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An improved interface for liquid chromatography/electron-capture detector coupling. Part II

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Summary

An improved interface for the coupling of a liquid chromatograph (LC) and an electron-capture detector (ECD) allows the use of the LC-ECD combination for the determination of various types of chlorinated aromatic compounds. The addition of up to 6% of dioxan to the hexane used as mobile phase can be tolerated without serious deterioration of detector performance. Derivatization of polar compounds such as anilines, phenylurea herbicides, chlorophenols and hydroxylated polychlorobiphenyls with fluorine-and non-fluorine-containing acid anhydrides is a useful tool to extend the application range of LC-ECD. As an example, the analysis of a spiked soil sample is discussed.

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References

  1. U. A. Th. Brinkman, in: Electron Capture, Theory and Practice in Chromatography,A. Zlatkis andC. F. Poole (Eds.), Elsevier, Amsterdam, 1981, Ch. 16.

    Google Scholar 

  2. I. S. Krull, D. Bushee, Anal. Lett. 13 (A14), 1277 (1980).

    Google Scholar 

  3. I. S. Krull, E. A. Davis, C. Santasania, S. Kraus, A. Basch, Y. Bamberger, Anal. Lett.14 (A16), 1363, (1981).

    Google Scholar 

  4. A. de Kok, R. B. Geerdink, U. A. Th. Brinkman, J. Chromatogr. in press.

  5. Y. A. Th. Brinkman, P. M. Onel, G. de Vries, J. Chromatogr.171, 424 (1979).

    Google Scholar 

  6. U. A. Th. Brinkman, J. W. F. L. Seetz, H. G. M. Reymer, J. Chromatogr.116, 353 (1976).

    Google Scholar 

  7. A. T. Chamberlain, J. S. Marlow, J. Chromatogr. Sci.15, 29 (1977).

    Google Scholar 

  8. A. de Kok, I. M. Roorda, R. W. Frei, U. A. Th. Brinkman, Chromatographia14, 579 (1981).

    Google Scholar 

  9. A. de Kok, A. A. van der Kooij, M. Linnekmap Y. J. Vos, R. W. Frei, U. A. Th. Brinkman, Proc. 4th Intern. Symp. Capillary Chromatography, Hindelang,R. E. Kaiser, (Ed.), Huthig Heidelberg, 1981, p. 53.

    Google Scholar 

  10. W. Krijgsman, C. G. van de Kamp, J. Chromatogr.131, 412 (1977).

    Google Scholar 

  11. L. Renberg, Chemosphere10, 767 (1981).

    Google Scholar 

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Authors and Affiliations

  1. Section of Environmental Chemistry, Dept. of Analytical Chemistry, Free University, De Boelelaan 1083, 1081 HV, Amsterdam, The Netherlands

    A. de Kok, R. B. Geerdink & U. A. Th. Brinkman

Authors
  1. A. de Kok
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  2. R. B. Geerdink
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  3. U. A. Th. Brinkman
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de Kok, A., Geerdink, R.B. & Brinkman, U.A.T. An improved interface for liquid chromatography/electron-capture detector coupling. Part II. Chromatographia 16, 237–241 (1982). https://doi.org/10.1007/BF02258910

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  • DOI: https://doi.org/10.1007/BF02258910

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