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Kinetics of reduction of tris(4,4,4-trifluoro-1-(2-thienyl)-butane-1,3-dionato)ruthenium(III) in methanol

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Abstract

Reduction of tris(4,4,4-trifluoro-1-(2-thienyl)-butane-1,3-dionato) ruthenium(III) in methanol solution containing potassium hydroxide has been studied kinetically. The results suggest outer-sphere complex formation between ruthenium(III) species and methoxide anion.

Abstract

Исследовали кинетику восстановления комплекса (4,4,4-трифторо-1-(2-тионил)-бутандион-1,3)рутения(III) в метанольном растворе калиевой щелочи. На основе полученных результатов можно заключить, что во время реакции образуется промежуточный аддукт исследованного комплекса с метокси-ионом.

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Author notes

  1. R. Grobelny

    Present address: Department of Chemistry, Rivers State University Science and Technology, PMB 5080, Port-Harcurt, Nigeria

Authors and Affiliations

  1. Institute of Chemistry, University of Wroclaw, 50-383, Wroclaw, Poland

    R. Grobelny & B. Banaś

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  1. R. Grobelny
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  2. B. Banaś
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Grobelny, R., Banaś, B. Kinetics of reduction of tris(4,4,4-trifluoro-1-(2-thienyl)-butane-1,3-dionato)ruthenium(III) in methanol. React Kinet Catal Lett 24, 217–222 (1984). https://doi.org/10.1007/BF02093430

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  • DOI: https://doi.org/10.1007/BF02093430

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