Abstract
The electric quadrupole interaction of 19O(Iπ=(5/2)+, T1/2=27.0 s) in TiO2 single crystal was studied in detail by means of the β-NQR to determine the electric quadrupole moments Q of short-lived β-emitting nuclei 19O and 13O(Iπ=(3/2)-, T1/2=8.6 ms). Two implantation sites were found for the implanted O nucleus and the quadrupole coupling constants of 19O at these sites were determined. We observed FT-NMR of the enriched stable isotope 17O in TiO2 and obtained the electric field gradient (EFG) at the oxygen substitutional site. With this knowledge, we have determined Q(13O)=11.0 ± 1.3 mb and Q(19O)=3.7 ± 0.4 mb. The present results are compared with the theoretical values calculated by the shell model code, OXBASH and by the Hartree–Fock calculation with the realistic potential.
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Sato, K., Miyake, T., Morishita, A. et al. Hyperfine interactions of 19O in TiO2 and quadrupole moments of 13,19O. Hyperfine Interactions 120, 661–665 (1999). https://doi.org/10.1023/A:1017031908770
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DOI: https://doi.org/10.1023/A:1017031908770