Conclusions
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1.
The relation between the atomic refractions of the halogens and the energies of the C-X bonds in monohaloalkanes was found.
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2.
Some general equations were proposed for calculating the bond energy D(R-X) in alkyl halides.
Literature cited
I. V. Martynov and B. I. Martynov, Zh. Vses. Khim. Obshch.,21, 586 (1976).
V. A. Pal'm, Principles of Quantitative Theory of Organic Reactions [in Russian], Khimiya, Leningrad (1977), p. 322.
V. I. Vedeneev and V. V. Voevodskii, Zh. Fiz. Khim.,30, No. 4, 789 (1956).
Handbook. Rupture Energy of Chemical Bonds. Ionization Potentials and Electron Affinity [in Russian], Izd. AN SSSR, Moscow (1962).
N. N. Semenov, Some Problems of Chemical Kinetics and Reactivity [in Russian], Izd. AN SSSR, Moscow (1958).
A. I. Vogel, J. Chem. Soc., 645 (1948).
R. R. Dreisbach, Physical Properties of Chemical Compounds, Washington (1961), p. 29.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1400–1403, June, 1981.
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Martynov, I.V. Atomic refractions and bond energies of monohaloalkanes. Russ Chem Bull 30, 1123–1126 (1981). https://doi.org/10.1007/BF00950312
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DOI: https://doi.org/10.1007/BF00950312