The presence of melt ponds on the surface of Arctic Sea ice affects its albedo, thermal properties, and overall melting rate; thus, the detection of melt pond onset is of significant importance for understanding the Arctic’s changing climate. This study investigates the utility of a novel method for detecting the onset of melt ponds on sea ice using a satellite-based, dual-sensor C-band approach, whereby Sentinel-1 provides horizontally polarized (HH) data and Advanced SCATterometer (ASCAT) provides vertically polarized (VV) data. The co-polarized ratio (VV/HH) is used to detect the presence of melt ponds on landfast sea ice in the Canadian Arctic Archipelago in 2017 and 2018. ERA-5 air temperature and wind speed re-analysis datasets are used to establish the VV/HH threshold for pond onset detection, which have been further validated by Landsat-8 reflectance. The co-polarized ratio threshold of three standard deviations from the late winter season (April) mean co-pol ratio values are used for assessing pond onset detection associated with the air temperature and wind speed data, along with visual observations from Sentinel-1 and cloud-free Sentinel-2 imagery. In 2017, the pond onset detection rates were 70.59% for FYI and 92.3% for MYI. Results suggest that this method, because of its dual-platform application, has potential for providing large-area coverage estimation of the timing of sea ice melt pond onset using different earth observation satellites. Full article

In this study we explore the effect of a professional development (PD) program on four science teachers’ views and practices nearly a year after its completion, regarding inquiry implementation in everyday school practice. The PD program aimed to familiarize participants with current trends in science education (SE), putting emphasis on the inquiry approach. The basic research question guiding this study is whether science teachers’ inquiry practices and views changed, and to which extent, long after their participation in the PD program. Teachers’ practices were recorded, both during and after the PD, through non-participatory observation and were analysed through a semi-quantitative method. Teachers’ views were also recorded both during and after PD through structured questionnaires and reflective interviews, producing qualitative data that were analysed. Findings are encouraging concerning the preservation of guided inquiry practices obtained during the program, while more open inquiry practices proved to be limited. Teachers’ views concerning inquiry remained positive, also maintaining their innovative character. Full article

With the advent of the big data era, data security and sharing have become the core elements of new-era data processing. Privacy-preserving record linkage (PPRL), as a method capable of accurately and securely matching and sharing the same entity across multiple data sources, is receiving increasing attention. Among the existing research methods, although PPRL methods based on Bloom Filter encoding excel in computational efficiency, they are susceptible to privacy attacks, and the security risks they face cannot be ignored. To balance the contradiction between security and computational efficiency, we propose a multi-party PPRL method based on secondary encoding. This method, based on Bloom Filter encoding, generates secondary encoding according to well-designed encoding rules and utilizes the proposed linking rules for secure matching. Owing to its excellent encoding and linking rules, this method successfully addresses the balance between security and computational efficiency. The experimental results clearly show that, in comparison to the original Bloom Filter encoding, this method has nearly equivalent computational efficiency and linkage quality. The proposed rules can effectively prevent the re-identification problem in Bloom Filter encoding (proven). Compared to existing privacy-preserving record linkage methods, this method shows higher security, making it more suitable for various practical application scenarios. The introduction of this method is of great significance for promoting the widespread application of privacy-preserving record linkage technology. Full article

Abstract: In this study, an improved PVA/PLA fibrous hemostatic membrane was prepared by electrospinning technology combined with air plasma modification. The plasma treatment was used to modify PLA to enhance the interlayer bonding between the PVA and PLA fibrous membranes first, then modify the PVA to improve the hemostatic capacity. The surfaces of the PLA and PVA were oxidized after air plasma treatment, the fibrous diameter was reduced, and roughness was increased. Plasma treatment enhanced the interfacial bond strength of PLA/PVA composite fibrous membrane, and PLA acted as a good mechanical support. Plasma-treated PVA/PLA composite membranes showed an increasing liquid-enrichment capacity of 350% and shortened the coagulation time to 258 s. The hemostatic model of the liver showed that the hemostatic ability of plasma-treated PVA/PLA composite membranes was enhanced by 79% compared to untreated PVA membranes, with a slight improvement over commercially available collagen. The results showed that the plasma-treated PVA/PLA fibers were able to achieve more effective hemostasis, which provides a new strategy for improving the hemostatic performance of hemostatic materials. Full article

