Abstract.
The extinction spectrum of single silver nanoparticles with size ranging from 20 to 80 nm is investigated with the spatial modulation spectroscopy technique using either a tunable laser or a white lamp as the broadband source. Results are in good agreement with the prediction of the Mie theory, permitting to extract the nanoparticle size from the measured absolute value of the optical extinction cross-section. In contrast, the deduced refractive index of the nanoparticle environment and the reduction of the electron mean free path show a large dependence on the precise value of the bulk silver dielectric function.
Similar content being viewed by others
References
S.A. Empedocles, D.J. Norris, M.G. Bawendi, Phys. Rev. Lett. 77, 3873 (1996)
T. Klar, M. Perner, S. Grosse, G. von Plessen, W. Spirkl, J. Feldmann, Phys. Rev. Lett. 80, 4249 (1998)
W.E. Moerner, M. Orrit, Science 283, 1670 (1999)
C. Sonnichsen, S. Geier, N.E. Hecker, G. von Plessen, J. Feldmann, Appl. Phys. Lett. 77, 2949 (2000)
D. Boyer, P. Tamarat, A. Maali, B. Lounis, M. Orrit, Science 297, 1160 (2002)
K. Lindfors, T. Kalkbrenner, P. Stoller, V. Sandogdhar, Phys. Rev. Lett. 93, 037401 (2004)
A. Arbouet, D. Christofilos, N. Del Fatti, F. Vallée, J.-R. Huntzinger, L. Arnaud, P. Billaud, M. Broyer, Phys. Rev. Lett. 93, 127401 (2004)
I.I. Smolyaminov, J. Elliott, A.V. Zayats, C.C. Davis, Phys. Rev. Lett. 94, 057401 (2005)
O.L. Muskens, N. Del Fatti, F. Vallée, J.-R. Huntzinger, P. Billaud, M. Broyer, Appl. Phys. Lett. 88, 063109 (2006)
O.L. Muskens, N. Del Fatti, F. Vallée, Nano Lett. 6, 552 (2006)
C. Voisin, N. Del Fatti, D. Christofilos, F. Vallée, J. Phys. Chem. B 105, 2264 (2001)
C.F. Bohren, D.R. Huffman, Absorption and Scattering of Light by Small Particles (Wiley, New York, 1983)
U. Kreibig, M. Vollmer, Optical Properties of Metal Custers (Springer, Berlin, 1995)
E.D. Palik, Handbook of Optical Constants of Solids (Academic Press, New York, 1985)
P.B. Johnson, R.W. Christy, Phys. Rev. B 6, 4370 (1972)
M.-M. Dujardin, M.L. Theye, J. Phys. Chem. Solids 32, 2033 (1971)
O. Muskens, D. Christofilos, N. Del Fatti, F. Vallée, J. Opt. A 8, 264 (2006)
P. Moreno, F. Gonzalez, J.M. Saiz, Opt. Lett. 31, 1902 (2006)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Billaud, P., Huntzinger, JR., Cottancin, E. et al. Optical extinction spectroscopy of single silver nanoparticles. Eur. Phys. J. D 43, 271–274 (2007). https://doi.org/10.1140/epjd/e2007-00112-y
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1140/epjd/e2007-00112-y