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Cumene hydroperoxide decomposition reaction catalyzed by ruthenium(III)β-diketonates

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Abstract

Catalytic decomposition of cumene hydroperoxide (ROOH) in the presence of Ru(III) β-diketonates has been investigated. Activation of ROOH via outer sphere [ROOH]−[Ru] interaction has been proposed.

Abstract

Исследован каталитический распад гидроперекиси кумола в присутствии β-дикетонатов Ru(III). Найдено что активация ROOH происходит вследствие внешнесферного взаимодействия [ROOH] с [Ru(III)].

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Authors and Affiliations

  1. Institute of Chemistry, University of Wroclaw, 50-383, Wroclaw, Poland

    A. M. Trzeciak, R. Grobelny & J. J. Ziólkowski

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  1. A. M. Trzeciak
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  2. R. Grobelny
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  3. J. J. Ziólkowski
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Trzeciak, A.M., Grobelny, R. & Ziólkowski, J.J. Cumene hydroperoxide decomposition reaction catalyzed by ruthenium(III)β-diketonates. React Kinet Catal Lett 17, 121–125 (1981). https://doi.org/10.1007/BF02069527

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  • DOI: https://doi.org/10.1007/BF02069527

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