The 2023 MDPI Annual Report has
been released!
 
26 pages, 6059 KiB  
Article
Enhancing Sustainable Urban Intermodal Systems: Simulating the Effects of Key Parameters in Integrated Ride-Pooling and Public Transport
by Ester Lorente, Esteve Codina, Jaume Barceló and Klaus Nökel
Sustainability 2024, 16(12), 5013; https://doi.org/10.3390/su16125013 (registering DOI) - 12 Jun 2024
Abstract
Mobility as a service, and its associated variants, has been proposed as a method to improve the sustainability of transport systems; however, most of the approaches that have been proposed so far have been unsuccessful or have worsened the situation. The work presented [...] Read more.
Mobility as a service, and its associated variants, has been proposed as a method to improve the sustainability of transport systems; however, most of the approaches that have been proposed so far have been unsuccessful or have worsened the situation. The work presented in this paper investigates an intermodal system that combines a ride-pooling service with a public transport network. The system is composed of a dedicated simulator that evaluates the transport scenario and an intermodal dispatcher that optimises the service according to requests, accounting for their time windows. This intermodal approach considers trips with multiple legs, for which either ride-pooling or public transport are used. This study investigates how the batch size and the early dispatching of the last leg, supported by a vehicle reservation strategy, impact diverse demand profiles that range from single-passenger to multiple-passenger requests, while also addressing the critical aspect of fleet size. The experimental setting used in this work is the metropolitan area of Barcelona; the experimentation results yield valuable insights into the functionality of the proposed intermodal system. Full article
(This article belongs to the Collection Sustainable Urban Mobility Project)
Show Figures

Figure 1

Article
Exploring User Attitudes and Behavioral Intentions towards Augmented Reality Automotive Assistants: A Mixed-Methods Approach
by Fucheng Wan, Jian Teng and Lisi Feng
World Electr. Veh. J. 2024, 15(6), 258; https://doi.org/10.3390/wevj15060258 (registering DOI) - 12 Jun 2024
Abstract
As augmented reality (AR) technology is increasingly permeating the automotive industry, this study investigates users’ attitudes towards AR automotive assistants and their impact on usage behavior. Using the theory of reasoned action (TRA) and integrating insights from the Kano model, critical factors driving [...] Read more.
As augmented reality (AR) technology is increasingly permeating the automotive industry, this study investigates users’ attitudes towards AR automotive assistants and their impact on usage behavior. Using the theory of reasoned action (TRA) and integrating insights from the Kano model, critical factors driving user acceptance and engagement were identified. The research reveals that trust in AR technology, perceived utility, and ease of interaction are prioritized by users. Clustering analysis identified three distinct user groups: a ‘Safety-Conscious Group’, a ‘Technology Enthusiast Group’, and an ‘Experience-Seeking Group’, each displaying unique preferences towards AR features. Additionally, a support vector machine (SVM) model effectively predicted user behavior with a training set accuracy of 89.96%. These findings provide valuable insights for the design and marketing of AR automotive assistants, acknowledging both essential features and delighters identified through the Kano model. By understanding user preferences and expectations, tailored AR solutions can be developed to enhance user satisfaction and adoption rates in the automotive sector. Moreover, this research contributes to the sustainable development goals related to the automotive industry by fostering innovation in vehicle technology, promoting eco-friendly driving practices, and enhancing overall mobility efficiency. Full article
Review
Nature’s Plastic Predators: A Comprehensive and Bibliometric Review of Plastivore Insects
by Joseph Boctor, Gunjan Pandey, Wei Xu, Daniel V. Murphy and Frances C. Hoyle
Polymers 2024, 16(12), 1671; https://doi.org/10.3390/polym16121671 (registering DOI) - 12 Jun 2024
Abstract
Unprecedented plastic production has resulted in over six billion tons of harmful waste. Certain insect taxa emerge as potential agents of plastic biodegradation. Through a comprehensive manual and bibliometric literature analysis, this review analyses and consolidates the growing literature related to insect-mediated plastic [...] Read more.
Unprecedented plastic production has resulted in over six billion tons of harmful waste. Certain insect taxa emerge as potential agents of plastic biodegradation. Through a comprehensive manual and bibliometric literature analysis, this review analyses and consolidates the growing literature related to insect-mediated plastic breakdown. Over 23 insect species, representing Coleoptera, Lepidoptera, and 4 other orders, have been identified for their capacity to consume plastic polymers. Natural and synthetic polymers exhibit high-level similarities in molecular structure and properties. Thus, in conjunction with comparative genomics studies, we link plastic-degrading enzymatic capabilities observed in certain insects to the exaptation of endogenous enzymes originally evolved for digesting lignin, cellulose, beeswax, keratin and chitin from their native dietary substrates. Further clarification is necessary to distinguish mineralisation from physicochemical fragmentation and to differentiate microbiome-mediated degradation from direct enzymatic reactions by insects. A bibliometric analysis of the exponentially growing body of literature showed that leading research is emerging from China and the USA. Analogies between natural and synthetic polymer’s degradation pathways will inform engineering robust enzymes for practical plastic bioremediation applications. By aggregating, analysing, and interpreting published insights, this review consolidates our mechanistic understanding of insects as a potential natural solution to the escalating plastic waste crisis. Full article
(This article belongs to the Special Issue Degradation of Plastics)
16 pages, 5594 KiB  
Article
Modeling the Dynamics of Water and Mud Inrush in Fault Fracture Zones: The Role of Seepage–Erosion Interactions
by Qingyan Zhang and Xiaowen Zhou
Appl. Sci. 2024, 14(12), 5115; https://doi.org/10.3390/app14125115 (registering DOI) - 12 Jun 2024
Abstract
By using the principles of porous media seepage mechanics and solute transport theories, a seepage–erosion theory model was developed to uncover the dynamics of mud and water inrush in fault rupture zones during the construction of tunnels. This model consists of a mass [...] Read more.
By using the principles of porous media seepage mechanics and solute transport theories, a seepage–erosion theory model was developed to uncover the dynamics of mud and water inrush in fault rupture zones during the construction of tunnels. This model consists of a mass conservation equation, a flow transformation equation, a porosity evolution equation, and a permeability evolution equation. These components illustrate the interaction between seepage–erosion particle loss and the transformation of seepage flow patterns throughout the mud and water inrush evolution in the fault fracture zone. This model proves to be effective in illustrating the catastrophic process of mud and water inrushes within tunnels located in fault rupture zones. To address the spatial and temporal variations, the implicit difference and Galerkin finite element schemes were utilized, and the Newton–Raphson iteration method was applied to handle the nonlinear attributes of the equations. The theoretical model underwent further development and numerical simulations were performed using COMSOL multi-field coupling software. A comparison with existing indoor water inrush mud model test results validated the effectiveness of our model. The theoretical model was then applied to the Yong Lian tunnel scenario within the fault rupture zone. This computational analysis exposed the sequence of flow pattern transformations and the instability in seepage–erosion evolution within the fault rupture zone, ultimately leading to the emergence of mud and water inrush disasters. The findings of this study offer valuable insights for addressing tunnel engineering challenges related to underwater inrush disasters. Full article
(This article belongs to the Special Issue Engineering Groundwater and Groundwater Engineering)
Show Figures