This paper introduces a cutting-edge data architecture designed for a smart advertising context, prioritizing efficient data flow and performance, robust security, while guaranteeing data privacy and integrity. At the core of this study lies the application of federated learning (FL) as the primary methodology, which emphasizes the authenticity and privacy of data while promptly discarding irrelevant or fraudulent information. Our innovative data model employs a semi-random role assignment strategy based on a variety of criteria to efficiently collect and amalgamate data. The architecture is composed of model nodes, data nodes, and validator nodes, where the role of each node is determined by factors such as computational capability, interconnection quality, and historical performance records. A key feature of our proposed system is the selective engagement of a subset of nodes for modeling and validation, optimizing resource use and minimizing data loss. The AROUND social network platform serves as a real-world case study, illustrating the efficacy of our data architecture in a practical setting. Both simulated and real implementations of our architecture showcase its potential to dramatically curtail network traffic and average CPU usage, while preserving the accuracy of the FL model. Remarkably, the system is capable of achieving over a 50% reduction in both network traffic and average CPU usage even when the user count escalates by twenty-fold. The click rate, user engagement, and other parameters have also been evaluated, proving that the proposed architecture’s advantages do not affect the smart advertising accuracy. These findings highlight the proposed architecture’s capacity to scale efficiently and maintain high performance in smart advertising environments, making it a valuable contribution to the evolving landscape of digital marketing and FL. Full article

The mining industry produces large amounts of tailings which are disposed of in deposits, which neglects their potential value and represents important economic, social and environmental risks. Consequently, implementing circular economy principles using these unconventional geomaterials may decrease the wide-ranging impacts of raw material extraction. This paper presents an experimental characterization of iron ore tailings, which are the most abundant type of mining waste. The characterization includes various aspects of behavior that are relevant to different types of use as a building material, including physical and identification properties, compaction behavior and stress–strain properties under undrained monotonic and cyclic triaxial loading. The tailings tested can be described as low-plasticity silty sand materials with an average solids density of 4.7, a maximum dry unit weight close to 3 g/cm³ and a higher angle of friction and liquefaction resistance than common granular materials. The experimental results highlight the particular features of the behavior of iron ore tailings and emphasize the potentially promising combination of high shear resistance and high density that favors particular geotechnical applications. Overall, the conclusions provide the basis for promoting the use of mining wastes in the construction of sustainable geotechnical works and underpin the advanced analysis of tailings storage facilities’ safety founded on an open-minded geotechnical approach. Full article

Cobalt-aluminum-layered double hydroxides containing carboxymethyl β-cyclodextrin (CMβCD) were synthesized by coprecipitation and evaluated as a cobalt source for the 4-nitrophenol reduction in an aqueous medium. Several physicochemical techniques (XRD, FTIR, TGA) indicated the intercalation of the anionic cyclodextrin without damages to the hydrotalcite-type structure. These lamellar cobalt-aluminum hybrid materials (CoAl_CMβCD) were evaluated in the 4-nitrophenol reduction and showed higher activities in comparison with the CMβCD-free standard material (CoAl_CO₃). To rationalize these results, a set of experimental controls going from physical mixtures of CoAl_CO₃ with different cyclodextrins to other cobalt-based materials were investigated, highlighting the beneficial effects of both the layered double hydroxide and CMβCD-based hybrid structures. CMβCD also showed a beneficial effect as an additive during the 4-nitrophenol reduction. CoAl_CO₃, dispersed in a fresh CMβCD solution could be re-used for five successive cycles without the loss of activity. Full article

