Abstract
Measurements with photoemission spectroscopy in the photon-energy range 35–130 eV have been used to determine the valence band of the stable icosahedral Al65Cu20Os15. Resonant photoemission near the Os 5p → 5d and 4f → 5d transitions has been employed to show that the feature in the valence band with the maximum intensity at 1.5 (1) eV below the Fermi level is predominantly of the Os 5d character. This has been additionally verified by conducting the photoemission measurements in the constant-initial-state mode and by using the effect of the Cooper minimum in the photoionization cross section of the Os 5d orbitals. The valence band feature with the maximum intensity at 3.7 (1) eV below the Fermi level has been shown as being due mainly to the states of the Cu 3d character. The Os 5d and Cu 3d empirical partial density of states have been determined from the photoemission spectra. The decrease of intensity towards the Fermi level has been interpreted as being indicative of the presence of a theoretically predicted pseudogap around the Fermi level. It has been indicated, however, that the Fermi cut-off also contributes to the observed intensity decrease. It has been demonstrated that the energy resolution of the spectroscopic measurements performed so far on quasicrystals was not high enough to unambiguously determine the presence of such a pseudogap. No unusual features in the valence band of icosahedral Al65Cu20Os15, which could be ascribed to its quasiperiodic nature, have been observed within the resolution of the experiment. High energy-resolution spectroscopic measurements were also shown to be essential to observe the theoretically predicted spikiness of the density of states in quasicrystals. A critical review of published spectroscopic data on the electronic structure of quasicrystals has also been presented.
Similar content being viewed by others
References
Schechtman, D., Blech, I., Gratis, D., Cahn, J.W.: Phys. Rev. Lett.53, 1951 (1984)
For a review, see Janot, C.: Quasicrystals, a primer. Oxford: Clarendon Press 1992
For reviews, see Quasicrystals, the state of the art. DiVincenzo, D.P., Steinhardt, P.J. (eds.) Singapore: World Scientific 1991; Quasicrystals. Fujiwara, T., Ogawa, T. (eds.), Berlin, Heildelberg, New York: Springer 1990
For a review, see Poon, S.J.: Adv. Phys.41, 303 (1992)
O'Handley, R.C., Dunlap, R.A., McHenry, M.E.: In: Handbook of Magnetic Materials, Vol. 6, p. 453. Buschow, K.H.J. (ed.), Amsterdam, London, New York: North-Holland 1991
Stadnik, Z.M., Stroink, G.: Phys. Rev. B43, 894 (1991) Phys. Rev. B44, 4255 (1991)
Nasu, S., Miglierini, M., Kuwano, T.: Phys. Rev. B45, 12778 (1992)
Tsai, A.-P., Inoue A., Masumoto, T.: Jpn. J. Appl. Phys.26, L1505 (1987)
Tsai, A.-P., Inoue, A., Masumoto, T.: Jpn. J. Appl. Phys.27, L1587 (1988)
Tsai, A.P., Inoue, A., Yokoyama, Y., Masumoto, T.: Mater. Trans., Jpn. Inst. Metals31, 98 (1990); Phil. Mag. Lett.61, 9 (1990)
