Abstract
A mathematical model of ignition and burning of organic polymers was used for evaluation and quantification of the tendency of polymers to ignition. The model permits investigation of the influence of one parameter of the polymer on the others. It was found that the model could be used for the verification of the ignitability method developed by Miller et al. [1].
Different steady states of combustion were found when using the model proposed. There is a characteristic steady state for normal flaming combustion, another for non-flaming combustion, and there are also unstable steady states that have no real physical meaning.
Similar content being viewed by others
References
B. Miller, R. Martin and R. Turner, J. Appl. Polym. Sci., 28 (1983) 45.
Comprehensive Chemical Kinetics, Vol. 17, Gas-phase Combustion, (Eds C. H. Bamford and C. F. H. Tipper), Elsevier P. H., Amsterdam-Oxford-New York 1977, p. 345.
A. Búcsi and J. Rychly, Polymer Degradation and Stability, 38 (1992) 33.
J. Rychly and L. Costa, Fire and Materials, 19 (1995) 215.
J. Rychly and L. Rychlá, Polymer Degradation and Stability, 54 (1996) 249.
J. Rychly and L. Rychlá, Fire and Materials, 10 (1986) 7.
Gy. Bazsa, Nonlinear dynamics and exotic kinetic phenomena in chemical systems (in Hungarian) Debrecen-Budapest-Gödöllő 1992.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Búcsi, A., Rychly, J. Ignitability of Polymers Related to Polymer Properties and Different Steady States of Combustion Theoretical Approach. Journal of Thermal Analysis and Calorimetry 55, 727–739 (1999). https://doi.org/10.1023/A:1010157011275
Issue Date:
DOI: https://doi.org/10.1023/A:1010157011275