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Mössbauer spectroscopy with the 93 keV-resonance in67Zn

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Zeitschrift für Physik B Condensed Matter

Abstract

The procedures and results of high resolution Mössbauer experiments performed with the 93.3 keV resonance in absorbers of67ZnO,67ZnS (both wurtzite and sphalerite structures),67ZnSe,67ZnTe and67ZnF2 are reported. An essentially linear dependence between the isomer shift and the Pauling electronegativity of the ligands was found. A value ofΔ 〈r 2〉=+11×10−3 fm2 is estimated. The Mössbauer parameters for both ZnS structures are equal within present limits of error. In particular, no quadrupole interaction was observed in the wurtzite modification. This indicates a nearly identical local symmetry at the Zn site in the two ZnS structures.

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Authors and Affiliations

  1. Physik-Department E 15, Technische Universität München, James-Franck-Strasse, D-8046, Garching bei München, Federal Republic of Germany

    A. Forster, W. Potzel & G. M. Kalvius

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  1. A. Forster
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  2. W. Potzel
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  3. G. M. Kalvius
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Work supported by the Bundesministerium für Forschung und Technologie, Federal Republic of Germany and the Kernfor-schungszentrum Karlsruhe

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Forster, A., Potzel, W. & Kalvius, G.M. Mössbauer spectroscopy with the 93 keV-resonance in67Zn. Z Physik B 37, 209–219 (1980). https://doi.org/10.1007/BF01323034

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  • DOI: https://doi.org/10.1007/BF01323034

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