Tsai, A.-P., Yokoyama, Y., Inoue, A., Masumoto, T.: Jpn. J. Appl. Phys.29, L1161 (1990)
Honda, Y., Edagawa, K., Yoshioka, A., Hashimoto, T., Takeuchi, S.: Jpn. J. Appl. Phys. AA33 4929 (1994)
Mott, N.: Conduction in non-crystalline materials. Oxford: Clarendon Press 1993
Pierce, F.S., Poon, S.J., Guo, Q.: Science261, 737 (1993)
Klein, T., Berger, C., Mayou, D., Cyrot-Lackmann, F.: Phys. Rev. Lett.66, 2907 (1991)
Berger, C., Grenet, T., Lindqvist, P., Lanco, P., Grieco, J.C., Fourcaudot, G., Cyrot-Lackmann, F.: Solid State Commun.87, 977 (1993)
Matsuo, S., Ishimasa, T., Nakano, H., Fukano, Y.: J. Phys.F 18, L175 (1988); Stadnik, Z.M., Stroink, G., Ma, H., Williams, G.: Phys. Rev.B39, 9797 (1989)
Hume-Rothery, W.: J. Inst. Metals35, 295 (1926); The metallic state. London, Edinburgh, Glasgow: Oxford University Press 1931
Mott, N.F., Jones, H.: The theory of the properties of metals and alloys. Glasgow, New York, Toronto: Oxford University Press 1958
Phillips, J.C.: Phys. Rev. B47, 7747 (1993)
Heine, V., Weaire, D.: In: Solid state physics. Advances in Research and Applications Vol. 24, p. 249. Ehrenreich, H., Seitz, F., Turnbull, D. (eds.) New York, London: Academic Press 1970; Cottrell, A.: Introduction to the modern theory of metals. London: The Institute of Metals 1988
Smith, A.P., Ashcroft, N.W.: Phys. Rev. Lett.59, 1365 (1987)
Friedel, J., Dénoyer, F.: C.R. Acad. Sci. (Paris)305, 171 (1987);
Friedel, J.: Helv. Phys. Acta61, 538 (1988); Phil. Mag. B65, 1125 (1992)
Vaks, V.G., Kamyshenko, V.V., Samolyuk, G.D.: Phys. Lett. A132, 131 (1988)
Fradkin, M.A.: J. Phys.: Condensed Matter4, 10497 (1992)
Carlsson, A.E.: Phys. Rev. B47, 2515 (1993); J. Non-Cryst. Solids153 & 154, 386 (1993)
Fujiwara, T.: Phys. Rev. B40, 942 (1989); J. Non-Cryst. Solids117 & 118, 844 (1990); Fujiwara, T., Trambly de Laissardière, G., Yamamoto, S.: Mater. Sci. Eng. A179 & 180, 118 (1994)
Fujiwara, T., Yokokawa, T.: Phys. Rev. Lett.66, 333 (1991); Fujiwara, T.: J. Non-Cryst. Solids153 & 154, 390 (1993)
Fujiwara, T., Yamamoto, S., Trambly de Laissardière, G.: Phys. Rev. Lett.71, 4166 (1993); Eujiwara T.: J. Non-Cryst. Solids156 & 158, 865 (1993); Mater. Sci. Eng.B19, 77 (1993)
Trambly de Laissardière, G., Fujiwara, T.: Phys. Rev.B50, 5999 (1994)
Hafner, J., Krajčí, M.: Phys. Rev. Lett.68, 2321 (1992); Europhys. Lett.17, 145 (1992); J. Non-Cryst. Solids150, 337 (1992)
Hafner, J., Krajčí, M.: Phys. Rev. B47, 11795 (1993)
Hippert, F., Kandel, L., Calvayrac, Y., Dubost, B.: Phys. Rev. Lett.69, 2086 (1992)
Phillips, J.C., Rabe, K.M.: Phys. Rev. Lett.66, 923 (1991)
Phillips, J.C.: Solid State. Commun.83, 379 (1992); Phys. Rev. B47, 2522 (1993); Phys. Rev. B47, 7747 (1993)
Mayou, D., Berger, C., Cyrot-Lackmann, F., Klein, T., Lanco, P.: Phys. Rev. Lett.70, 3815 (1993)
Yamamoto, S., Fujiwara, T.: Mater. Sci. Eng. A181 & 182, 726 (1994)
