Skip to main content
SpringerLink
Log in

Thermoanalytische Charakterisierung Strahlengehärteter Polymerfilme

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Thermo-oxidative and thermo-mechanical stabilities of radiation-cured acrylates and epoxides were examined by TG, DMA and DSC.

The polymeric trifunctional acrylates PETIA, TMPTA and THEIC displayed the highest temperatures of onset of degradation. The high crosslinking density of the films resulted in an almost temperature-independent complex E-modulus, as measured by DMA. With increasing degree of ethoxylation or propoxylation of the monomers, decreases in thermal stability and strength were found. For difunctional polymeric acrylates and epoxides, the glass transition temperature was measured.

The average degree of curing of UV-cured epoxy films can be determined from the temperature of the maximum in the loss modulus (E″max.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literatur

  1. P. G. Garratt, Strahlenhärtung, Vincentz-Verlag, Hannover 1996.

    Google Scholar 

  2. P. Holl, 7. UCB Radcure-Symposium, 12/13, 9, 1996, Bamberg.

    Google Scholar 

  3. A. Priola, G. Gozzelino, F. Ferrero und G. Malucelli, Polymer, 34 (1993) 3653.

    Google Scholar 

  4. A. Udagawa, F. Sakurai und T. Takahashi, J. Appl. Polymer Sci., 42 (1991) 1861.

    Google Scholar 

  5. G. Meichsner, F. Deuter, T. Gross, F. Beck und K. Menzel, Farbe + Lack, 103 (1997) 45.

    Google Scholar 

  6. H. Langguth und B. Hösselbarth, unveröffentlichte Ergebnisse.

  7. A. Zosel, Lack und Polmerfilme, Vincentz-Verlag, Hannover 1996.

    Google Scholar 

  8. W. König, Farbe + Lack, 65 (1959) 435, DIN 53 157, ISO 1522.

    Google Scholar 

  9. P. J.-M. Manus, Cationic UV Curable Coatings and Recent Applications, Rad. Tech. Europe Newsletter 1/1991.

  10. J. V. Koleske, Cationic Radiation Curing, Federation of Societies for Coatings Technology, USA, June 1991.

  11. A. Carroy, Rad. Tech. Europe (1991) 265.

  12. E. Bittmann and G. W. Ehrenstein, Plaste und Kautschuk, 41 (1994) 216.

    Google Scholar 

  13. G. Malucelli, G. Gozzelino, F. Ferrero, R. Bongiovanni und A. Priola, J. Appl. Polym. Sci., 65 (1997) 491.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institut für Oberflächenmodifizierung e. V., Permoserstraβe 15, D-04318, Leipzig, Deutschland

    B. Hösselbarth & K. Friese

  2. Umweltforschungszentrum Leipzig-Halle, Deutschland

    W. Geyer

Authors
  1. B. Hösselbarth
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. K. Friese
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. W. Geyer
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hösselbarth, B., Friese, K. & Geyer, W. Thermoanalytische Charakterisierung Strahlengehärteter Polymerfilme. Journal of Thermal Analysis and Calorimetry 52, 145–155 (1998). https://doi.org/10.1023/A:1010122525663

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1010122525663

Search

Navigation