Skip to main content
SpringerLink
Log in

Studies of the reasons for the deactivation of palladium(II)-nitrate catalytic systems

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

Studies of the reasons for the deactivation of palladium-nitrate catalytic systems indicate that this process is due to the formation of insoluble palladium complexes with side products of catalytic reactions, e.g. cyanide ion, oxalic and nitrolic acids. The deactivation is decreased by the addition of ions of transition metals Ru, Rh, Ni and Fe.

Abstract

Исследованы причины, приводящие к дезактивации палладий-нитратных каталитических систем. Установлено, что процесс дезактивации обусловлен образованием нерастворимых комплексов палладия с продуктами побочных окислительновосстановительных реакций, такими, как цианид-ион, щавелевая кислота и нитроловые кислоты. Показано, что введение в раствор ионов переходных металлов Ru, Rh, Ni и Fe приводит к замедлению процесса дезактивации.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. M. G. Volkhonskii, V. A. Likholobov, Yu. I. Yermakov: Kinet. Katal.,20, 362 (1979).

    Google Scholar 

  2. M. G. Volkhonskii, V. A. Likholobov, Yu. I. Yermakov: Kinet. Katal.,20, 367 (1979).

    Google Scholar 

  3. M. G. Volkhonskii, V. A. Likholobov, Yu. I. Yermakov: Kinet. Katal., (in press).

  4. M. G. Volkhonskii, V. A. Lukholobov, Yu. I. Yermakov: Kinet. Katal., (in press).

  5. R. Shrainer, R. C. Fuson: Systematic Qualitative Analysis of Organic Compounds, Inostr. Lit., Moskva 1950.

    Google Scholar 

  6. A. Guben-Weil: Methods of Organic Chemistry, pp. 630, 637. Goskhimizdat, Moskva 1963.

    Google Scholar 

  7. V. A. Likholobov, E. N. Yurchenko: Kinet. Katal.,18, 813 (1977).

    Google Scholar 

  8. B. Brightwait, D. Wright: Chem. Comm.,22, 1328 (1969).

    Google Scholar 

  9. V. A. Likholobov, Yu. I. Yermakov: Catalytic Nitration of Olefins, p. 81. Institut Kataliza, Novosibirsk 1972.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Catalysis, Novosibirsk, USSR

    M. G. Volkhonskii, V. A. Likholobov & Yu. I. Yermakov

Authors
  1. M. G. Volkhonskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. A. Likholobov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. I. Yermakov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Volkhonskii, M.G., Likholobov, V.A. & Yermakov, Y.I. Studies of the reasons for the deactivation of palladium(II)-nitrate catalytic systems. React Kinet Catal Lett 21, 213–218 (1982). https://doi.org/10.1007/BF02070613

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02070613

Keywords

Search

Navigation