The 2023 MDPI Annual Report has
been released!
 
23 pages, 7465 KiB  
Article
An Integrated Building Information Modeling and Life-Cycle Assessment Approach to Facilitate Design Decisions on Sustainable Building Projects in Canada
by Parsa Namaki, Bhavya Sree Vegesna, Saeide Bigdellou, Ruizhi Chen and Qian Chen
Sustainability 2024, 16(11), 4718; https://doi.org/10.3390/su16114718 (registering DOI) - 1 Jun 2024
Abstract
In the context of the digital and sustainable transformation of building projects, the integrated approach of Building Information Modeling (BIM) and life-cycle assessment (LCA) has been widely studied. Recent advancements in such integrated modeling processes and techniques have not yet provided reliable and [...] Read more.
In the context of the digital and sustainable transformation of building projects, the integrated approach of Building Information Modeling (BIM) and life-cycle assessment (LCA) has been widely studied. Recent advancements in such integrated modeling processes and techniques have not yet provided reliable and robust decision-making capabilities for designers to intuitively choose between material alternatives. This study develops a new design framework that integrates BIM, LCA, and multi-criteria decision-making (MCDM) algorithms to facilitate sustainable design processes in building projects. A case study using a single-family housing project in the British Columbia province of Canada was implemented to test the designs to demonstrate the effectiveness of the proposed integrated framework, including a three-way comparison of design scenarios—conventional hot-roll steel, recycled steel, and timber. The results indicate a significant performance improvement with the adoption of recycled structural steel materials, surpassing conventional steel designs and demonstrating a similar performance to that of timber designs. The study underscores the importance of informed decision-making in material selection, driven by the quantitative analysis of digital designs and multi-criteria evaluation (e.g., social carbon cost). This integrated framework offers a valuable tool for designers, engineers, and builders to achieve sustainability when designing building projects through the systematic and rapid comparison of environmental performance. Full article
(This article belongs to the Special Issue Advances of Sustainability Research: A Canadian Perspective)
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13 pages, 7096 KiB  
Article
Microstructure and Biocompatibility of Graphene oxide/BCZT Composite Ceramics via Fast Hot-Pressed Sintering
by Bingqing Zhao, Qibin Liu, Geng Tang and Dunying Wang
Coatings 2024, 14(6), 689; https://doi.org/10.3390/coatings14060689 (registering DOI) - 1 Jun 2024
Abstract
Improving fracture toughness, electrical conductivity, and biocompatibility has consistently presented challenges in the development of artificial bone replacement materials. This paper presents a new strategy for creating high-performance, multifunctional composite ceramic materials by doping graphene oxide (GO), which is known to induce osteoblast [...] Read more.
Improving fracture toughness, electrical conductivity, and biocompatibility has consistently presented challenges in the development of artificial bone replacement materials. This paper presents a new strategy for creating high-performance, multifunctional composite ceramic materials by doping graphene oxide (GO), which is known to induce osteoblast differentiation and enhance cell adhesion and proliferation into barium calcium zirconate titanate (BCZT) ceramics that already exhibit good mechanical properties, piezoelectric effects, and low cytotoxicity. Using fast hot-pressed sintering under vacuum conditions, (1 − x)(Ba0.85Ca0.15Zr0.1Ti0.9)O3−xGO (0.2 mol% ≤ x ≤ 0.5 mol%) composite piezoelectric ceramics were successfully synthesized. Experimental results revealed that these composite ceramics exhibited high piezoelectric properties (d33 = 18 pC/N, kp = 62%) and microhardness (173.76 HV0.5), meeting the standards for artificial bone substitutes. Furthermore, the incorporation of graphene oxide significantly reduced the water contact angle and enhanced their wettability. Cell viability tests using Cell Counting Kit-8, alkaline phosphatase staining, and DAPI staining demonstrated that the GO/BCZT composite ceramics were non-cytotoxic and effectively promoted cell proliferation and growth, indicating excellent biocompatibility. Consequently, with their superior mechanical properties, piezoelectric performance, and biocompatibility, GO/BCZT composite ceramics show extensive potential for application in bone defect repair. Full article
(This article belongs to the Special Issue Advances of Ceramic and Alloy Coatings, 2nd Edition)
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18 pages, 587 KiB  
Article
On the Construct of Subjective Risk Intelligence and its Relationships with Personality, Emotional Intelligence and Coping Strategies: A Comparison between Adolescents and Adults
by Maria Guarnera, Rita Zarbo, Stefania Lucia Buccheri and Paola Magnano
Eur. J. Investig. Health Psychol. Educ. 2024, 14(6), 1543-1560; https://doi.org/10.3390/ejihpe14060102 (registering DOI) - 1 Jun 2024
Abstract
The complexity of today’s scenario has made it necessary to investigate the need for individuals to make choices that entail increasing exposure to risk and uncertainty. Among the individual resources that could help people to cope with situations of uncertainty, the new construct [...] Read more.
