Abstract
An arc of calcium burning in hydrogen at low pressure emits numerous bands in the region 6000-7000A. This spectrum was photographed at high dispersion and two groups of bands, shading toward the violet may be distinguished: the A groups with heads at , 7028, 6921, 6903 and the B groups with heads at , 6382. In addition to these, the arc emits an isolated C group—a single band in the ultra-violet at . This group is identical with a band of calcium hydride recently studied by R. S. Mulliken. The structures of A, B and C are very different. The A group forms a doublet system (, ) of branches. The bands of the B group have a similar structure to that of the violet cyanogen bands, signified by doublet , and , branches. The C group consists of a single band having branches. In all bands the series deviate largely from polynomials of second degree. Thus, in B and C there is a remarkable "red-shift" of high numbered lines, accompanied by a sharp cut-off in their intensity. From combinations found between the branches, conclusions are reached regarding the spectral terms in CaH. The A, B and C groups have a common final () electronic term with a rotational doubling (, ). The initial state of A forms an electronic doublet (, ) with the emission electron in a -orbit (, ), thus explaining the appearance of branches in A. In B (initial) there is again a rotational doubling (, ). In C (initial) only one component is present (, ). The departure from half-integral quantum numbers in C is avoided by accepting a large Kratzer's linear term . The nuclear spacings in the CaH molecule are not in correlation with their vibration frequencies, violating a rule by Birge and Mecke. A comparison of the A group with the spectra of ZnH, CdH and HgH shows several interesting parallels, confirming the theory of Mulliken regarding these spectra.
- Received 30 September 1926
DOI:https://doi.org/10.1103/PhysRev.29.97
©1927 American Physical Society