Conclusion
1. It has been established that, as the chain of polyphenylquinoxalines becomes more rigid by addition of aromatic nuclei of the naphthylimide group to the macromolecule part, the wear resistance of graphite-filled polymer systems increases.
2. It has been demonstrated that during friction with filled polyphenylquinoxalines in the polymer binder there occur complex destructive-structurizing processes whose penetration depth is determined by the chemical constitution of the selected polymers.
3. It has been established that in the rigid-chain polyphenylquinoxaline during friction at high temperatures, just below the glass-transition point but within the range of faster relaxation processes, the destructive-structurizing processes abate and then at temperatures above 250°C active gelling occurs.
Similar content being viewed by others
Literature cited
I. A. Gribova, S. A. Pavlova, A. V. Vinogradov, A. N. Chumaevskaya, L. V. Dubrovina, A. P. Krasnov, A. V. Khomutov, and V. V. Korshak, “Physicochemical processes during friction with lubricating materials”, Mekh. Polim., No. 4, 634–640 (1974).
V. V. Korshak, E. S. Krongauz, A. M. Berlin, A. N. Novikov, and A. N. Moskal'chuk, “Polyphenylqunioxalines with a higher heat resistance”, Vysokomol. Soedin. Ser. B,16, No. 7, 509 (1974).
I. V. Kragel'skii, Friction and Wear [in Russian], 2nd Ed., Moscow (1968).
V. V. Korshak, I. A. Gribova, A. V. Vinogradov, Ya. V. Genin, A. P. Krasnov, D. Ya. Tsvankin, V. V. Lokshin, G. L. Gladyshev, and I. P. Laiutina, “Behavior of antifrictional self-lubricating plastics during friction at high temperatures”, Mekh. Polim., No. 4, 649–657 (1976).
G. I. Timofeeva, E. S. Krongauz. A. M. Berlin, V. V. Korshak, and S. A. Pavlova, “Hydrodynamic characteristics and polydispersion of poly- (2,2-(1,4-phenylen)-7,7-oxy-bis-(3-phenyloxaline)”, Vysokomol. Soedin. Ser. A,18, No. 4, 863 (1976).
G. V. Mamatsashvili, “Development and study of antifrictional self-lubricating plastics based on polyphenylquinoxalines”, Candidate's dissertation, Moscow (1977).
Additional information
Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow. Translated from Mekhanika Polimerov, No. 6, pp. 1049–1054, November–December, 1978.
Rights and permissions
About this article
Cite this article
Korshak, V.V., Gribova, I.A., Krasnov, A.P. et al. Behavior of filled polyphenylquinoxalines during friction. Polymer Mechanics 14, 844–847 (1978). https://doi.org/10.1007/BF00860100
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00860100