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IR predissociation of halogenated methane van der Waals complexes

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Zeitschrift für Physik D Atoms, Molecules and Clusters

Abstract

The infrared dissociation spectra of several halogenated methanes (CHCl2F, CH3F, CF3I and CF3Br) have been studied. Bonded and free C–F stretch excitations have been observed.H-bridges forming the bonding in CHCl2F or CH3F dimers lead to very large red-shifts in the dissociation spectrum with respect to the gas-phase absorptions. Double resonance techniques have been employed to study the homogeneity of the spectral features.

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Authors and Affiliations

  1. Fysisch Laboratorium, Katholieke Universiteit Nijmegen, Toernooiveld, 6525 ED, Nijmegen, The Netherlands

    C. Liedenbaum, B. Heijmen, S. Stolte & J. Reuss

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  1. C. Liedenbaum
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  2. B. Heijmen
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  3. S. Stolte
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  4. J. Reuss
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Liedenbaum, C., Heijmen, B., Stolte, S. et al. IR predissociation of halogenated methane van der Waals complexes. Z Phys D - Atoms, Molecules and Clusters 11, 175–180 (1988). https://doi.org/10.1007/BF01444434

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  • DOI: https://doi.org/10.1007/BF01444434

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