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1H NMR spectroscopic study of the interaction between cyclodextrins and bicyclo[3.3.1]nonanes

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Abstract

The formation and structure of inclusion complexes of 2,6- and 2,9-substituted bicyclo[3.3.1]nonanes withα- andβ-cyclodextrin (CD) has been investigated by high-resolution1H NMR spectroscopy.α- andβ-CD were found to form 1:1 inclusion complexes and the binding constants were estimated from titration studies. 2D ROESY experiments provided insight into the structure of the complexes.

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Authors and Affiliations

  1. Department of Organic Chemistry of Vilnius University, Naugarduko 24, 2006, Vilnius, Lithuania

    Eugenius Butkus

  2. High-Resolution NMR Centre, Room 9G621, Vrije Universiteit Brussel, Pleinlaan 2, 1050, Brussel, Belgium

    José C. Martins

  3. Organic Chemistry 1, Chemical Center, University of Lund, P.O. Box 124, S-22100, Lund, Sweden

    Ulf Berg

Authors
  1. Eugenius Butkus
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  2. José C. Martins
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  3. Ulf Berg
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Butkus, E., Martins, J.C. & Berg, U. 1H NMR spectroscopic study of the interaction between cyclodextrins and bicyclo[3.3.1]nonanes. J Incl Phenom Macrocycl Chem 26, 209–218 (1996). https://doi.org/10.1007/BF01053539

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  • DOI: https://doi.org/10.1007/BF01053539

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