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57Fe Mössbauer spectra and spin-crossover behavior of [Fe(mbpN)(lut)]BPh4

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Abstract

New spin-crossover complexes [Fe(III)L(lut)]BPh4 (L = mbpN or bpN) with N4O2 moiety are reported. The structure of the mbpN (N3O2 quinquedentate ligand) complex is determined at 293 K, and the temperature dependences of the57Fe Mössbauer spectra and magnetic susceptibilities for both complexes have been examined.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki, Higashiku, 812, Fukuoka, Japan

    Y. Maeda, Y. Noda, H. Oshio & Y. Takashima

  2. Department of Chemistry, Faculty of Science, Tohoku University, Aoba, Aramaki, 980, Sendai, Japan

    H. Oshio

Authors
  1. Y. Maeda
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  2. Y. Noda
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  3. H. Oshio
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  4. Y. Takashima
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Maeda, Y., Noda, Y., Oshio, H. et al. 57Fe Mössbauer spectra and spin-crossover behavior of [Fe(mbpN)(lut)]BPh4 . Hyperfine Interact 80, 1099–1102 (1993). https://doi.org/10.1007/BF00567470

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  • DOI: https://doi.org/10.1007/BF00567470

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