Abstract
The51V NMR in dilute solid solutions of O and N in V was used to study quadrupolar effects due to alloying. The foils with the strong texture showed the discernible structure in the wings of the observed NMR spectra. The metallic site neighbour positions were selectively identified. Electric field gradients (EFG'S) and Knight shifts at these sites were measured. The origin of EFG's is discussed. The experimental data were used to construct the impurity potentials. The energy of O−O bonds in vanadium was estimated.
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Vol'nov, V.O., Shevakin, A.F. Quadrupolar effects in interstitial solid solutions of oxygen and nitrogen in vanadium. Hyperfine Interact 60, 949–952 (1990). https://doi.org/10.1007/BF02399908
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DOI: https://doi.org/10.1007/BF02399908