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67Zn Mössbauer study of Zn metal and Cu−Zn alloys at high pressure

  • Metals and Alloys
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Abstract

A high pressure Mössbauer spectrometer for the 93.3keV resonance in67Zn has been used to investigate Zn metal and two Cu−Zn alloys with Zn concentrations of 41.9at% and 48.0at% at 4.2K and pressures up to ∼58kbar. For Zn metal the c/a-ratio plays an important role to describe the change of the Mössbauer parameters with pressure. Most striking is the increase of the recoil-free fraction by a factor of ∼3. In the brass alloys a new phase is observed at 4.2K and high pressures which we tentatively identify with a martensitic α1-phase.

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Authors and Affiliations

  1. Physik-Department E15, Technische Universität München, D-8046, Garching, FRG

    W. Adlassnig, W. Potzel, J. Moser, W. Schiessl, C. Schäfer & G. M. Kalvius

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  1. W. Adlassnig
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  2. W. Potzel
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  3. J. Moser
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  4. W. Schiessl
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  5. C. Schäfer
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  6. G. M. Kalvius
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Adlassnig, W., Potzel, W., Moser, J. et al. 67Zn Mössbauer study of Zn metal and Cu−Zn alloys at high pressure. Hyperfine Interact 41, 529–534 (1988). https://doi.org/10.1007/BF02400445

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