Figure 1

Article
Gelatin-Based Liver Phantoms for Training Purposes: A Cookbook Approach
by Radu Claudiu Elisei, Florin Graur, Amir Szold, Andreas Melzer, Sever Cãlin Moldovan, Mihai Motrescu, Emil Moiş, Cãlin Popa, Doina Pîsla, Cãlin Vaida, Tiberiu Tudor, Adrian Coţe and Nadim Al-Hajjar
J. Clin. Med. 2024, 13(12), 3440; https://doi.org/10.3390/jcm13123440 (registering DOI) - 12 Jun 2024
Abstract
Background: Patients with liver pathology benefit from image-guided interventions. Training for interventional procedures is recommended to be performed on liver phantoms until a basic proficiency is reached. In the last 40 years, several attempts have been made to develop materials to mimic [...] Read more.
Background: Patients with liver pathology benefit from image-guided interventions. Training for interventional procedures is recommended to be performed on liver phantoms until a basic proficiency is reached. In the last 40 years, several attempts have been made to develop materials to mimic the imaging characteristics of the human liver in order to create liver phantoms. There is still a lack of accessible, reproducible and cost-effective soft liver phantoms for image-guided procedure training. Methods: Starting from a CT-scan DICOM file, we created a 3D-printed liver mold using InVesalius (Centro de Tecnologia da informação Renato Archer CTI, InVesalius 3 open-source software, Campinas, Brazil) for segmentation, Autodesk Fusion 360 with Netfabb (Autodesk software company, Fusion 360 2.0.19426 with Autodesk Netfabb Premium 2023.0 64-Bit Edition, San Francisco, CA, USA) for 3D modeling and Stratasys Fortus 380 mc 3D printer (Stratasys 3D printing company, Fortus 380 mc 3D printer, Minneapolis, MN, USA). Using the 3D-printed mold, we created 14 gelatin-based liver phantoms with 14 different recipes, using water, cast sugar and dehydrated gelatin, 32% fat bovine milk cream with intravenous lipid solution and technical alcohol in different amounts. We tested all these phantoms as well as ex vivo pig liver and human normal, fatty and cirrhotic liver by measuring the elasticity, shear wave speed, ultrasound attenuation, CT-scan density, MRI signal intensity and fracture force. We assessed the results of the testing performed, as well as the optical appearance on ultrasound, CT and MRI, in order to find the best recipe for gelatin-based phantoms for image-guided procedure training. Results: After the assessment of all phantom recipes, we selected as the best recipe for transparent phantoms one with 14 g of gelatin/100 mL water and for opaque phantom, the recipes with 25% cream. Conclusions: These liver gelatin-based phantom recipes are an inexpensive, reproducible and accessible alternative for training in image-guided and diagnostic procedures and will meet most requirements for valuable training. Full article
22 pages, 8603 KiB  
Article
Novel Methods for Personalized Gait Assistance: Three-Dimensional Trajectory Prediction Based on Regression and LSTM Models
by Pablo Romero-Sorozábal, Gabriel Delgado-Oleas, Annemarie F. Laudanski, Álvaro Gutiérrez and Eduardo Rocon
Biomimetics 2024, 9(6), 352; https://doi.org/10.3390/biomimetics9060352 (registering DOI) - 12 Jun 2024
Abstract
Enhancing human–robot interaction has been a primary focus in robotic gait assistance, with a thorough understanding of human motion being crucial for personalizing gait assistance. Traditional gait trajectory references from Clinical Gait Analysis (CGA) face limitations due to their inability to account for [...] Read more.
Enhancing human–robot interaction has been a primary focus in robotic gait assistance, with a thorough understanding of human motion being crucial for personalizing gait assistance. Traditional gait trajectory references from Clinical Gait Analysis (CGA) face limitations due to their inability to account for individual variability. Recent advancements in gait pattern generators, integrating regression models and Artificial Neural Network (ANN) techniques, have aimed at providing more personalized and dynamically adaptable solutions. This article introduces a novel approach that expands regression and ANN applications beyond mere angular estimations to include three-dimensional spatial predictions. Unlike previous methods, our approach provides comprehensive spatial trajectories for hip, knee and ankle tailored to individual kinematics, significantly enhancing end-effector rehabilitation robotic devices. Our models achieve state-of-the-art accuracy: overall RMSE of 13.40 mm and a correlation coefficient of 0.92 for the regression model, and RMSE of 12.57 mm and a correlation of 0.99 for the Long Short-Term Memory (LSTM) model. These advancements underscore the potential of these models to offer more personalized gait trajectory assistance, improving human–robot interactions. Full article
Show Figures

