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Mössbauer study on tris(1,10-phenanthroline) iron(II) ion synthesized in zeolite Y and its pyrolysis products

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Abstract

Tris(1,10-phenanthroline) iron(II) ([Fe(phen)3]2+) ion synthesized in the supercage of zeolite Y has been characterized by Mössbauer, UV-VIS reflectance, and X-ray diffraction methods. The complex in the supercage may be significantly distorted by interaction between the complex and the supercage wall. Pyrolysis mechanism under air of the complex in the supercage was studied on the basis of Mössbauer spectra.

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Authors and Affiliations

  1. Department of Chemistry, School of Science, University of Tokyo, 113, Hongo, Tokyo, Japan

    Y. Umemura, Y. Minai & T. Tominaga

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  1. Y. Umemura
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  2. Y. Minai
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  3. T. Tominaga
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Umemura, Y., Minai, Y. & Tominaga, T. Mössbauer study on tris(1,10-phenanthroline) iron(II) ion synthesized in zeolite Y and its pyrolysis products. Journal of Radioanalytical and Nuclear Chemistry Letters 186, 213–226 (1994). https://doi.org/10.1007/BF02162752

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  • DOI: https://doi.org/10.1007/BF02162752

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