Abstract
A series of methyl and allyl derivatives of ansa-titano- and ansa-zirconocenes with isopropylidene or dimethylsilyl bridging groups were synthesized. A dinuclear complex, [Me2C(C5H4)2]2Ti2O2, resulting from the thermal decomposition of the corresponding dimethyl derivative of ansa-titanocene in the air, was characterized by X-ray diffraction analysis.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 967–969, May, 1993.
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Churakov, A.V., Nifant'ev, I.E., Urazovskii, I.F. et al. Synthesis and properties of ansa-titano- and ansa-zirconocenes. Russ Chem Bull 42, 928–931 (1993). https://doi.org/10.1007/BF00698963
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DOI: https://doi.org/10.1007/BF00698963