In response to the widespread absence of global navigation satellite system (GNSS) signals in underground parking scenes, we propose a multimodal localization method that integrates enhanced berth mapping with Clothoid trajectory prediction, enabling high-precision localization for intelligent vehicles in underground parking environments. This method began by constructing a lightweight map based on the key berths. The map consisted of a series of discrete nodes, each encompassing three elements: holistic and local scene features extracted from an around-view image, and the global pose of the mapping vehicle calculated using the positions of the key berth’s corner points. An adaptive localization strategy was employed during the localization phase based on the trajectory prediction result. A progressive localization strategy, relying on multi-scale feature matching, was applied to the nodes within the map coverage range. Additionally, a compensation localization strategy that combined odometry with the prior pose was utilized for the nodes outside the map coverage range. The experiments conducted in two typical underground parking scenes demonstrated that the proposed method achieved a trajectory prediction accuracy of 40 cm, a nearest map search accuracy exceeding 92%, and a metric localization accuracy meeting the 30 cm standard. These results indicate that the proposed approach satisfies the high-precision, robust, real-time localization requirements for intelligent vehicles in underground parking scenes, while effectively reducing the map memory requirements. Full article

High-voltage heat release from batteries can cause safety issues for electric vehicles. Relevant scientific research work is carried out in the laboratory. The battery safety of laboratory experiments should not be underestimated. In order to evaluate the safety performance of batteries in the laboratory testing of driving conditions of electric vehicles, this paper simulated and compared the discharge characteristics of two common batteries (lithium iron phosphate (LFP) battery and nickel–cobalt–manganese (NCM) ternary lithium battery) in three different operating conditions. The operating conditions are the NEDC (New European Driving Cycle), WLTP (World Light Vehicle Test Procedure) and CLTC-P (China light vehicle test cycle) for normal driving of electric vehicles. LFP batteries have a higher maximum voltage and lower minimum voltage under the same initial voltage conditions, with a maximum voltage difference variation of 11 V. The maximum current of WLTP is significantly higher than NEDC and CLTC-P operating conditions (>20 A). Low current discharge conditions should be emulated in teaching simulation and experiments for safety reasons. The simulation data showed that the LFP battery had good performance in maintaining the voltage plateau and discharge voltage stability, while the NCM battery had excellent energy density and long-term endurance. Full article

This paper presents a comprehensive study on single- and repetitive-frequency UIS characteristics of 1200 V asymmetric (AT) and double trench silicon carbide (DT-SiC) metal-oxide-semiconductor field-effect transistors (MOSFETs) and their electrical degradation under electrical–thermal working conditions, investigated through experiment and simulation verification. Because their structure is different, the failure mechanisms are different. Comparatively, the gate oxide of a DT-MOSFET is more easily damaged than an AT-MOSFET because the hot carriers are injected into the oxide. The parameters’ degradation under repetitive UIS stress also requires analysis. The variations in the measured parameters are recorded to evaluate typical electrical features of device failure. Furthermore, TCAD simulation is used to reveal the electrothermal stress inside the device during avalanche. Additionally, failed devices are decapsulated to verify the location of the failure point. Finally, a new type of stepped-oxide vertical power DT MOSFET with P-type shielding and current spread layers, along with its feasible process flow, is proposed for the improvement of gate dielectric reliability. Full article

In engineering, concrete often develops cracks due to various reasons, which accelerate the erosion rate of chloride ions in concrete and consequently expedite the degradation of the mechanical properties of concrete structures. This study simplifies the four-phase model into a two-phase model using homogenization methods. Based on this, numerical simulations are employed to investigate the influences of dimensionless structural parameters and material parameters of cracks on the equivalent diffusion coefficient of cracked concrete, and a theoretical model for the equivalent diffusion coefficient of cracked concrete is established according to Fick’s diffusion law. The research findings indicate that when cracks are positioned in the middle of the boundary through which chloride ions enter and exit the concrete, and the direction of the cracks is parallel to the diffusion direction of chloride ions; this scenario is the most detrimental to the durability of concrete. For n cracks (n ≥ 2), when they are parallel to the x-axis and symmetrical about the x-axis, and the spacing between cracks equals 1/n times the width of the concrete, this scenario is the most detrimental to the durability of concrete containing multiple cracks. Whether for a single crack or multiple cracks, when they are in the most unfavorable condition, the “parallel-then-series” theoretical model can accurately predict the equivalent diffusion coefficient of cracked concrete. Full article

