Skip to main content
Log in

Comparison of solvents for determination of monoterpenes in wine using liquid-liquid extraction

  • Originals
  • Gas Chromatography
  • Published:
Chromatographia Aims and scope Submit manuscript

Summary

The extraction capacity of seven solvents for volatile compounds in a model aqueous alcohol system was investigated. The five major terpenes usually found in grapes and wines (linalool, α-terpineol, citronellol, nerol and geraniol) were studied in a model wine. Liquid-liquid extraction with dichloromethane, diethyl ether, freon-11, ether-pentane (1∶1), ether-hexane (1∶1), pentane and hexane as extracting solvents are compared. Dichloromethane and diethyl etherpentane (1∶1,v/v) were the best solvents for a quantitation of these aromatic compounds.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Etievant, P.X.Connaissance Vigne Vin 1987,21, 247–265.

    CAS  Google Scholar 

  2. Terrier, A.; Boidron, J.N.Connaissance Vigne Vin 1972,1, 69–85.

    Google Scholar 

  3. Wagner, R.; Dirninger, N.; Fuchs, V.; Bonner, A. In ProceedingsOIV Int. Symp. Quality Vintage, Office International de la Vigne et du Vin, Paris1977, 137–142.

  4. Bayonove C. InLes acquisitions récentes en chromatographie du vin. Applications à l'analyse sensorielle des vins, Ed. Lavoisier, New York,1993, 99–119.

  5. Strauss, C.R.; Wilson, B.; Gooley, P.R.; Williams, P.J. InBiogeneration of Aromas, Parliament, T.H.; Croteau, R., Eds. American Chemical Society,1986, 222–242.

  6. Usseglio-Tomasset, L.; Di Stefano, R.Rev. Vitic. Enol. 1980,33, 58–68.

    CAS  Google Scholar 

  7. Marais, J.; Rapp, A.S. Afr. J. Enol. Vitic. 1981,12, 51–56.

    Google Scholar 

  8. Rapp, A.L'Enotecnico 1984,Gennaio, 25–33.

  9. Vernin, G.Parfums, Cosmétiques, Arômes 1986,68, Avril–Mai, 83–90.

    CAS  Google Scholar 

  10. Van Wyk, C.J.; Kepner, R.E.; Webb, A.D.J. Food Sci. 1967,32, 669–674.

    Article  Google Scholar 

  11. Dimitriadis, E.; Williams, P.J.Am. J. Enol. Vitic. 1984,35, 66–71.

    CAS  Google Scholar 

  12. Baumes, R.; Cordonnier, R.; Nitz, S.; Drawert, F.J. Sci. Food Agric. 1986,37, 927–943.

    CAS  Google Scholar 

  13. Herráiz, T.; Reglero, G.; Martín-Alvarez, P.J.; Herráiz, M.J. Sci. Food Agric. 1991,55, 103–106.

    Google Scholar 

  14. Williams, P.J.; Strauss, C.R.; Wilson, B.Am. J. Enol. Vitic. 1981,32, 230–235.

    CAS  Google Scholar 

  15. Marais, J.; Van Wyk, C.J.S. Afr. J. Enol. Vitic. 1986,7, 26–35.

    CAS  Google Scholar 

  16. Günata, Z.; Bitteur, S.; Brillouet, J.M.; Bayonove, C.; Cordonnier, R.Carbohydrate Research 1988,184, 139–149.

    Article  Google Scholar 

  17. Webster, D.R.; Edwards, C.G.; Spayd, S.E.; Peterson, J.C.; Seymour, B.J.Am. J. Enol. Vitic. 1993, 44, 275–284.

    CAS  Google Scholar 

  18. Guedes de Pinho, P.D.E.A., Université Bordeaux II,1991.

  19. Cobb, Ch.S.; Bursey, M.M.J. Agric. Food Chem. 1978,26, 197–199.

    Article  CAS  Google Scholar 

  20. Terrier, A.; Boidron, J.N.; Ribereau-Gayon, P. InJus de Fruits: Recherches Scientifiques et Technologiques, Fédération Internationale des Producteurs de Jus de Fruits, Dijon,1972, 125–139.

    Google Scholar 

  21. González-Mendoza, L.A.; Díaz-Rodríguez, F. Pomar-García, M.; Arriaga-Alvarez, E.Alimentaria 1994,Junio, 53–56.

    Google Scholar 

  22. Rogerson, F.S.S.; Silva, J.M.C.M. InI Congreso Internacional de la Vitivinicultura Atlántica, La Toja (Pontevedra),1994, 411–420.

  23. Dubourdieu, D.; Darriet, Ph.; Ollivier, Ph.; Boidron, J.N.; Ribereau-Gayon, P.C.R. Acad. Sci. Paris, Série III 1988,306, 489–493.

    CAS  Google Scholar 

  24. Orriols, I.; Rega, J.; Moreno, F. InI Congreso Internacional de la Vitivinicultura Atlántica, La Toja (Pontevedra),1994, 317–336.

  25. Di Stefano, R.Bull. OIV 1991,64, 721/722, 219–223.

    Google Scholar 

  26. Carro, N.; García, C.M.; Cela, R.J. Microcolumn. Sep. 1996,8, 453–460.

    Article  CAS  Google Scholar 

  27. Shimoda, M.; Shibamoto, T.; Noble, A.C.J. Agric. Food Chem. 1993,41, 1664–1668.

    Article  CAS  Google Scholar 

  28. Rapp, A.; Knipser, W.Chromatographia 1980,13, 698–702.

    Article  CAS  Google Scholar 

  29. González-Lara, R.; González, L.M.Alimentación 1993,Marzo, 49–57.

    Google Scholar 

  30. Salinas, M.R.; Alonso, G.L.; Esteban-Infantes, F.J.J. Agric. Food Chem. 1992,42, 1328–1331.

    Article  Google Scholar 

  31. Mattheis, J.P.; Buchanan, D.A.; Fellman, J.K.J. Agric. Food Chem. 1992,40, 471–474.

    Article  CAS  Google Scholar 

  32. Darriet, Ph.; Dubourdieu, D. InJournées Techniques du CIVB, Bordeaux,1993, 89–97.

  33. Cortés, S.; Falqué, E.; Gil, M.L.; Fernández, E. In8 a Jornadas Análisis Instrumental, Barcelona,1996, 231.

  34. Blanch, G.P.; Reglero, G.; Herráiz, M.; Tabera, J.J. Chromatogr. Sci. 1991,29, 11–15.

    CAS  Google Scholar 

  35. Valcárcel, M.; Silva, M.Teoría y Práctica de la Extracción Líquido-Líquido, Ed. Alhambra, Madrid,1984, 1–10.

  36. Perry, R.H.; Green, D.W.; Maloney, J.O.Manual del Ingeniero Químico. Tomo I. Ed. McGraw-Hill/Interamericana,1992, 3/65–3/81.

  37. UNIFAC: Prediction Method. ASPEN PLUS Program (Release 9.0), Aspen Tech. Inc.

  38. Hernánz-Vila, D.; Heredia-Mira, F.J.; Beltrán-Lucena, R.; Fernández-Recamales, M.A.Talanta 1999,50, 413–421.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

López, E.F., Gómez, E.F. Comparison of solvents for determination of monoterpenes in wine using liquid-liquid extraction. Chromatographia 52, 798–802 (2000). https://doi.org/10.1007/BF02491007

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02491007

Key Words

Navigation