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Systematic trends in the237neptunium Mössbauer isomer shift: Overlap of IV, V and VI neptunium oxidation states and correlation between isomer shift and crystal structure

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Abstract

The influence of the neptunium ion environment on the237Np Mössbauer isomer shifts has been studied in various metal coordination complexes: fluorides, oxides, oxide fluorides and polycarboxylates. A linear dependence between the isomer shift and the mean neptunium-ligand distance in a series of hexavalent Np compounds has been evidenced and the feasibility of overlapped isomer shift areas, namely Np(IV), Np(V) and Np(VI) has been established.

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  1. Institut Curie, Section de Physique et Chimie, Physicochimie des Eléments Transuraniens (UA 448 CNRS), 11 rue Pierre et Marie Curie, F-75231, Paris Cedex 05, France

    J. Jové, A. Cousson, H. Abazli, A. Tabuteau, T. Thévenin & M. Pagès

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  1. J. Jové
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Jové, J., Cousson, A., Abazli, H. et al. Systematic trends in the237neptunium Mössbauer isomer shift: Overlap of IV, V and VI neptunium oxidation states and correlation between isomer shift and crystal structure. Hyperfine Interact 39, 1–16 (1988). https://doi.org/10.1007/BF02394642

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