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Spectroscopic behaviour and internal friction of glasses containing iron having different redox ratios

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Abstract

The Mössbauer and ESR spectra and internal friction behaviour of Na2O-3SiO2 glasses having different redox ratios have been studied. As the redox ratio changes over a considerable range, there is a significant structural change associated with both the Fe3+ and Fe2+ ions, as evidenced from the analysis of the molar volume and Mössbauer data. The ESR data qualitatively supports the Mössbauer data on the Fe3+ ions. The change of internal friction behaviour of these glasses around 50% Fe3+ is described in terms of the structural changes associated with the Fe ions, which is thought to influence the oxygen structure of these glasses. The importance of this structural change on the electronic conductivity behaviour of these types of glasses is mentioned.

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Author notes

  1. P. Auric

    Present address: Laboratory of Hyperfine Interaction, Department of Fundamental Research, Centre of Nuclear Studies, 38 000, Grenoble-Cedex, France

Authors and Affiliations

  1. Laboratory of Materials Science and CNRS Glass Laboratory, University of Montpellier II, 34060, Montpellier-Cedex, France

    A. K. Bandyopadhyay, P. Auric, J. Phalippou & J. Zarzycki

Authors
  1. A. K. Bandyopadhyay
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  2. P. Auric
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  3. J. Phalippou
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  4. J. Zarzycki
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Bandyopadhyay, A.K., Auric, P., Phalippou, J. et al. Spectroscopic behaviour and internal friction of glasses containing iron having different redox ratios. J Mater Sci 15, 2081–2090 (1980). https://doi.org/10.1007/BF00550635

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