Abstract
The paper offers three applications of nuclear methods in the research of chemical structure. First, progress in positron annihilation spectroscopy is illustrated by a positron beamline study, which obtained results that are not available through conventional experiments. The positron beam was used for the study of Langmuir-Blodgett (LB) films containing 4-58 layers of arachidic acid and its salts. These measurements have shown that this emerging technique is capable of characterizing even such elusive systems. Second, the potential of Mössbauer spectroscopy to answer current challenges of solid state chemistry are shown in a study on perovskites of recent interest. 151Eu Mössbauer spectroscopy was used to study the effect of Pr substitution in EuBa2Cu3O7-δ. It was shown that the introduction of Pr into the rare earth site as well as into the Ba site results in the appearance of extra electrons both in the copper oxide planes and at the 4f shell of Eu cations. The observed effects were explained by the hole filling effect of Pr. Finally, a survey is presented on the recently developed techniques for nuclear resonant scattering of synchrotron radiation, an exciting and very rapidly developing extension to conventional Mössbauer spectroscopy. An interesting new result is that nuclear inelastic scattering experiments performed on solutions of 57Fe complexes show contribution from vibrations rather than from diffusion to the inelastic spectra.
Similar content being viewed by others
References
P. J. Schultz, K. G. Lynn, Rev. Mod. Phys., 60 (1988) 701.
A. Van Veen, A. C. Kruseman, H. Schut, P. E. Mijnarends, B. J. Kooi, J. Th. M. Hosson, Mat. Sci. For., 255 (1997) 76.
W. Brandt, S. Berko, W. W. Walker, Phys. Rev., 120 (1960) No. 4, 1289.
V. J. Ghosh, Appl. Surf. Sci., 85 (1995) 187.
A. Van Veen, H. Schut, J. de Vries, R. A. Hakvoort, M. R. Ijpma, in: Slow Positron Beams for Solids and Surfaces, P. J. Schultz, G. R. Massoumi and P. J. Simpson (Eds), Am. Inst. Phys., New York, 1990, p. 171.
I. Langmuir, K. Blodgett, Kolloid-Z., 73 (1935) 257.
G. G. Roberts, Adv. Phys., 34 (1985) No. 4, 475.
D. Brandl, Ch. Schoppmann, Ch. Tomaschko, M. Schurr, H. Voit, Thin Solid Films, 256 (1995) 220.
T. Marek, Cs. Szeles, É. Kiss, A. VÉrtes, K. G. Lynn, Mat. Sci. For., 255–257 (1997) 686.
R. L. MÖssbauer, Z. Phys., 151 (1958) 124.
A. VÉrtes, L. Korecz, K. Burger, Mössbauer Spectroscopy, Elsevier, Amsterdam, 1979.
J. G. Bednorz, K. A. MÜller, Z. Phys., B 64 (1986) 189.
W. Chu, J. Bechtold, L. Gao, P. H. Hor, Z. J. Huang, R. L. Meng, Y. Y. Sun, Y. Q. Wang, Y. Y. Xue, Phys. Rev. Lett., 60 (1988) 941.
H. Maeda, Y. Tanaka, M. Fukutomi, T. Asano, Japan J. Appl. Phys. Lett., 27 (1988) 209.
Z. Z. Sheng, A. M. Hermann, Nature, 332 (1988) 55.
Z. Iqbal, T. Datta, D. Kirven, A. Longu, J. C. Barry, F. J. Owens, A. G. Rinzler, D. Yang, F. Reidinger, Phys. Rev., B 49 (1994) 12322.
C. P. Poole, H. A. Farach, R. J. Creswick, Superconductivity, Academic Press, New York, London, 1995.
M. Guillaume, P. Allenspach, W. Henggeler, J. Mesot, B. Roessli, U. Staub, P. Fischer, A. Furrer, V. Trounov, J. Phys. Condens. Matter, 6 (1994) 7963.
W. Y. Guan, Y. C. Chen, J. Y. T. Wei, Y. H. Xu, M. K. Wu, Physica, C 209 (1993) 19.
K. Latka, A. Szytula, Z. Tomkowicz, A. Zygmunt, R. Duraj, Physica, C 171 (1990) 287.
D. Khomskii, Physica, B 199/200 (1994) 328.
G. Wortmann, I. Felner, Solid State Comm., 75 (1990) 981.
L. Soderholm, K. Zhang, D. G. Hinks, M. A. Beno, J. D. Jorgensen, C. U. Segre, I. K. Schuller, Nature, 328 (1987) 604.
D. P. Norton, D. H. Lowndes, B. C. Sales, J. D. Budai, B. C. Chakoumakos, H. R. Kerchner, Phys. Rev. Lett., 66 (1991) 1537.
