Abstract
The key step in the electrochemical oxidation of ketoximes which determines the composition of the electrolysis products is the reaction of the intermediate oxoimmonium cation with the original oxime, whereas in the case of aldoximes, the key step is dimerization of the iminoxyl radicals.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 625–629, March, 1990.
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Petrosyan, V.A., Niyazymbetov, M.E. & Ul'yanova, é.V. Anodic electrolysis of ketoximes and aldoximes: Mechanism. Russ Chem Bull 39, 546–550 (1990). https://doi.org/10.1007/BF00959580
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DOI: https://doi.org/10.1007/BF00959580