Abstract
Concentrations of sulfur gases H2S and SO2 have been measured in the marine atmosphere over the Atlantic Ocean at various sites. Mean values of 40 ng H2S m-3 STP and 209 ng SO2 m-3 STP are the results of the measurements. A diurnal variation of H2S concentration was detected on the west coast of Ireland with nighttime concentrations of up to 200 ng H2S m-3 STP and values below detection limit (15 ng H2S m-3 STP) during daytime.
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Adams D. F., Farwell S. O., Robinson E., Merrill P. R., and Bamesberger W. L., 1981, Biogenic sulfur source strengths, Environ. Sci. Tech. 15, 1493–1498.
Barnard W. R., Andreae M. O., Watkins W. E., Bingemer H., and Georgii H. W., 1982, The flux of dimethylsulfide from the oceans to the atmosphere, J. Geophys. Res. 87, 8787–8794.
Berresheim H. and Jaeschke W., 1983, The contribution of volcanoes to the global atmospheric sulfur budget, J. Geophys. Res. 88, 3732–3740.
Cadle R. D., 1976, The photo oxidation of hydrogen sulphide and dimethyl sulphide in air', Atmos. Environ. 10, 417.
Cox, R. A., 1975, Atmospheric photo-oxidation reactions, the gasphase reaction of OH-radicals with some sulphur compounds, AERE-Report 8132.
Delmas R., Baudet J., and Servant J., 1980, Emissions and concentrations of H2S in the air of tropical forest of the Ivory Coast and of temperate regions (France), J. Geophys. Res. 85, 4468–4474.
Delmas R. and Servant J., 1982, The origins of sulfur compounds in the atmosphere of a zone of high productivity (Gulf of Guinea), J. Geophys. Res. 87, 19–26.
Eriksson E., 1963, The yearly circulation of sulfure in nature, J. Geophys. Res. 68, 4003.
Farwell S. O., Sherrard A. E., Pack M. E., and Adams D. F., 1979, Sulfur compounds volatilized from soils at different moisture contents, Soil. Biol. Biochem. 11, 411–415.
Goldberg A. B., Maroulis P. J., Wilner L. A. and Bandy A. R., 1981, Study of H2S emissions from a salt water marsh', Atmos. Environ. 15, 11–18.
Graedel T. E., 1979, Reduced sulfur emissions from the open oceans, Geophys. Res. Lett. 6, 329–331.
Granat, L. Rodhe, H., and Hallberg, R. O., 1976, The global sulfur cycle, in: Svenson, B. H. and Soederlund, R. (eds.), Nitrogen, Phosphorus and Sulfur-Global Cycles, SCOPE Report 7 Ecol. Bull., Stockholm, 22, pp. 89–134.
Hansen M. H., Ingvorsen K., and Jorgensen B. B., 1978, Mechanisms of hydrogen sulfide release from coastal marine sediments to the atmosphere, Limnol. Oceanogr. 23, 68–76.
Ingvorsen K. and Jorgensen B. B., 1982, Seasonal variation in H2S emission to the atmosphere from intertidal sediments in Denmark, Atmos. Environ. 16, 855–865.
Jaeschke W., Georgii H. W., Claude H., and Malewski H., 1978, Contributions of H2S to the atmospheric sulfur cycle, Pageoph 116, 1–11.
Jaeschke W., Claude H., and Herrmann J., 1980, Sources and sinks for atmospheric H2S, J. Geophys. Res. 85, 5639–5644.
Jaeschke W. and Herrmann J., 1981, Measurements of H2S in the atmosphere, Int. J. Environ. Anal. Chem. 10, 107–120.
Lovelock J. E., 1974, CS2 and the natural sulphur cycle, Nature 248, 625–626.
Meixner F. X. and Jaeschke W., 1981, The detection of lower atmospheric SO2 concentrations with a chemiluminescence technique, Int. J. Environ. Anal. Chem. 10, 51–67.
Ockelmann, G., 1981, SO2 measurements over the Arctic and Atlantic Ocean, IAMAP Symposium on the Role of Oceans in Atmospheric Chemistry, Hamburg, submitted to J. Geophys. Res.
Twomey S., 1977, Atmospheric Aerosols, Developments in Atmospheric Sciences Vol. 7, Elsevier, New York, p. 18.
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Herrmann, J., Jaeschke, W. Measurements of H2S and SO2 over the Atlantic Ocean. J Atmos Chem 1, 111–123 (1984). https://doi.org/10.1007/BF00053834
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DOI: https://doi.org/10.1007/BF00053834