Differentiated high-grade thyroid carcinoma (DHGTC) is a new subset within the spectrum of thyroid malignancies. This review aims to provide a comprehensive overview of DHGTC, focusing on its historical perspective, diagnosis, clinical characteristics, molecular profiles, management, and prognosis. DHGTC demonstrates an intermediate prognosis that falls between well-differentiated thyroid carcinoma and anaplastic thyroid carcinoma. Previously unenumerated, this entity is now recognized for its significant impact. Patients with DHGTC often present at an older age with advanced disease and exhibit aggressive clinical behavior. Molecularly, DHGTC shares similarities with other thyroid malignancies, harboring driver mutations such as BRAFV600E and RAS, along with additional late mutations. The unique behavior and histologic features of DHGTC underscore the necessity of precise classification for prognostication and treatment selection. This highlights the critical importance of accurate diagnosis and recognition by pathologists to enrich future research on this entity further. Full article

Accurate vehicle velocity prediction is of great significance in vehicle energy distribution and road traffic management. In light of the high time variability of vehicle velocity itself and the limitation of single model prediction, a velocity prediction method based on K-means-QPSO-LSTM with kinematic segment recognition is proposed in this paper. Firstly, the K-means algorithm was used to cluster samples with similar characteristics together, extract kinematic fragment samples in typical driving conditions, calculate their feature parameters, and carry out principal component analysis on the feature parameters to achieve dimensionality reduction transformation of information. Then, the vehicle velocity prediction sub-neural network models based on long short-term memory (LSTM) with the QPSO algorithm optimized were trained under different driving condition datasets. Furthermore, the kinematic segment recognition and traditional vehicle velocity prediction were integrated to form an adaptive vehicle velocity prediction method based on driving condition identification. Finally, the current driving condition type was identified and updated in real-time during vehicle velocity prediction, and then the corresponding sub-LSTM model was used for vehicle velocity prediction. The simulation experiment demonstrated a significant enhancement in both the velocity and accuracy of prediction through the proposed method. The proposed hybrid method has the potential to improve the accuracy and reliability of vehicle velocity prediction, making it applicable in various fields such as autonomous driving, traffic management, and energy management strategies for hybrid electric vehicles. Full article

The selective hydrogenation of the biomass platform molecule furfural (FAL) to produce furfuryl alcohol (FA) is of great significance to alleviate the energy crisis. Cu-based catalysts are the most commonly used catalysts, and their catalytic performance can be optimized by changing the preparation method. This paper emphasized the effect of calcination atmosphere on the performance of a Cu/Al₂O₃ catalyst for the selective hydrogenation of FAL. The precursor of the Cu/Al₂O₃ catalyst prepared by the ammonia evaporation method was treated with different calcination atmospheres (N₂ and air). On the basis of the combined results from the characterizations using in situ XRD, TEM, N₂O titration, H₂-TPR and XPS, the Cu/Al₂O₃ catalyst calcined in the N₂ atmosphere was more favorable for the dispersion and reduction of Cu species and the reduction process could produce more Cu⁺ and Cu⁰ species, which facilitated the selective hydrogenation of FAL to FA. The experimental results showed that the N₂ calcination atmosphere improved the FAL conversion and FA selectivity, and the FAL conversion was further increased after reduction. Cu/Al₂O₃-N₂-R exhibited the outstanding performance, with a high yield of 99.9% of FA after 2 h at 120 °C and an H₂ pressure of 1 MPa. This work provides a simple, efficient and economic method to improve the C=O hydrogenation performance of Cu-based catalysts. Full article