R. Fehrenbacher, T. M. Rice, Phys. Rev. Lett., 70 (1993) 3471.
H. A. Blackstead, J. D. Dow, Phys. Rev. B, 51 (1995) No. 17, 11830.
H. A. Blackstead, J. D. Dow, D. B. Chrisey, J. S. Horwitz, M. A. Black, P. J. McGinn, A. E. Klunzinger, D. B. Pulling, Phys. Rev., B 54 (1996) 6122.
Z. Zou, K. Oka, T. Ito, Y. Nishihara, Japan J. Appl. Phys., 36 (1997) L18.
Z. Zou, Y. Nishihara, Phys. Rev. Lett., 82 (1999) 462.
V. N. Narozhnyi, S.-L. Drechsler, Phys. Rev. Lett., 82 (1999) 461.
Z. KlencsÁr, E. Kuzmann, Z. Homonnay, A. VÉrtes, K. Vad, J. BÁnkuti, T. RÁcz, M. BÓdog, I. Kotsis, Physica, C 304 (1998) 124.
Y. T. Ren, Y. Y. Xue, Y. Y. Sun, C. W. Chu, Physica, C 213 (1993) 224.
M. Park, M. J. Kramer, K. W. Dennis, R. W. McCallum, Physica, C 259 (1996) 43.
Z. Tomkowicz, K. Latka, A. Szytula, A. Bajorek, M. Balanda, R. Kmiec, R. Kruk, A. Zygmunt, Physica, C 174 (1991) 71.
Z. M. Stadnik, G. Stroink, T. Arakawa, Phys. Rev., B 44 (1991) 12552.
G. Wortmann, S. BlumenrÖder, A. Freimuth, D. Riegel, Physics Lett., A 126 (1988) 434.
I. Felner, I. Nowik, Supercond. Sci. Technol., 8 (1995) 121.
M. Eibschutz, D. W. Murphy, S. Sunshine, L. G. Van Uitert, S. M. Zahurak, W. H. Grodkiewicz, Phys. Rev., B 35 (1987) 8714.
D. H. Ha, Physica, C 302 (1998) 299.
M. J. Kramer, K. W. Dennis, D. Falzgraf, R. W. McCallum, S. K. Malik, W. B. Yelon, Phys. Rev., B 56 (1997) 5512.
Z. Xu, W. Yu, X. Zhang, Y. Ren, Z. Jiao, Q. Zhang, Physica, C 282–287 (1997) 1197.
G. Nieva, S. Ghamaty, B. W. Lee, M. B. Maple, I. K. Schuller, Phys. Rev., B 44 (1991) 6999.
A. A. Moolenar, P. C. M. Gubbens, J. J. Van Loef, M. J. V. Menken, A. A. Menovsky, Physica, C 267 (1996) 279.
Z. KlencsÁr, E. Kuzmann, A. VÉrtes, P. C. M. Gubbens, A. M. Van Der Kraan, M. BÓdogh, I. Kotsis, Phys. Rev. Lett., Submitted for publication.
A list of synchrotron beamlines appropriate for nuclear resonant scattering experiments is available at the following URL: http://www.kfki.hu/~mixhp/mossba.htm#nrs.
E. Gerdau, R. RÜffer, H. Winkler, W. Tolksdorf, C. P. Klages, J. P. Hannon, Phys. Rev. Lett., 54 (1985) 835.
G. V. Smirnov, Hyp. Int., 97/98 (1996) 551 and references therein.
D. L. Nagy, V. V. Pasyuk, Hyp. Int., 71 (1992) 1349.
L. DeÁk, L. BottyÁn, D. L. Nagy, H. Spiering, Phys. Rev., B53 (1996) 6158.
D. L. Nagy, L. BottyÁn, L. DeÁk, J. Dekoster, G. Langouche, V. G. Semenov, H. Spiering, E. SzilÁgyi, in: M. Miglierini, D. Petridis (Eds), Mössbauer Spectroscopy in Materials Sciences, NATO Science Series: High Technology, Vol. 66, Kluwer, Boston, 1999, p.323.
I. DeÁk, L. BottyÁn, D. L. Nagy, Hyp. Int., 92 (1994) 1083.
D. L. Nagy, L. BottyÁn, L. DeÁk, E. Gerdau, V. N. Gitisovich, J. Korecki, O. Leupold, H. Reuther, V. G. Semenov, E. SzilÁgyi, in: Condensed Matter Studies by Nuclear Methods, Proc. XXXII Zakopane School on Physics, E. A. GÖrlich and K. Latka (Eds), Institute of Physics, Jagellonian University and the Niewodniczanski Institute of Nuclear Physics, Cracow, 1997, p. 17.