Figure 1

19 pages, 1332 KiB  
Article
Importance of the Rotational Transform for L–H Transitions in the TJ-II Stellarator
by Boudewijn Philip van Milligen, Teresa Estrada, Benjamin Carreras, Luis García and TJ-II Team
Plasma 2024, 7(2), 446-464; https://doi.org/10.3390/plasma7020024 (registering DOI) - 12 Jun 2024
Abstract
We study the effect of the rotational transform profile on the L–H confinement transitions in the neutral beam-heated plasmas in the TJ-II stellarator. The rotational transform profile in the vacuum is determined by the external coil currents but is modified by the plasma [...] Read more.
We study the effect of the rotational transform profile on the L–H confinement transitions in the neutral beam-heated plasmas in the TJ-II stellarator. The rotational transform profile in the vacuum is determined by the external coil currents but is modified by the plasma current, Ip. We find that L–H confinement transitions systematically occur when the configuration and plasma current are such that a low-order rational is placed in the plasma edge region, with a distribution centered around ρ=0.8±0.05. It is suggested that magnetohydrodynamic turbulence plays an important role in triggering the L–H transitions at TJ-II. Full article
18 pages, 583 KiB  
Review
A Scoping Review of Research on the Use of Digital Technologies for Teaching Reading Fluency
by Grace Oakley
Educ. Sci. 2024, 14(6), 633; https://doi.org/10.3390/educsci14060633 (registering DOI) - 12 Jun 2024
Abstract
Background: Reading fluency is a crucial component of reading. Research indicates that the use of digital technologies can help students with reading difficulties and disabilities improve their reading fluency. Objectives: The objective of this scoping review was to identify and describe research focusing [...] Read more.
Background: Reading fluency is a crucial component of reading. Research indicates that the use of digital technologies can help students with reading difficulties and disabilities improve their reading fluency. Objectives: The objective of this scoping review was to identify and describe research focusing on the use of digital technologies for teaching reading fluency to primary or elementary students in English-speaking settings. Design: Online databases were used to identify papers published between 2013 and 2023. Eighty-six papers that met the inclusion criteria were selected for analysis. Results: The review indicates that research has primarily focused on the use of digital technologies as interventions to support students at risk of reading difficulties and students with disabilities, with relatively little research emphasis on general classroom teaching of reading fluency. Moreover, uses of digital technologies for the teaching of reading fluency could mostly be categorised as “enhancements” of common non-digital strategies for teaching reading fluency, such as explicit teaching, drill and practice, and repeated readings. Much of the research has focused on the use of programs as opposed to the innovative use of open-ended digital tools. Conclusions: This paper raises questions about the relatively narrow uses of digital technologies in the teaching and research of reading fluency and calls for an expanded research agenda to include a broader range of pedagogical goals and approaches. Full article
41 pages, 5093 KiB  
Review
A Short History of the First 50 Years: From the GRB Prompt Emission and Afterglow Discoveries to the Multimessenger Era
by Filippo Frontera
Universe 2024, 10(6), 260; https://doi.org/10.3390/universe10060260 (registering DOI) - 12 Jun 2024
Abstract
More than fifty years have elapsed from the first discovery of gamma-ray bursts (GRBs) with American Vela satellites, and more than twenty-five years from the discovery with the BeppoSAX satellite of the first X-ray afterglow of a GRB. Thanks to the afterglow discovery [...] Read more.
More than fifty years have elapsed from the first discovery of gamma-ray bursts (GRBs) with American Vela satellites, and more than twenty-five years from the discovery with the BeppoSAX satellite of the first X-ray afterglow of a GRB. Thanks to the afterglow discovery and to the possibility given to the optical and radio astronomers to discover the GRB optical counterparts, the long-time mystery about the origin of these events has been solved. Now we know that GRBs are huge explosions, mainly ultra relativistic jets, in galaxies at cosmological distances. Starting from the first GRB detection with the Vela satellites, I will review the story of these discoveries, those obtained with BeppoSAX, the contribution to GRBs by other satellites and ground experiments, among them being Venera, Compton Gamma Ray Observatory, HETE-2, Swift, Fermi, AGILE, MAGIC, H.E.S.S., which were, and some of them are still, very important for the study of GRB properties. Then, I will review the main results obtained thus far and the still open problems and prospects of GRB astronomy. Full article
(This article belongs to the Special Issue GRBs Phenomenology, Models and Applications: A Beginner Guide)
19 pages, 811 KiB  
Review
The Complex Intracellular Lifecycle of Staphylococcus Aureus Contributes to Reduced Antibiotic Efficacy and Persistent Bacteremia
by Cecilia F. Volk, Richard A. Proctor and Warren E. Rose
Int. J. Mol. Sci. 2024, 25(12), 6486; https://doi.org/10.3390/ijms25126486 (registering DOI) - 12 Jun 2024
Abstract
Staphylococcus aureus bacteremia continues to be associated with significant morbidity and mortality, despite improvements in diagnostics and management. Persistent infections pose a major challenge to clinicians and have been consistently shown to increase the risk of mortality and other infectious complications. S. aureus [...] Read more.
Staphylococcus aureus bacteremia continues to be associated with significant morbidity and mortality, despite improvements in diagnostics and management. Persistent infections pose a major challenge to clinicians and have been consistently shown to increase the risk of mortality and other infectious complications. S. aureus, while typically not considered an intracellular pathogen, has been proven to utilize an intracellular niche, through several phenotypes including small colony variants, as a means for survival that has been linked to chronic, persistent, and recurrent infections. This intracellular persistence allows for protection from the host immune system and leads to reduced antibiotic efficacy through a variety of mechanisms. These include antimicrobial resistance, tolerance, and/or persistence in S. aureus that contribute to persistent bacteremia. This review will discuss the challenges associated with treating these complicated infections and the various methods that S. aureus uses to persist within the intracellular space. Full article
(This article belongs to the Special Issue Host-Pathogen Interactions during Persistent Bacterial Infections)
18 pages, 1048 KiB  
Review
Progress in Solvent-Based Recycling of Polymers from Multilayer Packaging
by Tianmiao Li, George Theodosopoulos, Chris Lovell, Adamantini Loukodimou, Kranthi Kumar Maniam and Shiladitya Paul
Polymers 2024, 16(12), 1670; https://doi.org/10.3390/polym16121670 (registering DOI) - 12 Jun 2024
Abstract