The complexity of today’s scenario has made it necessary to investigate the need for individuals to make choices that entail increasing exposure to risk and uncertainty. Among the individual resources that could help people to cope with situations of uncertainty, the new construct of subjective risk intelligence (SRI), known as a person’s ability to effectively weigh the pros and cons of a decision in situations where not all the outcomes are foreseen, would seem to play a prominent role. Considering that personality and coping strategies have been shown to be significantly related in previous research, the present study investigates the relationships between subjective risk intelligence, emotional intelligence, personality traits and coping strategies in both adults and adolescents. This cross-sectional study was conducted on 1390 Italian people, divided into two subsamples of 641 adolescents and 749 adults. The results showed that SRI mediated the roles that personality traits and emotional intelligence have in coping strategies differently in the adult sample, in which the mediating role of SRI was found for avoidance coping, and in the adolescent sample, in which SRI influenced all of the antecedents analysed in the study for almost all of the identified coping strategies. In light of these findings, subjective risk intelligence could be activated to deal with uncertain and risky situations, influencing the choice of effective or ineffective strategies in both adults and adolescents. Full article
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11 pages, 854 KiB  
Article
A Terahertz Programmable Digital Metasurface Based on Vanadium Dioxide
by Tianrui Pan, Chenxi Liu, Shuang Peng, Haiying Lu, Han Zhang, Xiaoming Xu and Fei Yang
Photonics 2024, 11(6), 527; https://doi.org/10.3390/photonics11060527 (registering DOI) - 1 Jun 2024
Abstract
Metasurfaces can realize the flexible manipulation of electromagnetic waves, which have the advantages of a low profile and low loss. In particular, the coding metasurface can flexibly manipulate electromagnetic waves through controllable sequence encoding of the coding units to achieve different functions. In [...] Read more.
Metasurfaces can realize the flexible manipulation of electromagnetic waves, which have the advantages of a low profile and low loss. In particular, the coding metasurface can flexibly manipulate electromagnetic waves through controllable sequence encoding of the coding units to achieve different functions. In this paper, a three−layer active coding metasurface is designed based on vanadium dioxide (VO2), which has an excellent phase transition. For the designed unit cell, the top patterned layer is composed of two split square resonant rings (SSRRs), whose gaps are in opposite directions, and each SSRR is composed of gold and VO2. When VO2 changes from the dielectric state to the metal state, the resonant mode changes from microstrip resonance to LC resonance, correspondingly. According to the Pancharatnam−Berry (P−B) phase, the designed metasurface can actively control terahertz circularly polarized waves in the near field. The metasurface can manipulate the order of the generated orbital angular momentum (OAM) beams: when the dielectric VO2 changes to metal VO2, the order l of the OAM beams generated by the metasurface changes from −1 to −2, and the purity of the generated OAM beams is relatively high. It is expected to have important application values in terahertz wireless communication, radar, and other fields. Full article
(This article belongs to the Special Issue Emerging Trends in Metamaterials and Metasurfaces Research)
14 pages, 5621 KiB  
Article
Robertsonian Translocation between Human Chromosomes 21 and 22, Inherited across Three Generations, without Any Phenotypic Effect
by Concetta Federico, Desiree Brancato, Francesca Bruno, Daiana Galvano, Mariella Caruso and Salvatore Saccone
Genes 2024, 15(6), 722; https://doi.org/10.3390/genes15060722 (registering DOI) - 1 Jun 2024
Abstract
Chromosomal translocations can result in phenotypic effects of varying severity, depending on the position of the breakpoints and the rearrangement of genes within the interphase nucleus of the translocated chromosome regions. Balanced translocations are often asymptomatic phenotypically and are typically detected due to [...] Read more.
Chromosomal translocations can result in phenotypic effects of varying severity, depending on the position of the breakpoints and the rearrangement of genes within the interphase nucleus of the translocated chromosome regions. Balanced translocations are often asymptomatic phenotypically and are typically detected due to a decrease in fertility resulting from issues during meiosis. Robertsonian translocations are among the most common chromosomal abnormalities, often asymptomatic, and can persist in the population as a normal polymorphism. We serendipitously discovered a Robertsonian translocation between chromosome 21 and chromosome 22, which is inherited across three generations without any phenotypic effect, notably only in females. In situ hybridization with alpha-satellite DNAs revealed the presence of both centromeric sequences in the translocated chromosome. The reciprocal translocation resulted in a partial deletion of the short arm of both chromosomes 21, and 22, with the ribosomal RNA genes remaining present in the middle part of the new metacentric chromosome. The rearrangement did not cause alterations to the long arm. The spread of an asymptomatic heterozygous chromosomal polymorphism in a population can lead to mating between heterozygous individuals, potentially resulting in offspring with a homozygous chromosomal configuration for the anomaly they carry. This new karyotype may not produce phenotypic effects in the individual who presents it. The frequency of karyotypes with chromosomal rearrangements in asymptomatic heterozygous form in human populations is likely underestimated, and molecular karyotype by array Comparative Genomic Hybridization (array-CGH) analysis does not allow for the identification of this type of chromosomal anomaly, making classical cytogenetic analysis the preferred method for obtaining clear results on a karyotype carrying a balanced rearrangement. Full article
(This article belongs to the Special Issue Chromosomal Rearrangements in the Light of Evolutionary Genomics)
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13 pages, 3825 KiB  
Article
Flexural Behavior of Partially Encased Composite Beams with a Large Tensile Reinforcement Ratio
by Yuchen Jiang, Xiamin Hu, Hao Zheng and Haoyang Shuai
Buildings 2024, 14(6), 1606; https://doi.org/10.3390/buildings14061606 (registering DOI) - 1 Jun 2024
Abstract
Partially encased composite beams (PECBs) have advantages over conventional steel–concrete composite beams in load-carrying capacity, flexural stiffness and fire resistance. In order to determine whether the shearing force is sufficient to ensure the yield of the tensile reinforcement in the case of a [...] Read more.
