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Study of polyelectrolyte complexes of chitosan and sulfoethyl cellulose

  • Structure of Macromolecular Compounds
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Abstract

The complexing of polycation chitosan and polyanion sulphoethyl cellulose during the formation of polyelectrolyte simplex membranes using the layer-by-layer deposition of a solution of one polyion on a gel-like film of another one has been studied. The structural characteristics of the multilayer composites and their components have been analyzed by X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray microanalysis. A technique is proposed for studying the structure of surface layers of thin polymer films (15–20 μm) using a portable DIFREI-401 diffractometer. It is shown that the sequence of layer deposition during the formation of membrane films does not affect their structural characteristics. The interaction between positively charged chitosan groups (-NH +3 ) and negatively charged sulfoethyl cellulose groups (-SO −3 ) during the growth of polyelectrolyte complexes results in a packing of chitosan chains in the multilayer film.

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, 199004, Russia

    Yu. G. Baklagina, S. V. Kononova, V. A. Petrova, E. V. Kruchinina & L. A. Nud’ga

  2. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, nab. Makarova 2, St. Petersburg, 199034, Russia

    D. P. Romanov

  3. Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskii pr. 59, Moscow, 119333, Russia

    V. V. Klechkovskaya & A. S. Orekhov

  4. ZAO Nauchnye Pribory, St. Petersburg, Russia

    A. V. Bogomazov & S. N. Arkhipov

Authors
  1. Yu. G. Baklagina
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  2. S. V. Kononova
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  3. V. A. Petrova
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  4. E. V. Kruchinina
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  5. L. A. Nud’ga
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  6. D. P. Romanov
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  7. V. V. Klechkovskaya
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  8. A. S. Orekhov
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  9. A. V. Bogomazov
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  10. S. N. Arkhipov
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Correspondence to Yu. G. Baklagina.

Additional information

Original Russian Text © Yu.G. Baklagina, S.V. Kononova, V.A. Petrova, E.V. Kruchinina, L.A. Nud’ga, D.P. Romanov, V.V. Klechkovskaya, A.S. Orekhov, A.V. Bogomazov, S.N. Arkhipov, 2013, published in Kristallografiya, 2013, Vol. 58, No. 2, pp. 268–275.

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Baklagina, Y.G., Kononova, S.V., Petrova, V.A. et al. Study of polyelectrolyte complexes of chitosan and sulfoethyl cellulose. Crystallogr. Rep. 58, 287–294 (2013). https://doi.org/10.1134/S106377451302003X

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  • DOI: https://doi.org/10.1134/S106377451302003X

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