Intelligent and diversified development of modern detection technology greatly affects the battlefield survivability of military targets, especially infrared, acoustic wave, and radar detection expose targets by capturing their unavoidable infrared radiation, acoustic wave, and electromagnetic wave information, greatly affecting their battlefield survival and penetration capabilities. Therefore, there is an urgent need to develop stealth-protective materials that can suppress infrared radiation, reduce acoustic characteristics, and weaken electromagnetic signals. Fibrous three-dimensional porous materials, with their high porosity, excellent structural adjustability, and superior mechanical properties, possess strong potential for development in the field of stealth protection. This article introduced and reviewed the characteristics and development process of fibrous three-dimensional porous materials at both the micrometer and nanometer scales. Then, the process and characteristics of preparing fibrous three-dimensional porous materials through vacuum forming, gel solidification, freeze-casting, and impregnation stacking methods were analyzed and discussed. Meanwhile, their current application status in infrared, acoustic wave, and radar stealth fields was summarized and their existing problems and development trends in these areas from the perspectives of preparation processes and applicability were analyzed. Finally, several prospects for the current challenges faced by fibrous three-dimensional porous materials were proposed as follows: functionally modifying fibers to enhance their applicability through self-cross-linking; establishing theoretical models for the transmission of thermal energy, acoustic waves, and electromagnetic waves within fibrous porous materials; constructing fibrous porous materials resistant to impact, shear, and fracture to meet the needs of practical applications; developing multifunctional stealth fibrous porous materials to confer full-spectrum broadband stealth capability; and exploring the relationship between material size and mechanical properties as a basis for preparing large-scale samples that meet the application’s requirement. This review is very timely and aims to focus researchers’ attention on the importance and research progress of fibrous porous materials in the field of stealth protection, so as to solve the problems and challenges of fibrous porous materials in the field of stealth protection and to promote the further innovation of fibrous porous materials in terms of structure and function. Full article

The genome—the source of life and platform of evolution—is continuously exposed to harmful factors, both extra- and intra-cellular. Their activity causes different types of DNA damage, with approximately 80 different types of lesions having been identified so far. In this paper, the influence of a clustered DNA damage site containing imidazolone (Iz) or oxazolone (Oz) and 7,8-dihydro-8-oxo-2′-deoxyguanosine (^OXOdG) on the charge transfer through the double helix as well as their electronic properties were investigated. To this end, the structures of oligo-Iz, d[A₁Iz₂A₃^OXOG₄A₅]*d[T₅C₄T₃C₂T₁], and oligo-Oz, d[A₁Oz₂A₃^OXOG₄A₅]*d[T₅C₄T₃C₂T₁], were optimized at the M06-2X/6-D95**//M06-2X/sto-3G level of theory in the aqueous phase using the ONIOM methodology; all the discussed energies were obtained at the M06-2X/6-31++G** level of theory. The non-equilibrated and equilibrated solvent–solute interactions were taken into consideration. The following results were found: A) In all the discussed cases, ^OXOdG showed a higher predisposition to radical cation formation, and B) the excess electron migration toward Iz and Oz was preferred. However, in the case of oligo-Oz, the electron transfer from Oz₂ to complementary C₄ was noted during vertical to adiabatic anion relaxation, while for oligo-Iz, it was settled exclusively on the Iz₂ moiety. The above was reflected in the charge transfer rate constant, vertical/adiabatic ionization potential, and electron affinity energy values, as well as the charge and spin distribution. It can be postulated that imidazolone moiety formation within the CDL ds-oligo structure and its conversion to oxazolone can significantly influence the charge migration process, depending on the C2 carbon hybridization sp² or sp³. The above can confuse the single DNA damage recognition and removal processes, cause an increase in mutagenesis, and harm the effectiveness of anticancer therapy. Full article