Partially encased composite beams (PECBs) have advantages over conventional steel–concrete composite beams in load-carrying capacity, flexural stiffness and fire resistance. In order to determine whether the shearing force is sufficient to ensure the yield of the tensile reinforcement in the case of a large tensile reinforcement ratio, as well as the influence of encasing concrete strength and the addition of studs on the steel web, three PECB specimens were tested under bending. The results show that, in the case of a 5% tensile reinforcement ratio, natural bonding and friction forces ensure the yield of tensile reinforcement whether studs are added on the steel web or not. The encasing concrete strength and the addition of studs on the steel web have no obvious effect on both the elastic and plastic bending resistance of PECBs. The addition of studs on the steel web significantly slows down the stiffness deterioration of PECBs within the elastoplastic stage, while the flexural stiffness is not obviously affected by the strength of encasing concrete. The simplified plastic theory is proved to be applicable to predict the flexural capacity of PECBs with a large tensile reinforcement ratio. It is also indicated by calculation that, by increasing the tensile reinforcement ratio from 2% to 5%, the flexural capacity of PECBs has a significant increase, by about 32%. Full article
(This article belongs to the Section Building Structures)
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13 pages, 8901 KiB  
Article
A pH-Responsive Polycaprolactone–Copper Peroxide Composite Coating Fabricated via Suspension Flame Spraying for Antimicrobial Applications
by Tingting Cui, Daofeng Zhou, Yu Zhang, Decong Kong, Zhijuan Wang, Zhuoyue Han, Meiqi Song, Xierzhati Aimaier, Yanxin Dan, Botao Zhang and Hua Li
Materials 2024, 17(11), 2666; https://doi.org/10.3390/ma17112666 (registering DOI) - 1 Jun 2024
Abstract
In this study, a pH-responsive polycaprolactone (PCL)–copper peroxide (CuO2) composite antibacterial coating was developed by suspension flame spraying. The successful synthesis of CuO2 nanoparticles and fabrication of the PCL-CuO2 composite coatings were confirmed by microstructural and chemical analysis. The [...] Read more.
In this study, a pH-responsive polycaprolactone (PCL)–copper peroxide (CuO2) composite antibacterial coating was developed by suspension flame spraying. The successful synthesis of CuO2 nanoparticles and fabrication of the PCL-CuO2 composite coatings were confirmed by microstructural and chemical analysis. The composite coatings were structurally homogeneous, with the chemical properties of PCL well maintained. The acidic environment was found to effectively accelerate the dissociation of CuO2, allowing the simultaneous release of Cu2+ and H2O2. Antimicrobial tests clearly revealed the enhanced antibacterial properties of the PCL-CuO2 composite coating against both Escherichia coli and Staphylococcus aureus under acidic conditions, with a bactericidal effect of over 99.99%. This study presents a promising approach for constructing pH-responsive antimicrobial coatings for biomedical applications. Full article
(This article belongs to the Special Issue New Advances in Functionalization of Metal Materials)
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11 pages, 2052 KiB  
Article
Radiographic Assessment of Transverse Tarsometatarsal Instability Complicated by Metatarsus Adductus in Hallux Valgus Patients
by Shun-Ping Wang, Cheng-Min Shih, Yu-Hsien Wu and Yuan-Shao Chen
Life 2024, 14(6), 718; https://doi.org/10.3390/life14060718 (registering DOI) - 1 Jun 2024
Abstract
Objective evaluations of transverse tarsometatarsal (TMT) hypermobility/instability are lacking. This study aims to radiographically explore the relationship between transverse TMT instability and metatarsus adductus (MA) in hallux valgus (HV). This study retrospectively analyzed 207 feet with varying degrees of HV, employing the distance [...] Read more.
Objective evaluations of transverse tarsometatarsal (TMT) hypermobility/instability are lacking. This study aims to radiographically explore the relationship between transverse TMT instability and metatarsus adductus (MA) in hallux valgus (HV). This study retrospectively analyzed 207 feet with varying degrees of HV, employing the distance between the first and second metatarsals (M1-2 distance) to assess transverse TMT instability of the first ray. Participants were categorized into MA and non-MA groups. It was found that the M1-2 distance significantly increased with the hallux valgus angle (HVA) and metatarsus adductus angle (MAA), demonstrating significant differences between the MA and non-MA groups. The measurement of M1-2 distance showed high reliability, and its cutoff value was determined to be 4.05 mm. Additionally, the results suggest that the widening of the M1-2 distance may be a predisposing factor for MA in HV patients, highlighting its role in the pathogenesis of this foot condition. These findings highlight the need for a comprehensive assessment of TMT instability on both the axial and sagittal planes for the surgical planning of HV, particularly when complicated by a large MAA. Based on these insights, reoriented first-TMT arthrodesis might be recommended for HV with significant MA to address potential multiplanar instability. Full article
(This article belongs to the Special Issue Studies and Treatments in Foot and Ankle Surgery)
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16 pages, 3407 KiB  
Article
Performance Projection of Vacuum Gate Dielectric Doping-Free Carbon Nanoribbon/Nanotube Field-Effect Transistors for Radiation-Immune Nanoelectronics
by Khalil Tamersit, Abdellah Kouzou, José Rodriguez and Mohamed Abdelrahem
Nanomaterials 2024, 14(11), 962; https://doi.org/10.3390/nano14110962 (registering DOI) - 1 Jun 2024
Abstract
This paper investigates the performance of vacuum gate dielectric doping-free carbon nanotube/nanoribbon field-effect transistors (VGD-DL CNT/GNRFETs) via computational analysis employing a quantum simulation approach. The methodology integrates the self-consistent solution of the Poisson solver with the mode space non-equilibrium Green’s function (NEGF) in [...] Read more.
