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Cationic carbonyl complexes of ruthenium(II) and osmium(II) containing 2,2′-bipyridyl and 1,10-phenanthroline

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Summary

Reactions of ruthenium carbonyl complexes of the type [RuX2(CO)(Ph2RAs)3] (X=Cl or Br; R=Me or Et) with 2,2′-bipyridyl (bipy) and 1,10-phenanthroline (phen) in alcohol produce orange red cationic products of the formula [RuX(CO)(N-N)(Ph2RAs)2]ClO4 (N-N=bipy or phen). Likewise, the hydridocarbonyls of ruthenium and osmium of the type [MHX(CO)(Ph2RAs)3] (M=Ru or Os) react with bipy and phen to yield yellow cationic complexes of the composition [(MH(CO)(N-N)(Ph2RAs)2]ClO4. Structures have been assigned to all the complexes on the basis of i.r. and1 H n.m.r. spectral data.

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Authors and Affiliations

  1. Department of Chemistry, Central College, Bangalore University, 560001, Bangalore, India

    K. G. S. Murthy, K. N. Mahendra, N. M. N. Gowda & G. K. N. Reddy

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  1. K. G. S. Murthy
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  2. K. N. Mahendra
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  3. N. M. N. Gowda
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  4. G. K. N. Reddy
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Murthy, K.G.S., Mahendra, K.N., Gowda, N.M.N. et al. Cationic carbonyl complexes of ruthenium(II) and osmium(II) containing 2,2′-bipyridyl and 1,10-phenanthroline. Transition Met Chem 10, 236–238 (1985). https://doi.org/10.1007/BF00692636

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  • DOI: https://doi.org/10.1007/BF00692636

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