Conversion of chemical feedstocks derived from fossil fuels to virgin polymer, manufacturing of plastics in coal-dependent economies, and increasing consumption of virgin polymers for plastics packaging contribute significantly to environmental issues and the challenges we face. Nowadays, promoting sustainable development has become the [...] Read more.
Conversion of chemical feedstocks derived from fossil fuels to virgin polymer, manufacturing of plastics in coal-dependent economies, and increasing consumption of virgin polymers for plastics packaging contribute significantly to environmental issues and the challenges we face. Nowadays, promoting sustainable development has become the consensus of more and more countries. Among them, the recycling of multilayer packaging is a huge challenge. Due to the complexity of its structure and materials, as well as the limitations of existing recycling frameworks, currently, multilayer packaging cannot be commercially recycled thus resulting in a series of circular economy challenges. It is undeniable that multilayer packaging offers many positive effects on products and consumers, so banning the use of such packaging would be unwise and unrealistic. Developing the appropriate processes to recycle multilayer packaging is the most feasible strategy. In recent years, there have been some studies devoted to the recycling process of multilayer packaging. Many of the processes being developed involve the use of solvents. Based on the recycled products, we categorised these recycling processes as solvent-based recycling, including physical dissolution and chemical depolymerisation. In physical dissolution, there are mainly two approaches named delamination and selective dissolution–precipitation. Focusing on these processes, this paper reviews the solvents developed and used in the last 20 years for the recycling of polymers from multilayer packaging waste and gives a summary of their advantages and disadvantages in terms of cost, product quality, ease of processing, and environmental impact. Based on existing research, one could conclude that solvent-based recycling methods have the potential to be commercialised and become part of a standard recycling process for polymer-based multilayer packaging. The combined use of multiple solvent-based recycling processes could be a breakthrough in achieving unified recycling of multilayer packaging with different components. Full article
(This article belongs to the Section Circular and Green Polymer Science)
21 pages, 2362 KiB  
Article
Functional Alpha and Beta Diversity of Fish Communities and Their Relationship with Environmental Factors in the Huanghe River (Yellow River) Estuary and Adjacent Seas, China
by Shaowen Li, Yufang Huang, Fan Li, Yanfen Liu, Hongliang Ma, Xiaomin Zhang, Xiuxia Wang, Wei Chen, Guangxin Cui and Tiantian Wang
Fishes 2024, 9(6), 222; https://doi.org/10.3390/fishes9060222 (registering DOI) - 12 Jun 2024
Abstract
Fisheries and bottom seawater data were collected in July in 2022 and 2023 from 15 sampling stations in the Huanghe River estuary and adjacent seas in China. The patterns of functional alpha and beta diversity of fish communities in this area and their [...] Read more.
Fisheries and bottom seawater data were collected in July in 2022 and 2023 from 15 sampling stations in the Huanghe River estuary and adjacent seas in China. The patterns of functional alpha and beta diversity of fish communities in this area and their relationships with environmental factors were studied using trait-based analysis. Five functional classifications, which included 16 functional traits, four functional alpha diversity indices (functional richness, functional evenness, functional divergence, and community-weighted mean), three functional beta diversity indices (functional beta diversity and its turnover and nestedness components), and 14 bottom environmental factors were considered. The dominant traits of fish communities were the following: benthivorous feeding habits, small and front-facing mouths, high trophic level, demersal, anguilliform, low growth coefficient, medium resilience, low vulnerability, and adapted to warm temperate conditions. The dominant migration traits and types of fish eggs varied by year, and fish abundance was the main factor affecting the dominant traits of the communities. The results of multiple regression on distance matrices and variance partitioning analysis indicated that ammonia nitrogen content, total phosphorus content, and pH were the main environmental factors that affected fish functional diversity. The N/P ratio had a bottom-up control effect on fish functional diversity. Our findings also revealed that high pH gradients and distant geographical distances can inhibit trait turnover in fish communities. Full article
(This article belongs to the Special Issue Biodiversity and Spatial Distribution of Fishes)
10 pages, 1028 KiB  
Communication
Exploring Heavy Metal and Metalloid Exposure in Children: A Pilot Biomonitoring Study near a Sugarcane Mill
by Oliver Mendoza-Cano, Agustin Lugo-Radillo, Mónica Ríos-Silva, Irma Elizabeth Gonzalez-Curiel, Jaime Alberto Bricio-Barrios, Arlette A. Camacho-delaCruz, María Fernanda Romo-García, Herguin Benjamín Cuevas-Arellano, Ana Luz Quintanilla-Montoya, Ramón Solano-Barajas, Juan Manuel Uribe-Ramos, Luis A. García-Solórzano, Ángel Gabriel Hilerio-López, Alma Alejandra Solano-Mendoza, Rogelio Danis-Romero and Efrén Murillo-Zamora
Toxics 2024, 12(6), 426; https://doi.org/10.3390/toxics12060426 (registering DOI) - 12 Jun 2024
Abstract
Sugarcane production has been linked to the release of heavy metals and metalloids (HM/MTs) into the environment, raising concerns about potential health risks. This study aimed to assess the levels of 19 HM/MTs in children living near a sugarcane mill through a pilot [...] Read more.
Sugarcane production has been linked to the release of heavy metals and metalloids (HM/MTs) into the environment, raising concerns about potential health risks. This study aimed to assess the levels of 19 HM/MTs in children living near a sugarcane mill through a pilot biomonitoring investigation. We investigated sex-related differences in these element levels and their correlations. A cross-sectional study was conducted, analyzing data from 20 children in the latter part of 2023. Spearman correlation coefficients with 95% confidence intervals (CIs) were used to assess the relationships between urinary HM/MT levels. Detectable levels of 17 out of the 19 HM/MTs were found across the entire study sample, with arsenic and copper detectable in 95% of the children. Titanium exhibited higher levels in boys compared to girls (p = 0.017). We identified 56 statistically significant correlations, with 51 of them being positive, while the remaining coefficients indicated negative relationships. This study characterized HM/MT levels in school-aged children residing near a sugarcane mill through a pilot biomonitoring investigation. Further research employing larger sample sizes and longitudinal assessments would enhance our understanding of the dynamics and health impacts of HM/MT exposure in this vulnerable population. Full article
(This article belongs to the Section Metals and Radioactive Substances)
Show Figures