This paper investigates the performance of vacuum gate dielectric doping-free carbon nanotube/nanoribbon field-effect transistors (VGD-DL CNT/GNRFETs) via computational analysis employing a quantum simulation approach. The methodology integrates the self-consistent solution of the Poisson solver with the mode space non-equilibrium Green’s function (NEGF) in the ballistic limit. Adopting the vacuum gate dielectric (VGD) paradigm ensures radiation-hardened functionality while avoiding radiation-induced trapped charge mechanisms, while the doping-free paradigm facilitates fabrication flexibility by avoiding the realization of a sharp doping gradient in the nanoscale regime. Electrostatic doping of the nanodevices is achieved via source and drain doping gates. The simulations encompass MOSFET and tunnel FET (TFET) modes. The numerical investigation comprehensively examines potential distribution, transfer characteristics, subthreshold swing, leakage current, on-state current, current ratio, and scaling capability. Results demonstrate the robustness of vacuum nanodevices for high-performance, radiation-hardened switching applications. Furthermore, a proposal for extrinsic enhancement via doping gate voltage adjustment to optimize band diagrams and improve switching performance at ultra-scaled regimes is successfully presented. These findings underscore the potential of vacuum gate dielectric carbon-based nanotransistors for ultrascaled, high-performance, energy-efficient, and radiation-immune nanoelectronics. Full article
(This article belongs to the Section Nanoelectronics, Nanosensors and Devices)
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17 pages, 15996 KiB  
Article
Temporal Evolution, Oscillation and Coherence Characteristics Analysis of Global Solar Radiation Distribution in Major Cities in China’s Solar-Energy-Available Region Based on Continuous Wavelet Transform
by Haowen Xue, Guoxin Li, Dawei Qi and Haiming Ni
Appl. Sci. 2024, 14(11), 4794; https://doi.org/10.3390/app14114794 (registering DOI) - 1 Jun 2024
Abstract
The majority of the energy required for human survival is derived either directly or indirectly from solar radiation, thus it is important to investigate the periodic fluctuations in global solar radiation over time. In this study, six cities—Harbin, Shenyang, Beijing, Shanghai, Wuhan, and [...] Read more.
The majority of the energy required for human survival is derived either directly or indirectly from solar radiation, thus it is important to investigate the periodic fluctuations in global solar radiation over time. In this study, six cities—Harbin, Shenyang, Beijing, Shanghai, Wuhan, and Guangzhou—located in the utilizable areas of solar energy in China, were selected, and the periodicity of the daily global solar radiation of these six cities with time were investigated by means of wavelet power spectrum analysis. Furthermore, Harbin, which has the lowest monthly average of global solar radiation in the cold of winter, was selected to explore the temporal evolution relationship between global solar radiation and other meteorological factors, and air quality factors by wavelet coherence analysis. Among the meteorological factors, the correlation between global solar radiation and sunshine duration exhibits the highest level of consistency. Global solar radiation demonstrates a positive association with atmospheric temperature/wind speed/precipitation over the annual cycle. Conversely, it displays a negative correlation with atmospheric pressure during this time frame. Additionally, on shorter timescales, global solar radiation is negatively correlated with air humidity and precipitation. Among air quality factors, the relationship between global solar radiation and CO/NO2/O3/PM2.5/PM10/SO2 primarily manifests in the broader annual cycle time scale. Within this context, global solar radiation shows a positive correlation with O3, while displaying negative associations with the other five air quality indicators. These findings contribute to urban environmental planning and the effective management and utilization of solar radiation, thereby providing valuable insights to guide the future development of cross-regional comprehensive energy utilization projects under diverse climatic and geographical conditions. Additionally, they serve as a reference for subsequent research aimed at enhancing the accuracy of global solar radiation prediction models. Full article
(This article belongs to the Section Environmental Sciences)
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17 pages, 2268 KiB  
Review
Tropical Shrimp Biofloc Aquaculture within Greenhouses in the Mediterranean: Preconditions, Perspectives, and a Prototype Description
by Dimitrios K. Papadopoulos, Maria V. Alvanou, Athanasios Lattos, Kosmas Ouroulis and Ioannis A. Giantsis
Fishes 2024, 9(6), 208; https://doi.org/10.3390/fishes9060208 (registering DOI) - 1 Jun 2024
Abstract
Biofloc technology (BFT) offers an innovative eco-friendly approach that is particularly applicable in shrimp farming. Penaeus vannamei is the most important seafood species in terms of global economic value. Nevertheless, its increasing global demand highlights the necessity for sustainable production of P. vannamei [...] Read more.
Biofloc technology (BFT) offers an innovative eco-friendly approach that is particularly applicable in shrimp farming. Penaeus vannamei is the most important seafood species in terms of global economic value. Nevertheless, its increasing global demand highlights the necessity for sustainable production of P. vannamei shrimps outside their native range, assuring the avoidance of genetic pollution risk. Towards this direction, the present study focuses on the feasibility of tropical shrimp species aquaculture in indoor systems evaluating BFT application in temperate zones. The achievability of P. vannamei cultivation inside greenhouses in temperate latitudes is thoroughly examined and a representative experimental biofloc setup for P. vannamei within a greenhouse in Northern Greece is demonstrated. Nevertheless, there are two major limitations, related to economy and ecology, namely the energy demand for high seawater temperature and the fact that most reared shrimps are non-indigenous species setting risk for genetic pollution, respectively. To overcome the former, energy-saving measures such as tank and greenhouse insulation in combination with a microclimate chamber construction were implemented to optimize water temperature at minimal cost. Concerning the latter, there is clear evidence that P. vannamei populations cannot be established in the Mediterranean, setting aside any environmental risk. Overall, based on the developed and tested pilot prototype, employment of optimal management practices, innovative manufacturing and clean energy alternatives, and the utilization of ecosystem services could reduce the environmental impact and maximize the profitability of biofloc operations. These actions could probably permit sustainable and economically viable farming of P. vannamei employing BFT within greenhouses in the Mediterranean. Full article
(This article belongs to the Special Issue Advances in Shrimp Aquaculture)
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15 pages, 9156 KiB  
Article
The Effect of Preheating Temperature on the Corrosion Resistance and Porosity Defects Development Behaviour of Ni60A Coating
by Fule Huang, Chen Li, Hailin Guo, Shuqin Huang, Fanghai Ling and Qijun Fu
Coatings 2024, 14(6), 688; https://doi.org/10.3390/coatings14060688 (registering DOI) - 1 Jun 2024
Abstract
The laser cladding of nickel-based fusion alloys makes them prone to cracks and defects that affect the overall performance of the coating. In this study, Ni60A coatings were prepared at different preheating temperatures (25 °C, 200 °C, 400 °C and 600 °C). The [...] Read more.
