Conclusions
Using the dynamic PMR method, it was shown that the silylotropic rearrangements in the trialkylsilyl derivatives of acetoacetic ester, malonic esters, and benzoylacetone have an intramolecular character, while the substituents, framing the β-dicarbonyl fragment, affect the thermodynamic and kinetic parameters of the process.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1904–1906, August, 1981.
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Kalikhman, I.D., Bannikova, O.B., Belousova, L.I. et al. Silylotropic rearrangements in silicon-containing derivatives of acetoacetic ester, malonic esters, and benzoylacetone. Russ Chem Bull 30, 1570–1572 (1981). https://doi.org/10.1007/BF00952221
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DOI: https://doi.org/10.1007/BF00952221