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Preparation and characterization of bis(acetonitrile)bis(acetylacetonato)technetium(III)

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Abstract

A new chemical species of bis(acetonitrile)bis(acetylacetonato)technetium(III), [Tc(acac)2(CH3CN)2]+, has been prepared by the reaction of tris(acetylacetonato)technetium(III) with acetonitrile in the presence of a strong acid, perchloric or hydrochloric acid. The reaction kinetics were followed by observing spectral change of Tc(acac)3 in the UV-visible region. The complex has been characterized by combination of elemental analyses, IR and UV-visible spectrophotometry, ion-exchange chromatography, and paper electrophoresis. Applicability of this substance to synthesize mixed-ligand technetium(III) complexes was discussed based on the solubility of this complex and the ease of substitution of the acetonitrile ligand.

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References

  1. D. Banarjea, S. Sarkar,J. Indian Chem. Soc., 50 (1973) 635.

    Google Scholar 

  2. H. Ogino, Y. Abe, M. Shoji,Inorg. Chem., 27 (1988) 986.

    Google Scholar 

  3. Y. Kasahara, Y. Hoshino, K. Shimizu, G.P. Sato,Chem. Lett. (1990) 381.

  4. G.A. Lawrence,Adv. Inorg. Chem., 34 (1989) 145.

    Google Scholar 

  5. T.R. Carroll, A. Davison, A.G. Jones, Technetium in Chemistry and Nuclear Medicine Vol. 2 (Eds by M. Nicolini, G. Bandoli, U. Mazzi), Raven Press, New York (1986) p. 169.

    Google Scholar 

  6. M.J. Abrams, A. Davison, A. Jones, C.E. Costello,Inorg. Chim. Acta, 77 (1983) L235.

    Google Scholar 

  7. D.A. Thornton,Coord. Chem. Rev., 104 (1990) 173.

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Tohoku University, Aoba-ku, 980, Sendai, Japan

    A. Mutalib & K. Yoshihara

  2. Department of Chemistry, Faculty of Science, Shizuoka University, 422, Ohtani, Shizuoka, Japan

    T. Omori

Authors
  1. A. Mutalib
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  2. T. Omori
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  3. K. Yoshihara
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Mutalib, A., Omori, T. & Yoshihara, K. Preparation and characterization of bis(acetonitrile)bis(acetylacetonato)technetium(III). Journal of Radioanalytical and Nuclear Chemistry Letters 165, 19–25 (1992). https://doi.org/10.1007/BF02166816

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  • DOI: https://doi.org/10.1007/BF02166816

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