The laser cladding of nickel-based fusion alloys makes them prone to cracks and defects that affect the overall performance of the coating. In this study, Ni60A coatings were prepared at different preheating temperatures (25 °C, 200 °C, 400 °C and 600 °C). The effect of the preheating temperature of the substrate on the corrosion resistance of the coating as well as on the development of defects were investigated by electrochemical tests and immersion experiments in a 65 wt% H2SO4 solution at 60 °C. The results indicate that preheating the substrate to 200 °C can completely eliminate cracks in the coating and reduce porosity. Preheating leads to a decrease in the corrosion resistance of the coating. The size of the porosity defects is related to the law of longitudinal development of the defects. Porosity defects with diameters smaller than 100 μm have a more pronounced tendency to expand vertically than those with diameters larger than 100 μm. Full article
(This article belongs to the Section Corrosion, Wear and Erosion)
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18 pages, 13836 KiB  
Article
The Performance of Agronomic and Quality Traits of Quinoa under Different Altitudes in Northwest of China
by Hongliang Cui, Qing Yao, Bao Xing, Bangwei Zhou, Syed Sadaqat Shah and Peiyou Qin
Agronomy 2024, 14(6), 1194; https://doi.org/10.3390/agronomy14061194 (registering DOI) - 1 Jun 2024
Abstract
Quinoa is a resilient crop known for its adaptability to diverse environmental conditions. This study examined the agronomic performance and ecological adaptability of quinoa across four distinct altitudes in the northwestern regions of China. Six quinoa genotypes were assessed for agronomic traits, phenology [...] Read more.
Quinoa is a resilient crop known for its adaptability to diverse environmental conditions. This study examined the agronomic performance and ecological adaptability of quinoa across four distinct altitudes in the northwestern regions of China. Six quinoa genotypes were assessed for agronomic traits, phenology and yield performances, and nutritional quality characteristics in Yining city, Nilka County, Tekes County and Zhaosu County under varied environmental conditions. Our findings demonstrate significant variations in all measured traits, including agronomic and nutritional quality traits, across the various altitudes and genotypes. In Yining city, a warmer and lower altitude area, genotypes exhibit superior traits for fodder production, including increased branches, longer panicles, robust stems, and high seed protein content. Genotypes Jinli 1 and Beijing 2 achieve yields exceeding 3 tons per hectare (t/ha), highlighting the region’s productivity. The Nilka and Tekes counties boasted the shortest quinoa crop cycles, with Jinli 1 yielding 4.05 t/ha seeds in Tekes County, exhibiting high protein and fat content alongside low saponins, making it a prime location for yield production. Zhaosu County, with its cooler climate and fertile chernozem soil, elicited high 1000 seed weight and more robust protein response than Nilka and Tekes counties, illustrating the impact of soil fertility on nutritional composition. Correlation analyses further elucidated that the plants characterized by shorter flowering times, crop cycles, compact inflorescence, and taller heights exhibited superior seed yields. Our study contributes significant insights into the ecological adaptability and nutritional dynamics of quinoa, with implications for sustainable crop production and food security in diverse agroecosystems. Full article
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12 pages, 1709 KiB  
Communication
Universal Software Only Radar with All Waveforms Simultaneously on a Single Platform
by Vitali Kozlov, Anton Kharchevskii, Eran Rebenshtok, Vjaceslavs Bobrovs, Toms Salgals and Pavel Ginzburg
Remote Sens. 2024, 16(11), 1999; https://doi.org/10.3390/rs16111999 (registering DOI) - 1 Jun 2024
Abstract
Abstract: While software-defined radars can switch their transmitted waveform on the go, they cannot transmit all waveforms at the same time, meaning they must balance the advantages and drawbacks of each configuration. Here, we propose theoretically and demonstrate experimentally the universal radar, which [...] Read more.
Abstract: While software-defined radars can switch their transmitted waveform on the go, they cannot transmit all waveforms at the same time, meaning they must balance the advantages and drawbacks of each configuration. Here, we propose theoretically and demonstrate experimentally the universal radar, which can apply the desired waveform in the post-processing stage after the physical measurement has been performed. This method also allows using a single measurement of a scene to design and test any other radar in complex scenarios without having to take it to the field. The method is based on post-processing the frequency response measured by a synthetically broadband stepped-frequency continuous wave radar, such as a vector network analyzer. An algorithm for overcoming distortions due to moving targets is derived as well. This approach not only provides an ultra-wideband software-only defined radar, but it also enables the acquired data from any measured site to be used for the design and analysis of almost any other future radar system, significantly cutting the time and cost of new developments. The method suggests the creation of radar raw data repositories that can be shared across diversely different radar platforms. Full article
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13 pages, 3321 KiB  
Article
Pilot Assistance Systems for Energy-Optimized Approaches: Is It Possible to Reduce Fuel Consumption and Noise at the Same Time?
by Jean Marc Wunderli, Jonas Meister, Johan Boyer, Martin Gerber, Tobias Bauer and Fethi Abdelmoula
Aerospace 2024, 11(6), 450; https://doi.org/10.3390/aerospace11060450 (registering DOI) - 1 Jun 2024
Abstract
Air traffic has appreciable environmental impacts, especially regarding gaseous emissions and noise. Recent studies have shown that the energy management during approach is a driving factor regarding environmental impact and is especially challenging for pilots. In a previous project, a newly developed pilot [...] Read more.
