Abstract
The characteristics of the distribution of particles by size were investigated for sulphates and selected metals (Pb, Fe, Mn, and Cu) in the air in two urban and an industrial area during the winter and summer periods using an Andersen cascade impactor.
In the case of metals, but not sulphates, the character of the area affected the value of mass median diameter. Lowest values were obtained in a sparsely populated urban area, whereas in a densely populated urban area and in the industrial area the values were higher.
In the industrial area a high correlation coefficient was found between sulphate and manganese, and between sulphate and lead, as well as a high value of the equivalent Mn2+/SO sup2-inf4 ratio for the total sample. It may therefore be assumed that in the industrial area manganese produces a catalytic effect on SO2 conversion to sulphate. Among the investigated metals lead stands out as a dominant cation which binds to the sulphate ion in the industrial and densely populated areas.
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References
Altshuller, A. P.: 1976, ‘Regional Transport and Transformation of Sulfur Dioxide to Sulfates in the U.S.’, Air Poll. Control Assoc. 26, 318–324.
Biggins, P. D. E. and Harrison, R. M.: 1979, ‘Characterization and Classification of Atmospheric Sulfates’, Air Poll. Control Assoc. 29, 838–840.
Dubois, L., Baker, C. J., Teichman, T., Zdrojewski, A., and Monkman, J. L.: 1969, ‘The Determination of Sulphuric Acid in Air: A Specific Method’, Mikrochim. Acta (Wien) 269–279.
Environmental Health Criteria 8: Sulfur Oxides and Suspended Particulate Matter, WHO, Geneva 1979.
Fritz, J. S. and Yamamura, S. S.: 1955, ‘Rapid Microtitration of Sulfate’, Anal. Chem. 27, 1461–1464.
Fugaš, M. and Gentilizza, M.: 1978, ‘The Relationship between Sulphate and Sulphur Dioxide in the Air’, Atm. Environ. 12, 335–337.
Harrison, R. M. and Pio, C. A.: 1983, ‘Size Differentiated Composition of Inorganic Atmospheric Aerosols of Both Marine and Polluted Continental Origin’, Atm. Environ. 17, 1733–1738.
Harrison, R. M. and Williams, C. R.: 1982, ‘Airborne Cadmium, Lead and Zinc at rural and urban sites in Worth West England’, Atm. Environ. 16, 2669–2681.
Hering, S. V. and Friedlander, S. K.: 1982, ‘Origins of Aerosol Sulfur Size Distributions in the Los Angeles Basin’, Atm. Environ. 16, 2647–2656.
Jaenicke, R.: 1978, ‘Physical Properties of Atmospheric Particulate Sulphur Compounds’, Atm. Environ. 12, 161–169.
Lee, R. E. and Goranson, S. S.: 1972a, ‘National Air Surveillance Cascade Impactor Network I. Size Distribution Measurements of Suspended Particulate Matter in Air’, Environ. Sci. Technol. 6, 1019–1024.
Lee, R. E., Goranson, S. S., Enrione, R. E., and Morgan, G. B.: 1972b, ‘National Air Surveillance Cascade Impactor Network II. Size Distribution Measurements of Trace Metal Compounds’ Environ. Sci. Technol. 6, 1025–1030.
Ludwig, F. L. and Robinson, E.: 1968, ‘Variations in the Size Distribution of Sulfur-containing Compounds in Urban Aerosols’, Atm. Environ. 2, 13–23.
McEllison, J. and Waller, R. E.: 1978, ‘A Review of Sulphur Oxides and Particulate Matter as Air Pollutants with Particular Reference to Effects on Health in the United Kingdom’, Environ. Research 16, 302–325.
Methods of Measuring Air Pollution, OECD, Paris 1964.
Scaringelli, E. P. and Rehme, K. A.: 1969, ‘Determination of Atmospheric Concentrations of Sulfuric Acid Aerosol by Spectrophotometry Coloumetry and Flame Photometry’, Anal. Chem. 41, 707–713.
Tani, B., Siegel, S., Johnson, S. A., and Kumar, R.: 1983, ‘X-ray Diffraction Investigation of Atmospheric Aerosols in the 0.3–1.0 μm Aerodynamic Size Range’, Atm. Environ. 17, 2277–2283.
Vadjić, V. and Gentilizza, M.: 1985, ‘The Effect of MnO2 and Some Manganese Salts on the Behaviour of Sulphur Dioxide in the Air Investigated on Model Systems’ The Sci. of the Total Environ. 44, 245–251.
Vadjić, V., Gentilizza, M., and Gomzi, Z.: 1986, ‘The Effect of Metal Oxides on the Behaviour of Sulphur Dioxide in the Air Investigated on Model Systems’, Staub Reinhalt. der Luft 46, 125–127.
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Gentilizza, M., Vadjić, V. & Hršsak, J. The characteristics of size distribution of suspended particulates in the air for sulphates and selected metals in different areas and seasons. Environ Monit Assess 11, 137–146 (1988). https://doi.org/10.1007/BF00401726
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DOI: https://doi.org/10.1007/BF00401726