Chernikov, M.A., Bernasconi, A., Beeli, C., Ott, H.R.: Europhys. Lett.21, 767 (1993)
Bruhwiler, P.A., Shen, Y., Schnatterly, S.E., Poon, S.J.: Phys. Rev. B36, 7347 (1987); Bruhwiler, P.A., Wagner, J.L., Biggs, B.D., Shen, Y., Wong, K.M., Schnatterly, S.E., Poon, S.J.: Phys. Rev. B37, 6529 (1988); Ederer, D.L., Schaefer, R., Tsang, K.-L., Zhang, C.H., Callcott, T.A., Arakawa, E.T.: Phys. Rev. B37, 8594 (1988)
Traverse, A., Dumoulin, L., Belin, E.: In: Quasicrystalline materials, p. 399. Janot, Ch., Dubois, J.M. (eds.) Singapore: World Scientific 1988
Belin, E., Traverse, A.: J. Phys.: Condensed Matter3, 2157 (1991)
Mori, M., Matsuo, S., Ishimasa, T., Matsuura, T., Kamiya, K., Inokuchi, H., Matsukawa, T., J. Phys.: Condensed Matter3, 767 (1991); Mori, M., Kamiya, K., Matsuo, S., Ishimasa, T., Nakano, H., Fujimoto, H., Inokuchi, H.: J. Phys.: Condensed Matter4, L157 (1992)
Matsubara, H., Ogawa, S., Kinoshita, T., Kishi, K., Takeuchi, S., Kimura, K., Suga, S., Jpn. J. Appl. Phys. A30, L389 (1991)
Belin, E., Kojnok, J., Sadoc, A., Traverse, A., Harmelin, M., Berger, C., Dubois, J.-M.: J. Phys. Condensed Matter4, 1057 (1992)
Belin, E., Dankhazi, Z., Sadoc, A., Calvayrac, Y., Klein, T., Dubois, J.-M.: J. Phys.: Condensed Matter4, 4459 (1992)
Belin, E.: In Physics and Chemistry of Finite Systems, Vol. II, p. 829. Jena, P., Khanna, S.N., Rao, B.K. (eds) Amsterdam: Kluwer 1992
Belin, E., Danhakázi, Z.: J. Non-Cryst. Solids153 & 154, 298 (1993); Sadoc, A., Belin, E., Dankhazi, Z., Flank, A.M.: J. Non-Cryst. Solids153 & 154, 338 (1993); Belin, E., Dankhazi, Z., Sadoc, A., J. Non-Cryst. Solids156 & 158, 896 (1993); Belin, E., Mayou, D., Phys. Scr. T49, 356 (1993); Berger C., Belin, E., Mayou, D.: Ann. Chim. Fr.18, 485 (1993); Belin, E., Traverse, A., Sonder, A.: Nucl. Instrum. Methods Phys. Res. B80 & 81, 80 (1993)
Stadnik, Z.M., Stroink, G.: Phys. Rev. B47, 100 (1993); J. Non-Cryst. Solids156 & 158, 891 (1993)
Mizutani, U., Matsuda, T., Itoh, Y., Tanaka, K., Domae, H., Mizuno, T., Murasaki, S., Miyoshi, Y., Hashimoto, K., Yamada, Y.: J. Non-Cryst. Solids156 & 158, 882 (1993)
Zhang, G.W., Stadnik, Z.M., Tsai, A.-P., Inoue, A.: Phys. Lett. A186, 345 (1994); Phys. Rev. B50, 6696 (1994)
Belin, E., Dankhazi, Z., Sadoc, A.: Mater. Sci. Eng. A181 & 182, 717 (1994)
Belin, E., Miyoushi, Y., Yamada, Y., Ishikawa, T., Matsuda, T., Mizutani, U.: Mater. Sci. Eng. A181 & 182, 730 (1994)
Nakamura, Y., Mizutani, U.: Mater. Sci. Eng. A181 & 182 790 (1994)
Hashimoto, K., Yamada, Y., Yamauchi, T., Tanaka, T., Matsuda, T., Mizutani, U.: Mater. Sci. Eng. A181 & 182 785 (1994); Mizutani, U., Yamada, Y., Takeuchi, T., Hashimoto, K., Belin, E., Sadoc, A., Yamauchi, T., Matsuda, T.: J. Phys.: Condensed Matter6, 7335 (1994)
Stadnik, Z.M., Zhang, G.W., Tsai, A.-P., Inoue, A.: J. Phys.: Condensed Matter6, 6885 (1994)
Häussler, P.: Phys. Rep.222, 65 (1992)
McHenry, M.E., Eberhart, M.E., O'Handley, R.C., Johnson, K.H.: Phys. Rev. Lett.56, 81 (1986)