Air traffic has appreciable environmental impacts, especially regarding gaseous emissions and noise. Recent studies have shown that the energy management during approach is a driving factor regarding environmental impact and is especially challenging for pilots. In a previous project, a newly developed pilot assistance system called LNAS (Low Noise Augmentation System) showed the potential of energy-optimized approaches to reduce fuel consumption and noise. Within the SESAR Exploratory Research project DYNCAT, novel functions based on LNAS have been integrated in the flight management system. In this contribution, results from real-time simulations with the enhanced FMS are presented, and mitigation of the environmental impact is analyzed. It was shown that with DYNCAT, the energy management could be improved, resulting in a later configuration and engines mostly in idle. With DYNCAT, procedures were also flown more uniformly and the variability in noise and fuel outcomes was reduced. However, the results revealed a trade-off for optimizing noise and fuel consumption simultaneously, whereby both parameters can be improved along specific optimum curves. A perfect strategy to minimize noise would be to first reduce speed and only secondly height, as high speeds lead to higher levels of airframe noise and sound exposure increases with decreasing distance. In contrast, saving fuel might be achieved by reducing the flight time, as the engines consume fuel even when being in idle. Full article
19 pages, 3165 KiB  
Article
Genomic Characterization of Preclinical Prostate Cancer Cell Line Models
by Erica L. Beatson, Emily N. Risdon, Giulia C. Napoli, Douglas K. Price, Cindy H. Chau and William D. Figg
Int. J. Mol. Sci. 2024, 25(11), 6111; https://doi.org/10.3390/ijms25116111 (registering DOI) - 1 Jun 2024
Abstract
As we move into the era of precision medicine, the growing relevance of genetic alterations to prostate cancer (PCa) development and treatment demonstrates the importance of characterizing preclinical models at the genomic level. Our study investigated the genomic characterization of eight PCa cell [...] Read more.
As we move into the era of precision medicine, the growing relevance of genetic alterations to prostate cancer (PCa) development and treatment demonstrates the importance of characterizing preclinical models at the genomic level. Our study investigated the genomic characterization of eight PCa cell lines to understand which models are clinically relevant. We designed a custom AmpliSeq DNA gene panel that encompassed key molecular pathways targeting AR signaling, apoptosis, DNA damage repair, and PI3K/AKT/PTEN, in addition to tumor suppressor genes. We examined the relationship between cell line genomic alterations and therapeutic response. In addition, using DepMap’s Celligner tool, we identified which preclinical models are most representative of specific prostate cancer patient populations on cBioPortal. These data will help investigators understand the genetic differences in preclinical models of PCa and determine which ones are relevant for use in their translational research. Full article
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12 pages, 4304 KiB  
Article
Bicolor Tuning and Hyper-Reflective Color Switching Based on Two Stacked Cholesteric Liquid Crystal Cells with Asymmetric Electrothermal Optical Responses
by Hsin-Kai Tseng, Po-Chang Wu and Wei Lee
Molecules 2024, 29(11), 2607; https://doi.org/10.3390/molecules29112607 (registering DOI) - 1 Jun 2024
Abstract
We propose a double-cell cholesteric liquid crystal (CLC) device composed of a left-handed (LH) CLC cell with a pair of sheet electrodes and a right-handed (RH) CLC cell with a tri-electrode configuration characterized by a sheet electrode on the top and an interdigitated [...] Read more.
We propose a double-cell cholesteric liquid crystal (CLC) device composed of a left-handed (LH) CLC cell with a pair of sheet electrodes and a right-handed (RH) CLC cell with a tri-electrode configuration characterized by a sheet electrode on the top and an interdigitated electrode on the bottom substrates. Bi-reflected color tuning and hyper-reflective color switching are revealed from this cell stack via the electrothermal control of the central wavelengths of the LH- and RH-bandgaps by voltage-induced pseudo-dielectric heating. The two CLCs are thermally sensitive and exhibit overlapped bandgaps in the field-off state with nearly identical temperature dependence, resulting in a hyper-reflective color at 720 nm at 23.4 °C and 380 nm at 29.8 °C. Upon the application of 4 Vrms at 2 MHz across the stacked device to induce pseudo-dielectric heating, two reflective colors can be resolved due to asymmetrical temperature elevations. Accordingly, the difference in wavelength between the two colors increases with increasing voltage through a series cell connection, while maintaining approximately constant via a parallel connection. This study provides a feasible pathway to developing a multifunctional device with electrothermally tunable bi-reflected and hyper-reflective states based on two conventional cell geometries, which is promising for lasers and color-related display applications. Full article
(This article belongs to the Special Issue Liquid Crystals II)
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13 pages, 4662 KiB  
Article
In Situ Synthesis of CsPbX3/Polyacrylonitrile Nanofibers with Water-Stability and Color-Tunability for Anti-Counterfeiting and LEDs
by Yinbiao Shi, Xiaojia Su, Xiaoyan Wang and Mingye Ding
Polymers 2024, 16(11), 1568; https://doi.org/10.3390/polym16111568 (registering DOI) - 1 Jun 2024
Abstract
Inorganic CsPbX3 (X = Cl, Br, I) perovskite quantum dots (PQDs) have attracted widespread attention due to their excellent optical properties and extensive application prospects. However, their inherent structural instability significantly hinders their practical application despite their outstanding optical performance. To enhance [...] Read more.
