Reply to “Comment on ‘Synthesis and properties of selenium trihydride at high pressures’ ”

Xiao Zhang, Wan Xu, Yu Wang, Shuqing Jiang, Federico A. Gorelli, Eran Greenberg, Vitali B. Prakapenka, and Alexander F. Goncharov
Phys. Rev. B 98, 106102 – Published 11 September 2018

Abstract

The Comment of Pace et al. [Phys. Rev. B 98, 106101 (2018)] claims that structural analysis and nomenclature of Zhang et al. [Zhang, Xu, Wang, Jiang, Gorelli, Greenberg, Prakapenka, and Goncharov, Phys. Rev. B 97, 064107 (2018)] are incorrect, that this compound is not metallic at high pressures and 200 K, and that the compound instead decomposes. In this Reply we argue that there are no experimental data that can discriminate between theoretically predicted Cccm H3Se and I4/mcm (H2Se)2H2 advocated by Pace et al. The difference in nomenclature is due to different naming conventions. We find the name “H3Se” more convenient to apply in the limit of high pressure. We also substantiate the initial claims of the stability up to 40 GPa at 170 K of the H3Se compound after synthesis at 4.6 GPa and argue that the pressure induced metallization above 23 GPa is a plausible explanation of the reported visual observations and Raman spectroscopy results.

  • Figure
  • Figure
  • Received 19 June 2018
  • Revised 8 August 2018

DOI:https://doi.org/10.1103/PhysRevB.98.106102

©2018 American Physical Society

Physics Subject Headings (PhySH)

Condensed Matter, Materials & Applied Physics

Authors & Affiliations

Xiao Zhang1,2, Wan Xu1,2, Yu Wang1,2, Shuqing Jiang1, Federico A. Gorelli1,3,4, Eran Greenberg5, Vitali B. Prakapenka5, and Alexander F. Goncharov1,2,6

  • 1Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, China
  • 2University of Science and Technology of China, Hefei 230026, China
  • 3Istituto Nazionale di Ottica, Consiglio Nazionale delle Ricerche, INO, 50019 Sesto Fiorentino, Italy
  • 4European Laboratory for Non Linear Spectroscopy (LENS), 50019 Sesto Fiorentino, Italy
  • 5Center for Advanced Radiations Sources, University of Chicago, Chicago, Illinois 60637, USA
  • 6Geophysical Laboratory, Carnegie Institution of Washington, Washington, DC 20015, USA

Comments & Replies

Comment on “Synthesis and properties of selenium trihydride at high pressures”

Edward J. Pace, Jack Binns, Phillip Dalladay-Simpson, Ross T. Howie, and Miriam Peña Alvarez
Phys. Rev. B 98, 106101 (2018)

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Original Article

Synthesis and properties of selenium trihydride at high pressures

Xiao Zhang, Wan Xu, Yu Wang, Shuqing Jiang, Federico A. Gorelli, Eran Greenberg, Vitali B. Prakapenka, and Alexander F. Goncharov
Phys. Rev. B 97, 064107 (2018)

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Issue

Vol. 98, Iss. 10 — 1 September 2018

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