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Structure and Kinetics of Desolvation of 2-Hexanone Inclusion Compounds of the Hexapedal Hosts, Hexakis(3-hydroxy-3,3-diphenyl-2-propynyl)benzene and 1,2,3,5,6,7-Hexakis(3-hydroxy-3,3-diphenyl-2-propynyl)naphthalene

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Abstract

The 2-hexanone inclusion compounds of hexakis(3-hydroxy-3,3-diphenyl-2-propynyl)benzene and 1,2,3,5,6,7-hexakis(3-hydroxy-3,3-diphenyl-2-propynyl)naphthalene have been prepared and characterised by single crystal X-ray diffraction and thermal analysis. The kinetic parameters and mechanisms for the desolvation reaction have also been determined for both compounds.

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Authors and Affiliations

  1. Department of Chemistry, University of Cape Town, Rondebosch, 7701, South Africa

    Susan A. Bourne & Katherine L Gifford Nash

  2. Department of Applied Chemistry, Faculty of Engineering, Ehime University, Matsuyama, 790, Japan

    Fumio Toda

Authors
  1. Susan A. Bourne
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  2. Katherine L Gifford Nash
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  3. Fumio Toda
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Bourne, S.A., Nash, K.L.G. & Toda, F. Structure and Kinetics of Desolvation of 2-Hexanone Inclusion Compounds of the Hexapedal Hosts, Hexakis(3-hydroxy-3,3-diphenyl-2-propynyl)benzene and 1,2,3,5,6,7-Hexakis(3-hydroxy-3,3-diphenyl-2-propynyl)naphthalene. Journal of Inclusion Phenomena 34, 169–187 (1999). https://doi.org/10.1023/A:1008051903290

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  • DOI: https://doi.org/10.1023/A:1008051903290

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