De Coulon, V., Reuse, F.A., Khanna, S.N.: Phys. Rev. B48, 814 (1993); Liu, F., Khanna, S.N., Magaud, L., Jena, P., De Coulon, V., He, X.-G., Cyrot-Lackmann, F.: Phys. Rev. B48, 1295 (1993)
Tsai, A.-P., Inoue, A., Nasumoto, T.: Mater. Trans. Jpn. Inst. Metals30, 666 (1989)
Matsubara, E., Waseda, Y.: In: Quasicrystals, p. 96. Kuo, K.H., Ninomiya, T. (eds.). Singapore: World Scientific 1991
Shinohara, T., Tsai, A.P., Sato, T., Masumoto, T.: J. Mater. Res.7, 1970 (1992)
Stadnik, Z.M., Zhang, G.W., Tsai, A.-P., Inoue, A.: (to be published)
Helmer, J.C., Weichert, N.H.: Appl. Phys. Lett.13, 266 (1968)
Shirley, D.A.: Phys. Rev. B5, 4709 (1972)
Yeh, J.-J.: Atomic calculation of photoionization cross-sections and asymmetry parameters. London: Gordon and Breach 1993
Allen, J.W.: In: Synchrotron radiation research. Advances in Surfaces and Interface Science, Vol. 1, p. 253. Bachrach, R.Z. (ed.), New York, London: Plenum Press 1992
Fuggle, J.C., Mårtensson, N.: J. Electr. Spectrosc. Relat. Phenom.21, 275 (1980)
Rossi, G., Lindau, I., Braicovich, L., Abbati, I.: Phys. Rev. B28, 3031 (1983); Cole, R.J., Evans, J.A., Duò, L., Laine, A.D., Fowles, P.S., Weightman, P., Mondio, G., Norman, D.: Phys. Rev. B46, 3747 (1992)
Davis, L.C.: J. Appl. Phys.59, R25 (1986); Kunz, C. In: Photoemission in Solids II, p. 299. Ley, L., Cardona, M. (eds.), Berlin Heidelberg, New York: Springer 1979
Eastman, D.E., Grobman, W.D.: Phys. Rev. Lett.28, 1327 (1972); Freeouf, J., Erbudak, M., Eastman, D.E.: Solid State Commun.13 771 (1973); Feibelman, P.J., Eastman, D.E.: Phys. Rev. B10, 4932 (1974); Nahm, T.-U., Han, M., Oh, S.-J., Park, J.-H., Allen, J.W., Chung, S.-M.: Phys. Rev. Lett.70, 3663 (1993)
Wright, H., Weightman, P., Andrews, P.T., Folkerts, W., Flipse, C.F.J., Sawatzky, G., Norman, D., Padmore, H.: Phys. Rev. B35, 519 (1987)
Folkerts, W., Van Der Marel, D., Haas, C., Sawatzky G.A., Norman, D., Padmore, H., Wright, H., Weight, H., Weightman, P.: J. Phys. F17, 657 (1987)
Allen, J.W., Oh, S.J., Gunnarsson, O., Schönhammer, K., Maple M.B., Torikachvili, M.S., Lindau, I.: Adv. Phys.35, 275 (1986) Soda, K., Mori, T., Taniguchi, M., Asaoka, S., Naito, K., Önuki, Y., Komatsubara, T., Miyahara, T., Sato, S., Ishii, T.: J. Phys. Soc. Jpn.55, 1709 (1986); Shen, Z.-X., Lindberg, P.A.P., Wells, B.O., Dessau, D.S., Borg, A., Lindau, I., Spicer, W.E., Ellis, W.P., Kwei, G.H., Ott, K.C., Kang, J.-S., Allen, J.W.: Phys. Rev. B40, 6912 (1989); Weidemann, R., Gumlich, H.-E., Kupsch, M., Middlemann, H.-U., Becker, U.: Phys. Rev. B45, 1172 (1992); Nohara, S., Namatame, H., Fujimori, A., Takabatake, T.: Phys. Rev. B47, 1754 (1993); Ueda, Y., Taniguchi, M., Mizokawa, T., Fujimori, A., Souma, I., Oka, Y., Phys. Rev. B49, 2167 (1994)
Nilsson, R., Berndtsson, A., Mårtensson, N., Nyholm, R., Hedman, J.: Phys. Status Solidi. (b)75, 197 (1976)
Baer, Y., Busch, G.: Phys. Rev. Lett.30, 280 (1973)
