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Transition metal ion complexes of theS-methyldithiocarbazate prepared from 2-acetylpyridineN-oxide

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Summary

Metal ion complexes of theS-methyldithiocarbazate of 2-acetylpyridineN-oxide, HONS, have been prepared and characterised by spectral and physical methods. Preparative ethanolic solutions on reflux yield complexes in which the deprotonated form of the ligand, ONS, is complexedvia itsN-oxide oxygen, azomethine nitrogen, and thione sulphur. Representative stoichiometries are as follows: [M(ONS)2]X (M=Fe3+, and X=ClO −4 , FeCl −4 or M=Co3+ and X=BF −4 ) and [M(ONS)X] (M=Co2+, Ni2+ and Cu2+ and X=Cl−, Br−). The i.r., electronic, and electron spin resonance spectra of the complexes are compared to analogous complexes of theX-methyldithiocarbazate of 2-acetylpyridine as well as the thiosemicarbazones of 2-acetylpyridineN-oxide.

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  1. Department of Chemistry, Illinois State University, 61761, Normal, IL, USA

    Douglas X. West & David L. Huffman

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  1. Douglas X. West
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West, D.X., Huffman, D.L. Transition metal ion complexes of theS-methyldithiocarbazate prepared from 2-acetylpyridineN-oxide. Transition Met Chem 14, 190–194 (1989). https://doi.org/10.1007/BF01043792

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