Skip to main content
Log in

The operation of long-life anodes in amalgam cells

  • Papers
  • Published:
Journal of Applied Electrochemistry Aims and scope Submit manuscript

Abstract

In recent years, long-life anodes have become a well established type of DSA(R) anodes for the production of chlorine in mercury cells. They offer considerable benefits compared to ‘normal’ or conventional metal anodes, i.e. reduced costs for repair, transportation and installation as well as a lower consumption of energy. The reason for the decline in damage incidents is probably the slightly increased electrical resistance of the coating. The reasons for the extended service life of the anodes are the decrease in the generation of oxygen and the improved protection of the titanium substrate against penetrating brine and oxygen diffusion.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. H. B. Beer, Netherland Patent 6 606 302 (1966).

  2. Idem, British Patent l 195 871 (1968).

  3. H. Hund, H. Schaefer and D. Bergner, German Patent 2 300 422 (1974).

  4. S. Kotowski, unpublished results.

  5. D. Bergner and J. W. Kühn- von Burgsdorff,Chem. Ins. Techn. 52 (1980) 429.

    Google Scholar 

  6. D. Bergner, H. Hund and H. Schaefer,ibid. 47 (1975) 136.

    Google Scholar 

  7. D. Bergner and J. W. Kühn-von Burgsdorff, ‘Modern Chlor-Alkali Technology’ (edited by M. O. Coulter) Ellis Horwood Ltd, Chichester (1980) Chap. 8.

    Google Scholar 

  8. H. Prüller, W. Kasper, W. Radunski, W. Drees ‘Datensammlung für den Bereich der Chlorfabrik’ (edited by Chemische Werke Hüls AG, D-4370 Marl).

  9. F. Hine, M. Yasuda, T. Noda, T. Yoshida and J. Okuda,J. Electrochem. Soc. 126 (1979) 1439.

    Google Scholar 

  10. L. D. Burke and O. J. Murphy,J. Electroanal chem. 109 (1980) 199.

    Google Scholar 

  11. F. Hine, M. Yasuda and T. Yoshida,J. Electrochem. Soc. 124 (1977) 500.

    Google Scholar 

  12. Ya. M. Kolotyrkin,Denki Kagaku,47 (1979) 390.

    Google Scholar 

  13. T. Loucka,J. Appl. Electrochem. 7 (1977) 211.

    Google Scholar 

  14. C. Iwakura, M. Inai, M. Manabe and H. Tamura,Denki Kagaku 48 (1980) 91.

    Google Scholar 

  15. G. Barral, J. Guitton, M. Montella and F. Vergara,Surface Technol. 8 (1979) 113.

    Google Scholar 

  16. H. Tamura,Denki Kagaku 43 (1975) 674.

    Google Scholar 

  17. D. Bergner,Chemiker Zeitung 104 (1980) 215.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bergner, D., Kotowski, S. The operation of long-life anodes in amalgam cells. J Appl Electrochem 13, 341–350 (1983). https://doi.org/10.1007/BF00941606

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00941606

Keywords

Navigation