Inorganic CsPbX3 (X = Cl, Br, I) perovskite quantum dots (PQDs) have attracted widespread attention due to their excellent optical properties and extensive application prospects. However, their inherent structural instability significantly hinders their practical application despite their outstanding optical performance. To enhance stability, an in situ electrospinning strategy was used to synthesize CsPbX3/polyacrylonitrile composite nanofibers. By optimizing process parameters (e.g., halide ratio, electrospinning voltage, and heat treatment temperature), all-inorganic CsPbX3 PQDs have been successfully grown in a polyacrylonitrile (PAN) matrix. During the electrospinning process, the rapid solidification of electrospun fibers not only effectively constrained the formation of large-sized PQDs but also provided effective physical protection for PQDs, resulting in the improvement in the water stability of PQDs by minimizing external environmental interference. Even after storage in water for over 100 days, the PQDs maintained approximately 93.5% of their photoluminescence intensity. Through the adjustment of halogen elements, the as-obtained composite nanofibers exhibited color-tunable luminescence in the visible light region, and based on this, a series of multicolor anti-counterfeiting patterns were fabricated. Additionally, benefiting from the excellent water stability and optical performance, the CsPbBr3/PAN composite film was combined with red-emitting K2SiF6:Mn4+ (KSF) on a blue LED (460 nm), producing a stable and efficient WLED device with a color temperature of around 6000 K and CIE coordinates of (0.318, 0.322). These results provide a general approach to synthesizing PQDs/polymer nanocomposites with excellent water stability and multicolor emission, thereby promoting their practical applications in multifunctional optoelectronic devices and advanced anti-counterfeiting. Full article
(This article belongs to the Special Issue New Advances in Polymer Electrospun Fibers)
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17 pages, 1360 KiB  
Article
Combining the Elicitor Up-Regulated Production of Unusual Linear Diterpene-Derived Variants for an In-Depth Assessment of the Application Value and Risk of the Medicinal and Edible Basidiomycete Schizophyllum commune
by Ying Wang, Fei Cao, Luning Zhou, Hanwei Liu, Hua Gao, Ge Cui, Changshan Niu, Peng Zhang, Dehai Li, Songqi Liu, Yan Jiang and Guangwei Wu
Molecules 2024, 29(11), 2608; https://doi.org/10.3390/molecules29112608 (registering DOI) - 1 Jun 2024
Abstract
To better assess the practical value and avoid potential risks of the traditionally medicinal and edible basidiomycete Schizophyllum commune, which may arise from undescribed metabolites, a combination of elicitors was introduced for the first time to discover products from cryptic and low-expressed [...] Read more.
To better assess the practical value and avoid potential risks of the traditionally medicinal and edible basidiomycete Schizophyllum commune, which may arise from undescribed metabolites, a combination of elicitors was introduced for the first time to discover products from cryptic and low-expressed gene clusters under laboratory cultivation. Treating S. commune NJFU21 with the combination of five elicitors led to the upregulated production of a class of unusual linear diterpene-derived variants, including eleven new ones (111), along with three known ones (1214). The structures and stereochemistry were determined by 1D and 2D NMR, HRESIMS, ECD, OR and VCD calculations. Notably, the elongation terminus of all the diterpenes was decorated by an unusual butenedioic acid moiety. Compound 1 was a rare monocyclic diterpene, while 26 possessed a tetrahydrofuran moiety. The truncated metabolites 4, 5 and 13 belong to the trinorditerpenes. All the diterpenes displayed approximately 70% scavenging of hydroxyl radicals at 50 μM and null cytotoxic activity at 10 μM. In addition, compound 1 exhibited potent antifungal activity against the plant pathogenic fungi Colletotrichum camelliae, with MIC values of 8 μg/mL. Our findings indicated that this class of diterpenes could provide valuable protectants for cosmetic ingredients and the lead compounds for agricultural fungicide development. Full article
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14 pages, 2065 KiB  
Article
Criticality of Spray Solvent Choice on the Performance of Next Generation, Spray-Based Ambient Mass Spectrometric Ionization Sources: A Case Study Based on Synthetic Cannabinoid Forensic Evidence
by Shahnaz Mukta, Ebenezer H. Bondzie, Sara E. Bell, Chase Deberry and Christopher C. Mulligan
Instruments 2024, 8(2), 34; https://doi.org/10.3390/instruments8020034 (registering DOI) - 1 Jun 2024
Abstract
Mass spectrometry (MS) is a highly selective and sensitive analytical tool with a myriad of applications, but such techniques are typically used in laboratory settings due to the handling and preparations that are necessary. The merging of two streams of robust research, portable [...] Read more.
Mass spectrometry (MS) is a highly selective and sensitive analytical tool with a myriad of applications, but such techniques are typically used in laboratory settings due to the handling and preparations that are necessary. The merging of two streams of robust research, portable MS systems and next-generation ambient ionization methods, now provides the ability to perform high-performance chemical screening in an on-site and on-demand manner, with natural applications in disciplines such as forensic science, where samples of interest are typically found in field environments (i.e., traffic stops, crime scenes, etc.). Correspondingly, investigations regarding the suitability and robustness of these methodologies when they are utilized for authentic forensic evidence processing are prudent. This work reports critical insights into the role that choice of spray solvent system plays regarding analytical performance of two spray-based ambient ionization sources, paper spray ionization (PSI) and filter cone spray ionization (FCSI), when employed for evidence types containing emerging synthetic cannabinoids. The systematic characterization studies reported herein show that the applied spray solvent can dramatically affect both spectral intensity and signal duration, and in some circumstances, yield deleterious false negative responses. Overall, acetonitrile-based systems are shown to strike a balance between analyte solubility concerns and spray ionization dynamics of the novel ion sources employed on portable MS systems. Full article
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14 pages, 2280 KiB  
Article
Influence of Feeding, Temperature and Photoperiod on Purple Sea Urchin (Paracentrotus lividus) Gonad Development
by João Araújo, Margarida Gamboa, Ioannis Choulis, Ana Candeias-Mendes, Elsa Cabrita, Pedro Pousão-Ferreira and Florbela Soares
Fishes 2024, 9(6), 207; https://doi.org/10.3390/fishes9060207 (registering DOI) - 1 Jun 2024
Abstract
Understanding and controlling reproductive cycles and gonad maturation in cultivated species are crucial in aquaculture. The sea urchin Paracentrotus lividus, known for its edible gonads, requires careful maturation control for both reproduction and commercialization. This study explores the impact of temperature, photoperiod, [...] Read more.