This study focused on the detection of water inrush in tunnels excavated by full−section hard rock tunnel boring machines (TBMs) and employed ground penetrating radar methods for conducting research on radar signal processing algorithms. The research demonstrates that conventional techniques are inadequate for eliminating the interference of TBM equipment on radar signal propagation. This study employs a radar antenna array method for signal transmission, utilizing a wavelet double−threshold filtering algorithm and wave propagation theory to suppress clutter. These methods exhibit strong signal reception capabilities and are effective in eliminating 13.1% of the direct wave components. The adoption of a novel, efficient radar signal imaging algorithm simplifies the imaging process. Results of verification indicate that the synthetic aperture algorithm, enhanced with cross−correlation calculation, yields the optimal imaging effect. This investigation, which was conducted in conjunction with the construction of a diversion tunnel in a specific region, has confirmed the applicability of the ground penetrating radar method for the detection of water inrush in TBM tunnels by conducting a comparative analysis of the direct wave removal algorithm and the integration of the optimal imaging algorithm. The innovative application of ground penetrating radar within TBM tunnels, along with a targeted technology to mitigate signal interference from metal equipment, has led to the selection of an appropriate algorithm for both signal processing and imaging. This approach offers a novel solution for the detection of water source disasters in TBM tunnels. Full article

The energy consumption profiles of conventional fuelled and electric vehicles are different due to the fundamental differences in the driving characteristics of these vehicles, which have been actively researched elsewhere but mostly on the basis of uncommon geographical contexts. This study, therefore, collected driving data on electric and conventional diesel buses running along exactly the same set of bus routes in Hong Kong during normal daily revenue operations. This enabled a fair comparison of driving characteristics for both types of bus under identical real-life, on-road driving conditions, which highlighted the originality and contributions of this study. A three-step approach was adopted to carry out detailed driving pattern analyses, which included key driving parameters, speed–acceleration probability distributions (SAPDs), and vehicle-specific power (VSP) distributions. Results found that route-based comparisons did highlight important differences in driving patterns between electric and diesel buses that might have been smoothed out by analyses with mixed-route datasets. In particular, the spread, intensity, and directions of these differences were found to be exaggerated at the route-based level. The differences in driving patterns varied across different routes, which has significant implications on vehicle energy consumption. Government agencies and/or bus operators should make references to these results in formulating electric bus deployment plans. Full article

2,6-pyridine dicarboxylic acid (DPA) is an exceptional biomarker of notorious anthrax spores. Therefore, the rapid, sensitive, and selective quantitative detection of DPA is extremely significant and urgent. This paper reports a Zn(II) metal–organic framework with the formula of {[Zn₆(NDA)₆(DPBT)₃] 2H₂O·3DMF}_n (MOF-1), which consists of 2,6-naphthalenedicarboxylic acid (2,6-NDA), 4,7-di(4-pyridyl)-2,1,3-benzothiadiazole (DPBT), and Zn(II) ions. Structural analysis indicated that MOF-1 is a three-dimensional (3D) network which crystallized in the monoclinic system with the C2/c space group, revealing high pH, solvent, and thermal stability. Luminescence sensing studies demonstrated that MOF-1 had the potential to be a highly selective, sensitive, and recyclable fluorescence sensor for the identification of DPA. Furthermore, fluorescent test paper was made to detect DPA promptly with color changes. The enhancement mechanism was established by the hydrogen-bonding interaction and photoinduced electron transfer transition between MOF-1 and DPA molecules. Full article

