiometry of the complexes, which show minimal ability to inhibit fungal growth and are considerably less active than the related copper(II) and nickel(II) complexes.

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Authors and Affiliations

  1. Department of Chemistry, Illinois State University, 61761, Normal, IL, USA

    Douglas X. West & Cinda S. Carlson

  2. Department of Biological Sciences, Illinois State University, 61761, Normal, IL, USA

    Anthony E. Liberta

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  1. Douglas X. West
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  2. Cinda S. Carlson
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  3. Anthony E. Liberta
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West, D.X., Carlson, C.S. & Liberta, A.E. Transition metal ion complexes of thiosemicarbazones derived from 2-acetylpyridine. Part 9. The chemical and antifungal properties of the iron(III) and cobalt(II, III) complexes of 2-acetylpyridine4 N-diethyl-and4 N-diopropylthiosemicarbazones. Transition Met Chem 16, 53–56 (1991). https://doi.org/10.1007/BF01127871

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  • DOI: https://doi.org/10.1007/BF01127871

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