Skip to main content
Log in

Investigation of the dependence of the quantum yield with respect to the fluorescence spectrum of solutions

  • Published:
Soviet Physics Journal Aims and scope

Abstract

On the basis of the theory of universal intermolecular interactions a general equation was obtained describing the dependence of the relative quantum yield on the frequency of the light of the fluorescence of solutions in the presence of quenching of the second kind. The spectral dependence of the quantum yield in the case of quenching of the fluorescence by contaminant nonlight-absorbing substances is considered in detail. Measurements carried out on aqueous glycerine solutions of 4-aminophthalimide and 1-, 3-, 5-triphenylpyrazoline quenched by potassium iodide confirmed the theoretical conclusions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. N. G. Bakhshiev, Opt. L Spektr.,10, 717 (1961);16, 821 (1964).

    Google Scholar 

  2. N. G. Bakhshiev, Spectroscopy of Intermolecular Interactions [in Russian], Leningrad (1972).

  3. L. Bilot and A. Kawski, Z. Naturforsch.,18a, 10 (1963).

    Google Scholar 

  4. N. G. Bakhshiev, Yu. T. Mazurenko, and I. V. Piterskaya, Opt. i Spektr.,21, 550 (1966).

    Google Scholar 

  5. Yu. T. Mazurenko, N. G. Bakhshiev, and I. V. Piterskaya, Opt. i Spektr.,25, 92 (1968).

    Google Scholar 

  6. T. V. Veselova, L. A. Limareva, A. S. Cherkasov, and F. I. Shirokov, Opt. i Spektr.,19, 78 (1965).

    Google Scholar 

  7. V. P. Klochkov, Zh. Fiz. Khim.,29, 1432 (1965).

    Google Scholar 

  8. A. S. Cherkasov, Dokl. Akad. Nauk SSSR,139, 658 (1961).

    Google Scholar 

  9. L. Onsager, J. Am. Chem. Soc.,58 1485 (1936).

    Google Scholar 

  10. C. Böttcher, Theory of Electric Polarization, Amsterdam (1952).

  11. S. I. Vavilov, Selected Works [in Russian], Vol. 1 (1954), p. 424.

    Google Scholar 

  12. A. Jablonski, Bull. Acad. Polon. Sci., Ser. Sci. Math. Astron. Phys.,8, 259 (1960).

    Google Scholar 

  13. A. Jablonski, Bull. Acad. Polon. Sci., Ser. Sci. Math. Astron. Phys.,8, 655 (1960).

    Google Scholar 

  14. A. Jablonski, Acta Phys. Polon.,26, 427 (1964).

    Google Scholar 

  15. A. N. Sevchenko, V. I. Popevich, and A. M. Sarzhevskii, Dokl. Akad. Nauk SSR,191, 1025 (1970).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 7, pp. 14–18, July, 1974.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Isachenkova, L.A., Popechits, V.I., Sarzhevskii, A.M. et al. Investigation of the dependence of the quantum yield with respect to the fluorescence spectrum of solutions. Soviet Physics Journal 17, 911–915 (1974). https://doi.org/10.1007/BF00891057

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00891057

Keywords

Navigation