The investigation of cycloaddition reactions involving acridine-based dipolarophiles revealed distinct regioselectivity patterns influenced mainly by the electronic factor. Specifically, the reactions of methyl-(2E)-3-(acridin-4-yl)-prop-2-enoate and 4-[(1E)-2-phenylethenyl]acridine with unstable benzonitrile N-oxides were studied. For methyl-(2E)-3-(acridin-4-yl)-prop-2-enoate, the formation of two regioisomers favoured the 5-(acridin-4-yl)-4,5-dihydro-1,2-oxazole-4-carboxylates, with remarkable exclusivity in the case of 4-methoxybenzonitrile oxide. Conversely, 4-[(1E)-2-phenylethenyl]acridine displayed reversed regioselectivity, favouring products 4-[3-(substituted phenyl)-5-phenyl-4,5-dihydro-1,2-oxazol-4-yl]acridine. Subsequent hydrolysis of isolated methyl 5-(acridin-4-yl)-3-phenyl-4,5-dihydro-1,2-oxazole-4-carboxylates resulted in the production of carboxylic acids, with nearly complete conversion. During NMR measurements of carboxylic acids in CDCl₃, decarboxylation was observed, indicating the formation of a new prochiral carbon centre C-4, further confirmed by a noticeable colour change. Overall, this investigation provides valuable insights into regioselectivity in cycloaddition reactions and subsequent transformations, suggesting potential applications across diverse scientific domains. Full article

Heavy metals such as copper, often discharged from industrial processes and agricultural activities, pose significant environmental and health risks due to their toxicity, particularly in the soluble form of Cu (II). This study investigates the effectiveness of biochar produced from date palm leaf midrib waste via a two-step pyrolysis process, as a sustainable and economical adsorbent for removing Cu (II) from aqueous solutions The biochar was characterized using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), Fourier-transform infrared spectroscopy (FTIR), and Brunauer–Emmett–Teller (BET) surface area analysis. Adsorption experiments were conducted to evaluate the effects of pH, adsorbent dosage, contact time, and initial Cu (II) concentration. The maximum adsorption capacity was observed at pH 6, with a capacity of 70 mg/g. The adsorption data were best described by the pseudo-second-order kinetic model, indicating chemisorption as the primary mechanism. Thermodynamic studies indicated that the adsorption process was spontaneous and exothermic, with a Gibbs free energy change (ΔG) of −1.245 kJ/mol at 25 °C, enthalpy change (ΔH) of −15.71 kJ/mol, and entropy change (ΔS) of 48.36 J/mol·K. Reusability tests demonstrated that the biochar retained over 85% of its initial adsorption capacity after five cycles, with capacities of 60 mg/g in the first cycle, decreasing to 52 mg/g by the fifth cycle. This study highlights the potential of biochar derived from date palm waste as an efficient, sustainable adsorbent for the removal of Cu (II) from wastewater, contributing to both environmental management and waste valorization. Future research should focus on optimizing the biochar production process and exploring its application for the removal of other contaminants. Full article

The Transforming Growth Factor-β (TGF-β) cascade plays a critical role in insect metamorphosis and involves cell-surface receptors known as type I and II, respectively (TβRI and TβRII). In Drosophila melanogaster, the TβRI receptor, Baboon (Babo), consists of three variants (BaboA, BaboB, and BaboC), each with isoform-specific functions. However, the isoforms and functional specifications of Babo in non-Drosophilid insects have not been established. Here, we examined babo transcripts from seven coleopteran species whose genomes have been published and found that mutually exclusive alternative splicing of the third exon produces three babo isoforms, identical to the Drosophila babo gene. The same three transcript variants were accordingly recognized from the transcriptome data of a coleopteran Henosepilachna vigintioctopunctata. RNA interference (RNAi)-mediated knockdown of all three babo transcripts at the fourth-instar larval stage hindered gut modeling and arrested larval development in H. vigintioctopunctata. All the resultant larvae became arrested prepupae; they were gradually dried and darkened and, eventually, died. Depletion of HvbaboA rather than HvbaboB or HvbaboC is similar to the phenotypic alterations caused by simultaneous RNAi of all three babo isoforms. Therefore, our results established diverged roles of the three Babo isoforms and highlighted the regulatory role of BaboA during larval-pupal transition in a non-Drosophilid insect species. Full article