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Mechanism of oxidation of xylenes with Pd(II) complexes

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Oxidation of xylenes with Pd(II) complexes in acidic medium is possible according to two pathways: a) electrophilic substitution in the arene ring with the formation of an organometalic intermediate and b) one-electron transfer from the arene to the palladium atom with the intermediacy of the arene cation-radical. The relative contribution of each pathway depends on the nature of the arene and on the acidity of the medium.

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Authors and Affiliations

  1. Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk

    I. V. Kozhevnikov, V. I. Kim & E. P. Talzi

Authors
  1. I. V. Kozhevnikov
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  2. V. I. Kim
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  3. E. P. Talzi
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2167–2174, October, 1985.

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Kozhevnikov, I.V., Kim, V.I. & Talzi, E.P. Mechanism of oxidation of xylenes with Pd(II) complexes. Russ Chem Bull 34, 2001–2007 (1985). https://doi.org/10.1007/BF00963221

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  • DOI: https://doi.org/10.1007/BF00963221

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