Figure 1

48 pages, 5365 KiB  
Review
Supramolecular Materials as Solid-Phase Microextraction Coatings in Environmental Analysis
by Nicolò Riboni, Erika Ribezzi, Federica Bianchi and Maria Careri
Molecules 2024, 29(12), 2802; https://doi.org/10.3390/molecules29122802 (registering DOI) - 12 Jun 2024
Abstract
Solid-phase microextraction (SPME) has been widely proposed for the extraction, clean-up, and preconcentration of analytes of environmental concern. Enrichment capabilities, preconcentration efficiency, sample throughput, and selectivity in extracting target compounds greatly depend on the materials used as SPME coatings. Supramolecular materials have emerged [...] Read more.
Solid-phase microextraction (SPME) has been widely proposed for the extraction, clean-up, and preconcentration of analytes of environmental concern. Enrichment capabilities, preconcentration efficiency, sample throughput, and selectivity in extracting target compounds greatly depend on the materials used as SPME coatings. Supramolecular materials have emerged as promising porous coatings to be used for the extraction of target compounds due to their unique selectivity, three-dimensional framework, flexible design, and possibility to promote the interaction between the analytes and the coating by means of multiple oriented functional groups. The present review will cover the state of the art of the last 5 years related to SPME coatings based on metal organic frameworks (MOFs), covalent organic frameworks (COFs), and supramolecular macrocycles used for environmental applications. Full article
(This article belongs to the Special Issue Applications of Solid-Phase Microextraction and Related Techniques)
Show Figures

Graphical abstract

17 pages, 8225 KiB  
Article
Qualities and Quantities of Poultry Litter Biochar Characterization and Investigation
by Yulai Yang, Xuejun Qian, Samuel O. Alamu, Kayla Brown, Seong W. Lee and Dong-Hee Kang
Energies 2024, 17(12), 2885; https://doi.org/10.3390/en17122885 (registering DOI) - 12 Jun 2024
Abstract
Excessive land application of poultry litter (PL) may lead to surface runoff of nitrogen (N) and phosphorus (P), which cause eutrophication, fish death, and water pollution that ultimately have negative effects on humans and animals. Increases in poultry production in the Delmarva Peninsula [...] Read more.
Excessive land application of poultry litter (PL) may lead to surface runoff of nitrogen (N) and phosphorus (P), which cause eutrophication, fish death, and water pollution that ultimately have negative effects on humans and animals. Increases in poultry production in the Delmarva Peninsula underscore the need for more efficient, cost-effective, and sustainable disposal technologies for processing PL instead of direct land application. The pyrolysis conversion process can potentially produce nutrient-rich poultry litter biochar (PLB), while the pyrolysis process can change the N and P to a more stable component, thus reducing its runoff. Pyrolysis also kills off any microorganisms that would otherwise trigger negative environmental health effects. This study is to apply an integrated method and investigate the effect of pyrolysis temperature (300 °C, 500 °C), poultry litter source (different feedstock composition), and bedding material mixture (10% pine shavings) on PLB qualities and quantities. Proximate and ultimate analysis showed PL sources and bedding material addition influenced the physicochemical properties of feedstock. The SEM and BET surface results indicate that pyrolysis temperature had a significant effect on changing the PLB morphology and structure, as well as the pH value (7.78 at 300 °C vs. 8.78 at 500 °C), extractable phosphorus (P) (18.73 ppm at 300 °C vs. 11.72 ppm at 500 °C), sulfur (S) (363 ppm at 300 °C vs. 344 ppm at 500 °C), and production yield of PLBs (47.65% at 300 °C vs. 60.62% at 500 °C). The results further suggest that adding a bedding material mixture (10% pine shavings) to PLs improved qualities by reducing the content of extractable P and S, as well as pH values of PLBs. This study also found the increment in both the pore volume and the area of Bethel Farm was higher than that of Sun Farm. Characterization and investigation of qualities and quantities of PLB using the integrated framework suggest that PL from Bethel Farm could produce better-quality PLB at a higher pyrolysis temperature and bedding material mixture to control N and P runoff problems. Full article
(This article belongs to the Special Issue Biomass and Bio-Energy—2nd Edition)
Show Figures

