Skip to main content
Log in

Radiolysis of water-nitrobenzene-carbon tetrachloride and water-chlorobenzene-carbon tetrachloride two-phase systems. Radiation yields of chloride ions

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

The influence of nitrobenzene and chlorobenzene on the total radiation yield of chloride ions in the γ-irradiation of water-carbon tetrachloride two-phase systems has been determined. Nitrobenzene at small concentrations shows a pronounced protective influence on the radiation destruction of carbon tetrachloride. Similar protective effect on the destruction of carbon tetrachloride is shown by chlorobenzene, too, but the decrease of radiation yields of chloride ions is smoother, which is explained by radiation decomposition of chlorobenzene itself. Protective effect of nitrobenzene and chlorobenzene on the radiation destruction of carbon tetrachloride is explained by transfer of energy from carbon tetrachloride molecules to the aromatic molecules.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Radiolysis and photolysis of nitroaromatic compounds haloalkane mixtures. Part 5. Part 4, M.K. Sahoo, J. Kuruc, A. Švec, R. Čech, M. Hutta,J. Radioanal. Nucl. Chem., Articles, 163 (1992) 131.

    Google Scholar 

  2. R. Čech, H. Chrenčiková, V. Širánová, J. Kuruc, F. Macášek,J. Radioanal. Nucl. Chem., Lett., 86 (1984) 337.

    Google Scholar 

  3. J. Kuruc, R. Čech,Radiochem. Radioanal. Lett., 57 (1983) 169.

    Google Scholar 

  4. J. Kuruc,J. Radioanal. Nucl. Chem., Articles, 82 (1984) 93.

    Google Scholar 

  5. R. Čech, F. Macášek, L. Mátel, J. Kuruc, P. Račay, Radiation stability of solutions of dicarbollide of cobalt (III) in two-phase systems. In: Research in reprocessing of irradiated fuel and disposal of radioactive wastes. 6th Symposium of COMECOM. Czechoslov. Atom. Energy Commis. Piestany, 1985, Preprint (in Russian).

    Google Scholar 

  6. J. Kuruc, A. Hlatká, R. Čech,Radiat. Phys. Chem., 28 (1986) 467.

    Google Scholar 

  7. J. Kuruc, A. Hlatká,J. Radioanal. Nucl. Chem., Lett., 166 (1992) 139.

    Google Scholar 

  8. A.K. Pikayev, Dosimetry in Radiation Chemistry, Nauka, Moscow, 1975, p. 150 (in Russian).

    Google Scholar 

  9. F. Macášek, R. Čech,Radiat. Phys. Chem., 23 (1984) 473.

    Google Scholar 

  10. I. Dvornik, U. Zec, A. Anic, F. Ranogajec, Solid State and Chemical Dosimetry in Medicine and Biology, Wien, IAEA, 1967, p. 273.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kuruc, J., Hlatká, A. Radiolysis of water-nitrobenzene-carbon tetrachloride and water-chlorobenzene-carbon tetrachloride two-phase systems. Radiation yields of chloride ions. Journal of Radioanalytical and Nuclear Chemistry Letters 166, 251–260 (1992). https://doi.org/10.1007/BF02164748

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02164748

Keywords

Navigation