Skip to main content
SpringerLink
Log in

GC-FTIR-MS analysis of volatile radiolysis products of nitrophenol solutions in carbon tetrachloride

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

Capillary gas chromatography — Fourier transform infrared spectroscopy combined with capillary gas chromatography — mass spectrometry is employed for the analysis of major volatile products in the γ-radiolysis of isomeric nitrophenol solutions in carbon tetrachloride. Isomeric di- and trichlorophenols, chloronitrophenols and dichloroisocyanatobenzenes in addition to those formed with m- and p-isomers, are among the important products formed in the solution of o-nitrophenol in carbon tetrachloride. Formation of dichloroisocyanatobenzene is explained by the interaction of dichlorocarbene with the nitro group followed by the ipso-substitution of OH and H atom by chlorine atom.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Radiolysis and Photolysis of Nitroaromatic Compounds-Halogenoalkane Mixtures, Part IX, Part VIII, J. Kuruc, M.K. Sahoo, R. Kubinec,Chromatographia, (in press).

  2. J. Rais, P. Selucký, M. Kyrš,J. Inorg. Chem., 38 (1976) 1376.

    Google Scholar 

  3. S. Čechová, F. Macášek,J. Radioanal. Nucl. Chem., Articles, 149 (1991) 281.

    Google Scholar 

  4. R. Čech, H. Chrenčiková, V. Širáňová, J. Kuruc, F. Macášek,J. Radioanal. Nucl. Chem., Lett. 86 (1984) 337.

    Google Scholar 

  5. J. Kuruc, M.K. Sahoo, P. Kuráň,Chromatographia (in press).

  6. J. Kuruc, M.K. Sahoo,J. Radioanal. Nucl. Chem., Articles, (in press).

Download references

Author information

Authors and Affiliations

  1. Department of Nuclear Chemistry Faculty of Natural Sciences, Comenius University, CS-84215, Bratislava, Slovakia

    J. Kuruc & M. K. Sahoo

  2. Institute of Chemistry, Faculty of Natural Sciences, Comenius University, CS-84215, Bratislava, Slovakia

    P. Kuráň & R. Kubinec

Authors
  1. J. Kuruc
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. K. Sahoo
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. P. Kuráň
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. R. Kubinec
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

This paper constitutes part of the Ph.D. thesis of M.K. Sahoo and was presented at the 10th conference on “Chromatographic method and its significance for human health” with international participation, Stará Lesná, High Tatras, Slovakia, Nov. 4–6, 1992.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kuruc, J., Sahoo, M.K., Kuráň, P. et al. GC-FTIR-MS analysis of volatile radiolysis products of nitrophenol solutions in carbon tetrachloride. Journal of Radioanalytical and Nuclear Chemistry Letters 175, 359–370 (1993). https://doi.org/10.1007/BF02164038

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02164038

Keywords

Search

Navigation