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Investigation of the ionic forms of triethylgermyllithium in solutions by PMR spectroscopy

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The processes involved in the solvation of Et3GeLi by donating solvents (L) in benzene were studied by the PMR method. The preferred stoichiometry and the spectral parameters of the Et3GeLi·nL complexes which form were determined.

  2. 2.

    It was shown that the structure of the ion pair of Et3GeLi in donating solvents at various temperatures can be determined from the PMR spectra.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    I. D. Kalikhman, D. A. Bravo-Zhivotovskii, B. Z. Pertsikov, V. A. Pestunovich, O. A. Kruglaya & N. S. Vyazankin

Authors
  1. I. D. Kalikhman
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  2. D. A. Bravo-Zhivotovskii
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  3. B. Z. Pertsikov
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  4. V. A. Pestunovich
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  5. O. A. Kruglaya
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  6. N. S. Vyazankin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 53–56, January, 1980.

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Kalikhman, I.D., Bravo-Zhivotovskii, D.A., Pertsikov, B.Z. et al. Investigation of the ionic forms of triethylgermyllithium in solutions by PMR spectroscopy. Russ Chem Bull 29, 43–47 (1980). https://doi.org/10.1007/BF00951875

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  • DOI: https://doi.org/10.1007/BF00951875

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