Figure 1

18 pages, 526 KiB  
Article
The Impact of Off-Farm Employment Recession and Land on Farmers’ Mental Health: Empirical Evidence from Rural China
by Ziyu Wang, Qiran Zhao and Yueqing Ji
Land 2024, 13(6), 837; https://doi.org/10.3390/land13060837 (registering DOI) - 12 Jun 2024
Abstract
The agricultural land management under the household responsibility system (HRS) in rural China empowers farmers with land tenure rights, meeting the basic needs for their livelihoods and employment by cultivating the land. This paper investigates the pivotal role of agricultural cultivated land as [...] Read more.
The agricultural land management under the household responsibility system (HRS) in rural China empowers farmers with land tenure rights, meeting the basic needs for their livelihoods and employment by cultivating the land. This paper investigates the pivotal role of agricultural cultivated land as a social safety net, ensuring livelihood security for farmers confronting a recession in off-farm employment. Our analysis is based on data collected from six provinces (Heilongjiang, Henan, Zhejiang, Yunnan, Shandong, and Anhui) in the rural areas of China from 2019 to 2020. We investigated the impact of the off-farm employment recession on the mental health of farmers and the moderating effect of land as a social safety net on the relationship between the off-farm employment recession and mental health. The analysis points to the following results: (1) The majority of farmers have significantly reduced off-farm working time during employment recession. (2) The off-farm employment recession has worsened farmers’ mental health. (3) Farmers’ land assets through tenure rights provide both income and employment security functions, which can mitigate the adverse effects of the off-farm employment recession on their mental health. The findings of this study highlight the crucial role of land assets to reduce the negative impact of unemployment in the context of economic recession, emphasizing the significance of the policies supporting the land rights among vulnerable rural groups. Full article
(This article belongs to the Section Land, Biodiversity, and Human Wellbeing)
23 pages, 3036 KiB  
Article
Probabilistic Fatigue Crack Growth Prediction for Pipelines with Initial Flaws
by Youngjin Choi and Seung-Jung Lee
Buildings 2024, 14(6), 1775; https://doi.org/10.3390/buildings14061775 (registering DOI) - 12 Jun 2024
Abstract
This paper presents a probabilistic method to predict fatigue crack growth for surface flaws in pipelines using a particle filtering method based on Bayes theorem. The random response of the fatigue behavior is updated continuously as measured data are accumulated by the particle [...] Read more.
This paper presents a probabilistic method to predict fatigue crack growth for surface flaws in pipelines using a particle filtering method based on Bayes theorem. The random response of the fatigue behavior is updated continuously as measured data are accumulated by the particle filtering method. Fatigue crack growth is then predicted through an iterative process in which particles with a high probability are reproduced more during the update process, and particles with a lower probability are removed through a resampling procedure. The effectiveness of the particle filtering method was confirmed by controlling the depth and length direction of the cracks in the pipeline and predicting crack growth in one- and two-dimensional cases. In addition, the fatigue crack growth and remaining service life with a 90% confidence interval were predicted based on the findings of previous studies, and the relationship between the fatigue crack growth rate and the crack size was explained through the Paris’ law, which represents fatigue crack growth. Finally, the applicability of the particle filtering method under different diameters, aspect ratios, and materials was investigated by considering the negative correlation between the Paris’ law parameters. Full article
(This article belongs to the Special Issue Study on the Durability of Construction Materials and Structures)
41 pages, 4946 KiB  
Review
A Review on the Applications of Dual Quaternions
by João Gutemberg Farias, Edson De Pieri and Daniel Martins
Machines 2024, 12(6), 402; https://doi.org/10.3390/machines12060402 (registering DOI) - 12 Jun 2024
Abstract
This work explores dual quaternions and their applications. First, a theoretical construction begins at dual numbers, extends to dual vectors, and culminates in dual quaternions. The physical foundations behind the developed theory lie in two important fundamentals: Chasles’ Theorem and the Transference Principle. [...] Read more.
This work explores dual quaternions and their applications. First, a theoretical construction begins at dual numbers, extends to dual vectors, and culminates in dual quaternions. The physical foundations behind the developed theory lie in two important fundamentals: Chasles’ Theorem and the Transference Principle. The former addresses how to represent rigid-body motion whereas the latter provides a method for operating on it. This combination presents dual quaternions as a framework for modeling rigid mechanical systems, both kinematically and kinetically, in a compact, elegant and performant way. Next, a review on the applications of dual quaternions is carried out, providing a general overview of all applications. Important subjects are further detailed, these being the kinematics and dynamics of rigid bodies and mechanisms (both serial and parallel), control and motion interpolation. Discussions regarding dual quaternions and their applications are undertaken, highlighting open questions and research gaps. The advantages and disadvantages of using dual quaternions are summarized. Lastly, conclusions and future directions of research are presented. Full article
(This article belongs to the Special Issue Control and Mechanical System Engineering)
27 pages, 2860 KiB  
Review
A Review of Advances in Molecular Imaging of Rheumatoid Arthritis: From In Vitro to Clinic Applications Using Radiolabeled Targeting Vectors with Technetium-99m
by Muhammad Ali, Viviana Benfante, Domenico Di Raimondo, Riccardo Laudicella, Antonino Tuttolomondo and Albert Comelli
Life 2024, 14(6), 751; https://doi.org/10.3390/life14060751 (registering DOI) - 12 Jun 2024
Abstract
Rheumatoid arthritis (RA) is a systemic autoimmune disorder caused by inflammation of cartilaginous diarthrodial joints that destroys joints and cartilage, resulting in synovitis and pannus formation. Timely detection and effective management of RA are pivotal for mitigating inflammatory arthritis consequences, potentially influencing disease [...] Read more.
