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Structure and spectroscopic properties of cyclodextrin inclusion complexes

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Abstract

We compare spectroscopic properties of higher order complexes of organic guests (e.g. naphthalene, phenols, indole, C60 fullerene) with cyclodextrins (CDx) to results of molecular modeling investigations. Naphthalene 1:2 complexes with α-CDx show high spectral resolution and peculiar triplet properties. Molecular simulations and calculation of the experimentally measured induced circular dichroism (ICD) provide detailed structural information.

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References

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Authors and Affiliations

  1. Institute for Theoretical Chemistry and Radiation Chemistry, University of Vienna, Althanstraße 14, 1090, Vienna, Austria

    G. Köhler, G. Grabner, C. TH. Klein, B. Mayer, K. Rechthaler & P. Wolschann

  2. Italian Council for Research (CNR), Institute of Photochemistry and High Energy Radiation, Via P. Gobetti 101, 40129, Bologna, Italy

    G. Marconi & S. Monti

  3. Polish Academy of Sciences, Institute for Physical Chemistry, Kasprzaka 44-52, PL-01-224, Warsaw, Poland

    K. Rotkiewicz

  4. University of Vienna, Institute for Pharmaceutical Technology, Althanstraβe 14, 1090, Vienna, Austria

    H. Viernstein

Authors
  1. G. Köhler
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  2. G. Grabner
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  3. C. TH. Klein
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  4. G. Marconi
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  5. B. Mayer
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  6. S. Monti
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  7. K. Rechthaler
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  8. K. Rotkiewicz
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  9. H. Viernstein
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  10. P. Wolschann
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Köhler, G., Grabner, G., Klein, C.T. et al. Structure and spectroscopic properties of cyclodextrin inclusion complexes. J Incl Phenom Macrocycl Chem 25, 103–108 (1996). https://doi.org/10.1007/BF01041546

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  • DOI: https://doi.org/10.1007/BF01041546

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