Understanding and controlling reproductive cycles and gonad maturation in cultivated species are crucial in aquaculture. The sea urchin Paracentrotus lividus, known for its edible gonads, requires careful maturation control for both reproduction and commercialization. This study explores the impact of temperature, photoperiod, and diet on gonad development to enhance year-round aquaculture practices. Using two independent cultivation systems, we manipulated environmental conditions to mimic different seasons. Sea urchins were exposed to natural or manipulated temperature and photoperiod conditions and fed either natural (Ulva spp.) or formulated diets. The gonadosomatic index (GI) and histological analysis were used to assess gonad development. The results revealed a clear correlation between environmental conditions, diet, and gonad maturation. Manipulated conditions accelerated maturation, with sea urchins showing advanced stages compared to natural conditions. Furthermore, sea urchins fed formulated diets exhibited higher GI values, indicating enhanced maturation. Histological analysis confirmed accelerated maturation, particularly in females. This study underscores the feasibility of controlling gonad maturation through environmental manipulation and diet, enabling year-round marketable gonad production. Providing formulated diets rich in polyunsaturated fatty acids, notably docosahexaenoic acid (DHA), enhances the commercial value of sea urchins. These findings optimize aquaculture practices for P. lividus, highlighting its adaptability to the maximal production of gonads throughout the year. Full article
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13 pages, 4096 KiB  
Article
Gas–Liquid Mass Transfer Intensification for Selective Alkyne Semi-Hydrogenation with an Advanced Elastic Catalytic Foam-Bed Reactor
by Mohamad Fayad, Maïté Michaud, Han Peng, Vincent Ritleng and David Edouard
Fluids 2024, 9(6), 132; https://doi.org/10.3390/fluids9060132 (registering DOI) - 1 Jun 2024
Abstract
The Elastic Catalytic Foam-bed Reactor (EcFR) technology was used to enhance a model catalytic hydrogenation reaction by improving gas–liquid mass transfer. This advanced technology is based on a column packed with a commercial elastomeric polyurethane open-cell foam, which also acts as a catalyst [...] Read more.
The Elastic Catalytic Foam-bed Reactor (EcFR) technology was used to enhance a model catalytic hydrogenation reaction by improving gas–liquid mass transfer. This advanced technology is based on a column packed with a commercial elastomeric polyurethane open-cell foam, which also acts as a catalyst support. A simple and efficient crankshaft-inspired system applied in situ compression/relaxation movements to the foam bed. For the first time, the catalytic support parameters (i.e., porosity, tortuosity, characteristic length, etc.) underwent cyclic and controlled changes over time. These dynamic cycles have made it possible to intensify the transfer of gas to liquid at a constant energy level. The application chosen was the selective hydrogenation of phenylacetylene to styrene in an alcoholic solution using a palladium-based catalyst under hydrogen bubble conditions. The conversion observed with this EcFR at 1 Hz as cycle frequency was compared with that observed with a conventional Fixed Catalytic Foam-bed Reactor (FcFR). Full article
(This article belongs to the Special Issue Mass Transfer in Multiphase Reactors)
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24 pages, 9198 KiB  
Article
Lake Environmental Data Harvester (LED) for Alpine Lake Monitoring with Autonomous Surface Vehicles (ASVs)
by Angelo Odetti, Gabriele Bruzzone, Roberta Ferretti, Simona Aracri, Federico Carotenuto, Carolina Vagnoli, Alessandro Zaldei and Ivan Scagnetto
Remote Sens. 2024, 16(11), 1998; https://doi.org/10.3390/rs16111998 (registering DOI) - 1 Jun 2024
Abstract
This article introduces the Lake Environmental Data Harvester (LED) System, a robotic platform designed for the development of an innovative solution for monitoring remote alpine lakes. LED is intended as the first step in creating portable robotic tools that are lightweight, cost-effective, and [...] Read more.
This article introduces the Lake Environmental Data Harvester (LED) System, a robotic platform designed for the development of an innovative solution for monitoring remote alpine lakes. LED is intended as the first step in creating portable robotic tools that are lightweight, cost-effective, and highly reliable for monitoring remote water bodies. The LED system is based on the Shallow-Water Autonomous Multipurpose Platform (SWAMP), a groundbreaking Autonomous Surface Vehicle (ASV) originally designed for monitoring wetlands. The objective of LED is to achieve the comprehensive monitoring of remote lakes by outfitting the SWAMP with a suite of sensors, integrating an IoT infrastructure, and adhering to FAIR principles for structured data management. SWAMP’s modular design and open architecture facilitate the easy integration of payloads, while its compact size and construction with a reduced weight ensure portability. Equipped with four azimuth thrusters and a flexible hull structure, SWAMP offers a high degree of maneuverability and position-keeping ability for precise surveys in the shallow waters that are typical of remote lakes. In this project, SWAMP was equipped with a suite of sensors, including a single-beam dual-frequency echosounder, water-quality sensors, a winch for sensor deployment, and AirQino, a low-cost air quality analysis system, along with an RTK-GNSS (Global Navigation Satellite System) receiver for precise positioning. Utilizing commercial off-the-shelf (COTS) components, a Multipurpose Data-Acquisition System forms the basis for an Internet of Things (IoT) infrastructure, enabling data acquisition, storage, and long-range communication. This data-centric system design ensures that acquired variables from both sensors and the robotic platform are structured and managed according to the FAIR principles. Full article

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