Rheumatoid arthritis (RA) is a systemic autoimmune disorder caused by inflammation of cartilaginous diarthrodial joints that destroys joints and cartilage, resulting in synovitis and pannus formation. Timely detection and effective management of RA are pivotal for mitigating inflammatory arthritis consequences, potentially influencing disease progression. Nuclear medicine using radiolabeled targeted vectors presents a promising avenue for RA diagnosis and response to treatment assessment. Radiopharmaceutical such as technetium-99m (99mTc), combined with single photon emission computed tomography (SPECT) combined with CT (SPECT/CT), introduces a more refined diagnostic approach, enhancing accuracy through precise anatomical localization, representing a notable advancement in hybrid molecular imaging for RA evaluation. This comprehensive review discusses existing research, encompassing in vitro, in vivo, and clinical studies to explore the application of 99mTc radiolabeled targeting vectors with SPECT imaging for RA diagnosis. The purpose of this review is to highlight the potential of this strategy to enhance patient outcomes by improving the early detection and management of RA. Full article
(This article belongs to the Section Radiobiology and Nuclear Medicine)
18 pages, 911 KiB  
Article
Spatial Distribution Heterogeneity of Riparian Plant Communities and Their Environmental Interpretation in Hillstreams
by Kejun Xu, Jihong Xia, Liting Sheng, Yue Wang, Jiayi Zu, Qihua Wang and Shuyi Ji
Appl. Sci. 2024, 14(12), 5114; https://doi.org/10.3390/app14125114 (registering DOI) - 12 Jun 2024
Abstract
In plant ecology and environmental remediation, the characterization of riparian plant communities and the influence of environmental factors have been widely discussed. However, the delineation of plant communities from different spatial perspectives is often overlooked, especially in hillstreams. In this study, the Lingshan [...] Read more.
In plant ecology and environmental remediation, the characterization of riparian plant communities and the influence of environmental factors have been widely discussed. However, the delineation of plant communities from different spatial perspectives is often overlooked, especially in hillstreams. In this study, the Lingshan River is taken as the research area, which is a quintessential hillstream and is characterized by a plethora of hydraulic structures lining its course by 20 weirs. We aim to investigate the multidimensional spatial distribution of riparian plants and their main environmental factors through plant field surveys combined with cluster analysis and redundancy analysis (RDA). The main findings are as follows: (1) In this study, a total of 104 herbaceous species were investigated, distributed among 12 families, in which Poaceae (16.67%) and Compositae (9.65%) showed significant dominance. (2) Plant community delineation was based on the complete linkage clustering. Five plant communities were classified along the longitudinal scale of the river, four plant communities were in the near-water zones, and three plant communities were in the far-water zones. (3) Riparian plant diversity and community distribution in longitudinal and lateral dimensions exhibits significant differentiation. Longitudinally, there was a significant decrease in plant diversity from upstream to downstream. Laterally, the plant biomass in the near-water zone was higher than in the far-water zone, while diversity demonstrated a reverse trend in the midstream. (4) The main environmental factors influencing plant distribution varied for different spatial dimensions. Longitudinally, the physical factor of soil is domination, particularly soil texture, which exhibits the strongest correlation with plant communities. Laterally, the chemical factor of soil is domination, such as soil organic matter and soil nitrate nitrogen content. This study enhances our understanding of the riparian area’s ecology, and provides a scientific basis for plant cover restoration and ecological environment protection, and their management. Full article
(This article belongs to the Section Ecology Science and Engineering)
21 pages, 4303 KiB  
Article
Effect of Trough Incidence Angle on the Aerodynamic Characteristics of a Biomimetic Leading-Edge Protuberanced (LEP) Wing at Various Turbulence Intensities
by Shanmugam Arunvinthan, Ponnusamy Gouri, Saravanan Divysha, RK Devadharshini and Rajan Nithya Sree
Biomimetics 2024, 9(6), 354; https://doi.org/10.3390/biomimetics9060354 (registering DOI) - 12 Jun 2024
Abstract
A series of wind tunnel tests were performed to investigate the effect of turbulent inflows on the aerodynamic characteristics of variously modified trough incident leading-edge-protuberanced (LEP) wing configurations at various turbulence intensities. A self-developed passive grid made of parallel arrays of round bars [...] Read more.
A series of wind tunnel tests were performed to investigate the effect of turbulent inflows on the aerodynamic characteristics of variously modified trough incident leading-edge-protuberanced (LEP) wing configurations at various turbulence intensities. A self-developed passive grid made of parallel arrays of round bars was placed at different locations of the wind tunnel to generate desired turbulence intensity. The aerodynamic forces acting over the trough incidence LEP wing configuration where obtained from surface pressure measurements made over the wing at different turbulence intensities using an MPS4264 Scanivalve simultaneous pressure scanner corresponding to a sampling frequency of 700 Hz. All the test models were tested at a wide range of angles of attack ranging between 0°α90° at turbulence intensities varying between 5.90% ≤ TI ≤ 10.54%. Results revealed that the time-averaged mean coefficient of lift (CL) increased with the increase in the turbulence intensity associated with smooth stall characteristics rendering the modified LEP test models advantageous. Furthermore, based on the surface pressure coefficients, the underlying dynamics behind the stall delay tendency were discussed. Additionally, attempts were made to statistically quantify the aerodynamic forces using standard deviation at both the pre-stall and the post-stall angles. Full article
(This article belongs to the Special Issue Bio-Inspired Fluid Flows and Fluid Mechanics)
Show Figures