Höchst, H., Steiner, P., Reiter, G., Hüfner, S.: Z. Phys. B42, 199 (1981)
Patthey, F., Delley, B., Schneider, W.-D., Baer, Y.: Phys. Rev. Lett.55, 1518 (1985); Weschke, E., Laubschat, C., Simmons, T., Domke, M., Strebel, O., Kaindl, G., Phys. Rev. B44, 8304 (1991); Hwu, Y., Lozzi, L., La Rosa, S., Onellion, M., Almeras, P., Gozzo, F., Lévy, F., Berger, H., Margaritondo, G.: Phys. Rev. B45, 5438 (1992)
Dankházi, Z., Trambly De Laissardière, G., Manh, D.N., Belin, E., Mayou, D.: J. Phys.: Condensed Matter5, 3339 (1993)
Weijs, P.J.W., Czyżyk, M.T., Fuggle J.C., Speier, W., Darma, D.D., Buschow, K.H.J.: Z. Phys. B78, 423 (1990)
Ławniczak-Jabłońska, K., Inoue, J., Tohyama, T., Czyżyk, M.T.: Phys. Rev. B49, 14165 (1994)
Imer, J.-M., Patthey, F., Dardel, B., Schneider, W.-D., Baer, Y., Petroff, Y., Zettl, A.: Phys. Rev. Lett.62, 336 (1989); Olson, C.G., Liu, R., Yang, A.-B., Lynch, D.W., Arko, A.J., List, R.S., Veal, B.W., Chang, Y.C., Jiang, P.Z., Paulikas, A.P.: Science245, 731 (1989); Shen, Z.-X., Dessau, D.S., Wells, B.O., King, D.M., Spicer, W.E., Arko, A.J., Marshall, D., Lombardo, L.W., Kapitulnik, A., Dickinson, P., Doniach, S., DiCarlo, J., Loesser, A.G., Park, C.H.: Phys. Rev. Lett.70, 1553 (1993)
Dardel, D., Grioni, M., Malterre, D., Weibel, P., Baer, Y., Lévy, F.: J. Phys.: Condensed Matter5, 6111 (1993)
Takahashi, T.: Comments Cond. Mat. Phys.16, 113 (1992)
Smith, K.E., Henrich, V.E.: Phys. Rev. B50, 1382 (1994)
Koshikawa, N., Sakamoto, S., Edagawa, K., Takeuchi, S.: Jpn. J. Appl. Phys.31, L966 (1992); Koshikawa, N., Edagawa, K., Takeuchi, S.: Mater. Trans. Jpn. Inst. Metals34, 188 (1993)
Niikura, A., Tsai, A.P., Inoue, A., Masumoto, T.: Philos. Mag. Lett.69, 351 (1994); Tsai, A.P., Niikura, A., Inoue, A., Masumoto, T., Nishida, Y., Tsuda, K., Tanaka, M.: Philos. Mag. Lett.70 169 (1994)
Janot, Ch., Dubois, J.M.: J. Phys. F18, 2303 (1988)
Stadnik, Z.M.: Hyperfine Interact.90, 215 (1994)
Shastri, A., Borsa, F., Goldman, A.I., Shield, J.E., Torgeson, D.R.: J. Non-Cryst. Soids153 & 154, 347 (1993)
Vernier, N., Bellessa, G., Perrin, B., Zarembovitch, A., De Boissieu, M.: Europhys. Lett.22, 187 (1993)
Doniach, S., Šunjić, M.: J. Phys. C3, 285 (1970)
Baer, Y., Busch, G., Cohn, P.: Rev. Sci. Instrum.46, 466 (1975); Flodstrom, S.A., Bachrach R.Z., Bauer, R.S., Hagström, S.B.: Phys. Rev. Lett.37, 1282 (1976); Hagström, S.B.M., Bachrach, R.Z., Bauer, R.S., Flodström, S.A.: Phys. Scr.16, 414 (1977)
Hillebrecht, F.U., Fuggle, J.C., Bennett, P.A., Zołnierek, Z., Freiburg, Ch.: Phys. Rev. B27, 2179 (1983)
Stadnik, Z.M., Stroink, G.: J. Non-Cryst. Solids99, 233 (1988)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Zhang, G.W., Stadnik, Z.M., Tsai, A.P. et al. Electronic structure of icosahedral alloys: The case of Al65Cu20Os15 . Z. Physik B - Condensed Matter 97, 439–452 (1995). https://doi.org/10.1007/BF01317227
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01317227