Skip to main content
Log in

Investigation of the phase barograms and diagrams of the GeI4-I2, GeI4-BiI3 and GeI4-HgI2 systems

  • Published:
Journal of thermal analysis Aims and scope Submit manuscript

Abstract

The phase barograms of the systems GeI4-I2, GeI4-BiI3 and GeI4-HgI2 were determined by total pressure measurements in a membrane zero manometer and the resulting phase diagrams were compared with those obtained by DTA measurements. All the systems were single eutectics.

Zusammenfassung

Durch Gesamtdruckmessungen mittels eines Membrannullmanometers wurden Phasenbarogramme der Systeme GeI4-I2, GeI4-BiI3 und GeI4-HgI2 ermittelt und die resultierenden Phasendiagramme mit den an Hand von DTA-Messungen erhaltenen verglichen. Alle diese Systeme besitzen einen eutektischen Punkt.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R. Dworsky and K. L. Komarek, Mh. Chem., 101 (1970) 984.

    Google Scholar 

  2. H. Oppermann, Z. Anorg. Allg. Chemie, 578 (1989) 229.

    Google Scholar 

  3. H. Oppermann and K. Witte, Z. Anorg. Allg. Chemie, (in press)

  4. S. Maneglier-Lacordaire, J. Rivet and J. Flahaut, Ann. Chim., 10 (1975) 287.

    Google Scholar 

  5. H. Oppermann, Z. Anorg. Allg. Chemie, 504 (1983) 95.

    Google Scholar 

  6. R. Hillel and J. Bouix, Z. Anorg. Allg. Chemie, 552 (1987) 221.

    Google Scholar 

  7. V. N. Chernyaev, N. J. Chetverikov, V. K. Khernzhitskij and E. Koak, Izv. Akad. Nauk SSSR, Neorg. Mat., 4 (1968) 720.

    Google Scholar 

  8. J. Barin, O. Knacke and O. Kubaschewski, Thermochemical properties of inorganic substances, Supplement, Springer-Verlag, Berlin 1977.

    Google Scholar 

  9. H. Oppermann and W. Ludwig, Z. Anorg. Allg. Chemie, (in press)

  10. V. P. Gluschko (Hrsg.), Termitscheskije Konstanti Weschtschestw III, Moskau, Akad. Nauk. SSSR 1968.

    Google Scholar 

  11. J. B. Sladkok, Russ. J. Phys. Chem., 48 (1974) 1117.

    Google Scholar 

  12. E. L. Dolgov, G. P. Lokot, B. S. Vasilina and V. J. Kuskma, Dokl. Nauk. Soobshich, L'vev Politekh., 12 (1974) 126.

    Google Scholar 

  13. O. Kubaschewski and C. B. Alcock, Metallurgical Thermochemistry, Pergamon Press, 5th Edition, 1977.

  14. S. Witter, Dipl. Thesis, TUD, 1990.

  15. S. J. Yosim, L. D. Ransom, R. L. Sollach and L. W. Topol, J. Phys. Chem., 66 (1962) 28.

    Google Scholar 

  16. M. Piechotka and E. Kaldis, J. Less-Common Met., 115 (1986) 315.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Dedicated to Prof. Dr. H. J. Seifert on the occasion of his 60th birthday

We express our thanks to Mrs. Dr. U. Stahlberg, who carried out the analyses at the MS 7 in the ZFW Dresden

Rights and permissions

Reprints and permissions

About this article

Cite this article

Oppermann, H., Witter, S. & Ludwig, W. Investigation of the phase barograms and diagrams of the GeI4-I2, GeI4-BiI3 and GeI4-HgI2 systems. Journal of Thermal Analysis 37, 1441–1453 (1991). https://doi.org/10.1007/BF01913480

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01913480

Keywords

Navigation