Figure 1

14 pages, 905 KiB  
Article
Analytical and Clinical Interference of Sample Hemolysis in Evaluating Blood Biochemical and Endocrine Parameters in Cows
by Dražen Kovačević, Marko Cincović, Mira Majkić, Jovan Spasojević, Radojica Djoković, Sandra Nikolić, Maja Došenović Marinković, Biljana Delić Vujanović, Nemanja Obradović, Ljiljana Anđušić, Aleksandar Čukić, Miloš Petrović, Jože Starič and Jožica Ježek
Animals 2024, 14(12), 1773; https://doi.org/10.3390/ani14121773 (registering DOI) - 12 Jun 2024
Abstract
Hemolysis is a common cause of errors in laboratory tests as it affects blood parameters and leads to a positive or negative bias. This study aims to examine the relationship between the level of hemolysis (expressed as cell-free hemoglobin concentration, g/L) and the [...] Read more.
Hemolysis is a common cause of errors in laboratory tests as it affects blood parameters and leads to a positive or negative bias. This study aims to examine the relationship between the level of hemolysis (expressed as cell-free hemoglobin concentration, g/L) and the variability of metabolic and endocrine parameters and to determine the threshold level of hemolysis that causes an analytically and clinically significant bias for the twenty most frequently examined blood parameters in cows. Paired blood samples of 10 mL each were obtained from 30 cows. One was subjected to mechanical trauma and plasma was extracted directly from the other. Hemolyzed and non-hemolyzed samples from the same animal were mixed to obtain final samples with cell-free hemoglobin concentrations of 0, 1, 2, 4, 6, 8, and 10 g/L. Metabolic and endocrine parameters were measured in the samples and their deviation and the linear equation between the level of hemolysis and the deviation were determined. The following threshold values of hemolysis were determined, which correspond to the acceptable analytical (lower value) and clinical (upper value) levels of parameter variability: BHB 0.96 and 4.81; NEFA 0.39 and 3.31; GLU 0.38 and 3.90; ALB 1.12 and 6.11; TPROT 1.40 and 6.80; UREA 6.62 and 20.1; TBIL 0.75 and 5.65; AST 0.11 and 2.18; GGT 1.71 and 8.90, LDH 0.01 and 0.11, ALP 0.97 and 2.95; TGC 1.56 and 15.5; CHOL 1.29 and 8.56; Ca 5.68 and 25.7; P 0.57 and 8.43; Mg 1.10 and 8.47; INS 1.15 and 3.89; T3 8.19 and 15.6; T4 8.97 and 18.5; and CORT 2.78 and 11.22 g/L cell-free hemoglobin. Three decision levels are available for each metabolic and endocrine parameter: if hemolysis is below the lower (analytical) threshold value, results can be reported without restriction; if hemolysis is between the lower and upper thresholds, the results can be issued with guidance in the form of corrective linear equations; and if hemolysis is above the upper (clinical) threshold, the results and sample must be discarded. This method contributes to an optimal approach to hemolysis interference with metabolic profile parameters in blood samples from cows. Full article
(This article belongs to the Special Issue Monitoring of Cows: Management and Sustainability)
Show Figures

Figure 1

16 pages, 1511 KiB  
Review
Towards Circular Economy: Integrating Waste Management for Renewable Energy Optimization in Zimbabwe
by Hagreaves Kumba, Denzel Christopher Makepa, Anesu Nicholas Charamba and Oludolapo A. Olanrewaju
Sustainability 2024, 16(12), 5014; https://doi.org/10.3390/su16125014 (registering DOI) - 12 Jun 2024
Abstract
Many countries across the globe are not yet exploiting the full potential energy that is inherent in waste to solve their energy and waste management crisis. This review critically examines the intersection of waste management and renewable energy optimization within the context of [...] Read more.
Many countries across the globe are not yet exploiting the full potential energy that is inherent in waste to solve their energy and waste management crisis. This review critically examines the intersection of waste management and renewable energy optimization within the context of Zimbabwe’s transition towards a circular economy. This review explores the integration of waste management practices into renewable energy initiatives to foster a circular economy in Zimbabwe. Therefore, by assessing the feasibility and benefits of incorporating waste-to-energy technologies, this study elucidates the potential for synergistic resource utilization and environmental sustainability. Through a comprehensive analysis of existing waste management frameworks and renewable energy strategies, this paper highlights opportunities for optimizing energy production while addressing pressing waste management challenges. Ultimately, the findings underscore the importance of adopting a comprehensive approach to renewable energy development that leverages waste as a valuable resource in Zimbabwe’s transition towards a circular economy paradigm. Full article
Show Figures

Figure 1

Open Access Journals

Browse by Indexing Browse by Subject Selected Journals
Back to TopTop