L. BottyÁn, J. Dekoster, L. DeÁk, A. Q. R. Baron, S. Degroote, R. Moons, D. L. Nagy, G. Langouche, Hyp. Int., 113 (1998) 295.
R. Coussement, S. Cottenier, C. L'AbbÉ, Phys. Rev., B 54 (1996) 16003.
J. Odeurs, R. Coussement, C. L'AbbÉ, G. Neyens, G. R. Hoy, E. E. Alp, W. Sturhahn, T. Toellner, C. Johnson. Hyperfine Interactions, 113 (1998) 455.
G. V. Smirnov, U. Van BÜrck, A. I. Chumakov, A. Q. R. Baron, R. RÜffer, Phys. Rev., B 55 (1997) 5811.
M. Seto, Y. Yoda, S. Kikuta, M. Ando, Phys. Rev. Lett., 74 (1995) 3828.
A. I. Chumakov, R. RÜffer, Hyp. Int., 113 (1998) 59.
W. Sturhahn, T. S. Toellner, E. E. Alp, X. Zhang, M. Ando, Y. Yoda, S. Kikuta, M. Seto, C. W. Kimball, B. Dabrowski, Phys. Rev. Lett., 74 (1995) 3832.
A. I. Chumakov, R. RÜffer, A. Q. R. Baron, H. GrÜnsteudel, H. F. GrÜnsteudel, V. G. Kohn, Phys. Rev., B 56 (1997) 10758.
V. G. Kohn, A. I. Chumakov, R. RÜffer, Phys. Rev., B 58 (1998) 8437.
H. Paulsen, H. Winkler, A. X. Trautwein, H. GrÜnsteudel, V. Rusanov, H. Toftlund, Phys. Rev., B 59 (1999) 975.
A. VÉrtes, D. L. Nagy, Mössbauer Spectroscopy of Frozen Solutions. Akadémiai Kiadó, Budapest, 1990.
X. Zhang, Y. Yoda, M. Seto, Y. Maeda, M. Ando, S. Kikuta, Japan J. Appl. Phys., 34 (1995) 330.
F. Sette, G. Ruocco, M. Kirsch, U. Bergmann, C. Masciovecchio, V. Mazzacurati, G. Signorelli, R. Verbeni, Phys. Rev. Lett., 75 (1995) 850.
A. I. Chumakov, A. Q. R. Baron, R. RÜffer, H. GrÜnsteudel, H. F. GrÜnsteudel, Phys. Rev., B 54 (1996) 9596.
L. BottyÁn, D. L. Nagy, E. SzilÁgyi, Gy. VankÓ, A. VÉrtes, to be published.
A. I. Chumakov, A. Q. R. Baron, R. RÜffer, H. GrÜnsteudel, H. F. GrÜnsteudel, A. Meyer, Phys. Rev. Lett., 76 (1996) 4258.
A. Q. R. Baron, H. Franz, A. Meyer, R. RÜffer, A. I. Chumakov, E. Burkel, W. Petry, Phys. Rev. Lett., 79 (1997) 2823.
A. SzÖke, in: Short Wavelength Coherent Radiation: Generation and Applications, D. T. Attwood, J. Bokor (Eds), AIP Conf. Proc. No. 147, AIP, New York, 1986.
G. R. Harp, D. K. Saldin, B. P. Tonner, Phys. Rev. Lett., 65 (1990) 1012.
D. K. Saldin, P. L. De Andres, Phys. Rev. Lett., 64 (1990) 1270.
M. Tegze, G. Faigel, Europhys. Lett., 16 (1991) 41.
M. Tegze, G. Faigel, Nature (London), 380 (1996) 49.
M. Tegze, G. Faigel, Phys. Rev. Lett., 82 (1999) 4847.
P. Koreczki, J. Koreczki, T. Slezak, Phys. Rev. Lett., 79 (1997) 3518.
P. Koreczki, J. Koreczki, W. Karas, Phys. Rev., B 59 (1999) 6139.
C. L'AbbÉ et al., in: Proc. XXXIV Zakopane School on Physics (Condensed Matter Studies by Nuclear Methods), in print.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Vértes, A., Klenesár, Z., Vankó, G. et al. Nuclear Techniques in the Elucidation of Chemical Structure. Journal of Radioanalytical and Nuclear Chemistry 243, 241–253 (2000). https://doi.org/10.1023/A:1006716708476
Issue Date:
DOI: https://doi.org/10.1023/A:1006716708476